百科

(S)-3-{(2R,13R)-2,13-Bis-methoxymethoxy-13-[(2R,5R,2'R,5'R)-5'-((S)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-tridecyl}-4-hydroxy-5-methyl-dihydro-furan-2-one

CAS号：1025947-35-6

英文名：(S)-3-{(2R,13R)-2,13-Bis-methoxymethoxy-13-[(2R,5R,2'R,5'R)-5'-((S)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-tridecyl}-4-hydroxy-5-methyl-dihydro-furan-2-one

分子式：C43H80O11

分子量：773.089

合成路线

165961-10-4

(4R,15R)-4,15-Bis-methoxymethoxy-15-[(2R,5R,2'R,5'R)-5'-((S)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-pentadecan-1-ol

1025947-35-6

(S)-3-{(2R,13R)-2,13-Bis-methoxymethoxy-13-[(2R,5R,2'R,5'R)-5'-((S)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-tridecyl}-4-hydroxy-5-methyl-dihydro-furan-2-one

165961-07-9

(+)-(4R,15R,16R,19R,20R,23R,24S)-1-O-(tert-Butyldimethylsilyl)-4-O-(methoxymethyl)-16,19:20,23:24,25-triepoxy-1,4,15-trihydroxypentacosane

1025947-35-6

(S)-3-{(2R,13R)-2,13-Bis-methoxymethoxy-13-[(2R,5R,2'R,5'R)-5'-((S)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-tridecyl}-4-hydroxy-5-methyl-dihydro-furan-2-one

165961-00-2

(R)-13-(tert-Butyl-dimethyl-silanyloxy)-10-methoxymethoxy-tridecan-1-ol

1025947-35-6

(S)-3-{(2R,13R)-2,13-Bis-methoxymethoxy-13-[(2R,5R,2'R,5'R)-5'-((S)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-tridecyl}-4-hydroxy-5-methyl-dihydro-furan-2-one

165960-98-5

(R)-13-Benzyloxy-4-methoxymethoxy-tridecan-1-ol

1025947-35-6

(S)-3-{(2R,13R)-2,13-Bis-methoxymethoxy-13-[(2R,5R,2'R,5'R)-5'-((S)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-tridecyl}-4-hydroxy-5-methyl-dihydro-furan-2-one

165961-03-5

((R)-13-Benzenesulfonyl-4-methoxymethoxy-tridecyloxy)-tert-butyl-dimethyl-silane

1025947-35-6

(S)-3-{(2R,13R)-2,13-Bis-methoxymethoxy-13-[(2R,5R,2'R,5'R)-5'-((S)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-tridecyl}-4-hydroxy-5-methyl-dihydro-furan-2-one

165961-05-7

(+)-(4R,15R,16R,19R,20R,23R,24S)-1-O-(tert-Butyldimethylsilyl)-16,19:20,23-diepoxy-4-O-(methoxymethyl)-1,4,15,24,25-pentahydroxypentacosane

1025947-35-6

(S)-3-{(2R,13R)-2,13-Bis-methoxymethoxy-13-[(2R,5R,2'R,5'R)-5'-((S)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-tridecyl}-4-hydroxy-5-methyl-dihydro-furan-2-one

165961-08-0

(1R,12R)-15-(tert-Butyl-dimethyl-silanyloxy)-1-[(2R,5R,2'R,5'R)-5'-((S)-1-hydroxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-12-methoxymethoxy-pentadecan-1-ol

1025947-35-6

(S)-3-{(2R,13R)-2,13-Bis-methoxymethoxy-13-[(2R,5R,2'R,5'R)-5'-((S)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-tridecyl}-4-hydroxy-5-methyl-dihydro-furan-2-one

204637-90-1

(-)-(2S,3R,6R,7R,10R,11S)-1,12-O-Bis(4-nitrobenzoyl)-3,6:7,10-diepoxy-1,2,11,12-tetrahydroxydodecane

1025947-35-6

(S)-3-{(2R,13R)-2,13-Bis-methoxymethoxy-13-[(2R,5R,2'R,5'R)-5'-((S)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-tridecyl}-4-hydroxy-5-methyl-dihydro-furan-2-one

