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(Z)-(5R,11S)-11-Isopropenyl-3-methyl-7-oxo-6,16-dioxa-tricyclo[11.2.1.15,8]heptadeca-1(15),2,8(17),13-tetraene-14-carboxylic acid
CAS号:1025782-65-3
英文名:(Z)-(5R,11S)-11-Isopropenyl-3-methyl-7-oxo-6,16-dioxa-tricyclo[11.2.1.15,8]heptadeca-1(15),2,8(17),13-tetraene-14-carboxylic acid
分子式:C20H22O5
分子量:342.386
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上游原料
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(3S)-10-(t-butyldimethylsilyloxy)-8-(t-butyldiphenylsilyloxy)-3-isopropenyl-13-(p-methoxybenzyloxy)-6,11-tri ecadiynal
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(8S)-1-(t-butyldimethylsilyloxy)-10,10-dimethoxy-8-isopropenyl-4-decyn-3-ol
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(S)-7,7-dimethoxy-5-isopropenyl-1-heptyne
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(13S)-2-t-butoxycarbonyl-6-(t-butyldimethylsilyloxy)-8-(t-butyldiphenylsilyloxy)-13-isopropenyl-4,9-cyclotetradecadiynone
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t-butyl (5S)-12-(t-butyldimethylsilyloxy)-10-(t-butyldiphenylsilyloxy)-5-isopropenyl-3-keto-15-(p-methoxybenzyloxy)-8,13-pentadecadiynoate
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(S)-5-(tert-Butyl-diphenyl-silanyloxy)-10-isopropenyl-3-oxo-15-oxa-bicyclo[10.2.1]pentadeca-1(14),12-dien-6-yne-13-carboxylic acid tert-butyl ester
上游原料
(3S)-10-(t-butyldimethylsilyloxy)-8-(t-butyldiphenylsilyloxy)-3-isopropenyl-13-(p-methoxybenzyloxy)-6,11-tri ecadiynal
(8S)-1-(t-butyldimethylsilyloxy)-10,10-dimethoxy-8-isopropenyl-4-decyn-3-ol
(S)-7,7-dimethoxy-5-isopropenyl-1-heptyne
(13S)-2-t-butoxycarbonyl-6-(t-butyldimethylsilyloxy)-8-(t-butyldiphenylsilyloxy)-13-isopropenyl-4,9-cyclotetradecadiynone
t-butyl (5S)-12-(t-butyldimethylsilyloxy)-10-(t-butyldiphenylsilyloxy)-5-isopropenyl-3-keto-15-(p-methoxybenzyloxy)-8,13-pentadecadiynoate
(S)-5-(tert-Butyl-diphenyl-silanyloxy)-10-isopropenyl-3-oxo-15-oxa-bicyclo[10.2.1]pentadeca-1(14),12-dien-6-yne-13-carboxylic acid tert-butyl ester