165961-06-8

Toluene-4-sulfonic acid (S)-2-{(2R,5R,2'R,5'R)-5'-[(1R,12R)-15-(tert-butyl-dimethyl-silanyloxy)-1-hydroxy-12-methoxymethoxy-pentadecyl]-octahydro-[2,2']bifuranyl-5-yl}-2-hydroxy-ethyl ester

1025947-35-6

(S)-3-{(2R,13R)-2,13-Bis-methoxymethoxy-13-[(2R,5R,2'R,5'R)-5'-((S)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-tridecyl}-4-hydroxy-5-methyl-dihydro-furan-2-one

165960-92-9

(-)-(2S,3R,6R,7R,10R,11S)-1,12-O-Bis(4-nitrobenzoyl)-3,6:7,10-diepoxy-2-O-methanesulfonyl-1,2,11,12-tetrahydroxydodecane

1025947-35-6

(S)-3-{(2R,13R)-2,13-Bis-methoxymethoxy-13-[(2R,5R,2'R,5'R)-5'-((S)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-tridecyl}-4-hydroxy-5-methyl-dihydro-furan-2-one

上游原料

(+)-(4R,15R,16R,19R,20R,23R,24S)-16,19:20,23-Diepoxy-1,4,15,24-tetrahydroxy-4,15,24-O-tris(methoxymethyl)tetratriacontanoic acid methyl ester tert-Butyl-((R)-4-methoxymethoxy-13-phenylsulfanyl-tridecyloxy)-dimethyl-silane ((R)-13-Benzenesulfonyl-4-methoxymethoxy-tridecyloxy)-tert-butyl-dimethyl-silane (1R,12R)-15-(tert-Butyl-dimethyl-silanyloxy)-1-[(2R,5R,2'R,5'R)-5'-((S)-1-hydroxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-12-methoxymethoxy-pentadecan-1-ol (-)-(2S,3R,6R,7R,10R,11S)-1,12-O-Bis(4-nitrobenzoyl)-3,6:7,10-diepoxy-1,2,11,12-tetrahydroxydodecane (4R,15R)-4,15-Bis-methoxymethoxy-15-[(2R,5R,2'R,5'R)-5'-((S)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-pentadecanoic acid (+)-(4R,15R,16R,19R,20R,23R,24S)-1-O-(tert-Butyldimethylsilyl)-16,19:20,23-diepoxy-4-O-(methoxymethyl)-1,4,15,24,25-pentahydroxypentacosane Toluene-4-sulfonic acid (S)-2-{(2R,5R,2'R,5'R)-5'-[(1R,12R)-15-(tert-butyl-dimethyl-silanyloxy)-1-hydroxy-12-methoxymethoxy-pentadecyl]-octahydro-[2,2']bifuranyl-5-yl}-2-hydroxy-ethyl ester (+)-(4R,15R,16R,19R,20R,23R,24S)-1-O-(tert-Butyldimethylsilyl)-4-O-(methoxymethyl)-16,19:20,23:24,25-triepoxy-1,4,15-trihydroxypentacosane ((R)-10-Methoxymethoxy-tridec-12-enyloxymethyl)-benzene (-)-(2S,3R,6R,7R,10R,11S)-1,12-O-Bis(4-nitrobenzoyl)-3,6:7,10-diepoxy-2-O-methanesulfonyl-1,2,11,12-tetrahydroxydodecane (R)-13-Benzyloxy-4-methoxymethoxy-tridecan-1-ol (+)-(4R)-13-(Benzyloxy)-1-<(tert-butyldimethylsilyl)oxy>-4-<(methoxymethyl)oxy>tridecane (-)-(2S,3S,6R,7R,10S,11S)-2,3:10,11-Diepoxy-6,7-O-isopropylidene-1,12-O-bis(4-nitrobenzoyl)-1,6,7,12-tetrahydroxydodecane (4R,15R)-4,15-Bis-methoxymethoxy-15-[(2R,5R,2'R,5'R)-5'-((S)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-pentadecan-1-ol (R)-13-(tert-Butyl-dimethyl-silanyloxy)-10-methoxymethoxy-tridecan-1-ol

下游产品

(+)-4,15,24-O-Tris(methoxymethyl)bullatacin