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(4R,15R)-4,15-Bis-methoxymethoxy-15-[(2R,5R,2'R,5'R)-5'-((S)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-pentadecanoic acid
CAS号:1025980-74-8
英文名:(4R,15R)-4,15-Bis-methoxymethoxy-15-[(2R,5R,2'R,5'R)-5'-((S)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-pentadecanoic acid
分子式:C40H76O10
分子量:717.025
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合成路线
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(-)-(2S,3S,6R,7R,10S,11S)-2,3:10,11-Diepoxy-6,7-O-isopropylidene-1,12-O-bis(4-nitrobenzoyl)-1,6,7,12-tetrahydroxydodecane
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(4R,15R)-4,15-Bis-methoxymethoxy-15-[(2R,5R,2'R,5'R)-5'-((S)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-pentadecanoic acid
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(+)-(4R)-13-(Benzyloxy)-1-<(tert-butyldimethylsilyl)oxy>-4-<(methoxymethyl)oxy>tridecane
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(4R,15R)-4,15-Bis-methoxymethoxy-15-[(2R,5R,2'R,5'R)-5'-((S)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-pentadecanoic acid
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(+)-(4R,15R,16R,19R,20R,23R,24S)-1-O-(tert-Butyldimethylsilyl)-4-O-(methoxymethyl)-16,19:20,23:24,25-triepoxy-1,4,15-trihydroxypentacosane
1025980-74-8
(4R,15R)-4,15-Bis-methoxymethoxy-15-[(2R,5R,2'R,5'R)-5'-((S)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-pentadecanoic acid
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tert-Butyl-((R)-4-methoxymethoxy-13-phenylsulfanyl-tridecyloxy)-dimethyl-silane
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(4R,15R)-4,15-Bis-methoxymethoxy-15-[(2R,5R,2'R,5'R)-5'-((S)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-pentadecanoic acid
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((R)-13-Benzenesulfonyl-4-methoxymethoxy-tridecyloxy)-tert-butyl-dimethyl-silane
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(4R,15R)-4,15-Bis-methoxymethoxy-15-[(2R,5R,2'R,5'R)-5'-((S)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-pentadecanoic acid
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(+)-(4R,15R,16R,19R,20R,23R,24S)-1-O-(tert-Butyldimethylsilyl)-16,19:20,23-diepoxy-4-O-(methoxymethyl)-1,4,15,24,25-pentahydroxypentacosane
1025980-74-8
(4R,15R)-4,15-Bis-methoxymethoxy-15-[(2R,5R,2'R,5'R)-5'-((S)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-pentadecanoic acid
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(1R,12R)-15-(tert-Butyl-dimethyl-silanyloxy)-1-[(2R,5R,2'R,5'R)-5'-((S)-1-hydroxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-12-methoxymethoxy-pentadecan-1-ol
1025980-74-8
(4R,15R)-4,15-Bis-methoxymethoxy-15-[(2R,5R,2'R,5'R)-5'-((S)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-pentadecanoic acid
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(4R,15R)-4,15-Bis-methoxymethoxy-15-[(2R,5R,2'R,5'R)-5'-((S)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-pentadecanoic acid
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Toluene-4-sulfonic acid (S)-2-{(2R,5R,2'R,5'R)-5'-[(1R,12R)-15-(tert-butyl-dimethyl-silanyloxy)-1-hydroxy-12-methoxymethoxy-pentadecyl]-octahydro-[2,2']bifuranyl-5-yl}-2-hydroxy-ethyl ester
1025980-74-8
(4R,15R)-4,15-Bis-methoxymethoxy-15-[(2R,5R,2'R,5'R)-5'-((S)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-pentadecanoic acid
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(-)-(2S,3R,6R,7R,10R,11S)-1,12-O-Bis(4-nitrobenzoyl)-3,6:7,10-diepoxy-2-O-methanesulfonyl-1,2,11,12-tetrahydroxydodecane
1025980-74-8
(4R,15R)-4,15-Bis-methoxymethoxy-15-[(2R,5R,2'R,5'R)-5'-((S)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-pentadecanoic acid
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上游原料
tert-Butyl-((R)-4-methoxymethoxy-13-phenylsulfanyl-tridecyloxy)-dimethyl-silane
((R)-13-Benzenesulfonyl-4-methoxymethoxy-tridecyloxy)-tert-butyl-dimethyl-silane
(1R,12R)-15-(tert-Butyl-dimethyl-silanyloxy)-1-[(2R,5R,2'R,5'R)-5'-((S)-1-hydroxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-12-methoxymethoxy-pentadecan-1-ol
(-)-(2S,3R,6R,7R,10R,11S)-1,12-O-Bis(4-nitrobenzoyl)-3,6:7,10-diepoxy-1,2,11,12-tetrahydroxydodecane
(+)-(4R,15R,16R,19R,20R,23R,24S)-1-O-(tert-Butyldimethylsilyl)-16,19:20,23-diepoxy-4-O-(methoxymethyl)-1,4,15,24,25-pentahydroxypentacosane
Toluene-4-sulfonic acid (S)-2-{(2R,5R,2'R,5'R)-5'-[(1R,12R)-15-(tert-butyl-dimethyl-silanyloxy)-1-hydroxy-12-methoxymethoxy-pentadecyl]-octahydro-[2,2']bifuranyl-5-yl}-2-hydroxy-ethyl ester
(+)-(4R,15R,16R,19R,20R,23R,24S)-1-O-(tert-Butyldimethylsilyl)-4-O-(methoxymethyl)-16,19:20,23:24,25-triepoxy-1,4,15-trihydroxypentacosane
((R)-10-Methoxymethoxy-tridec-12-enyloxymethyl)-benzene
(-)-(2S,3R,6R,7R,10R,11S)-1,12-O-Bis(4-nitrobenzoyl)-3,6:7,10-diepoxy-2-O-methanesulfonyl-1,2,11,12-tetrahydroxydodecane
(R)-13-Benzyloxy-4-methoxymethoxy-tridecan-1-ol
(+)-(4R)-13-(Benzyloxy)-1-<(tert-butyldimethylsilyl)oxy>-4-<(methoxymethyl)oxy>tridecane
(-)-(2S,3S,6R,7R,10S,11S)-2,3:10,11-Diepoxy-6,7-O-isopropylidene-1,12-O-bis(4-nitrobenzoyl)-1,6,7,12-tetrahydroxydodecane
(4R,15R)-4,15-Bis-methoxymethoxy-15-[(2R,5R,2'R,5'R)-5'-((S)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-pentadecan-1-ol
(R)-13-(tert-Butyl-dimethyl-silanyloxy)-10-methoxymethoxy-tridecan-1-ol
下游产品
(+)-4,15,24-O-Tris(methoxymethyl)bullatacin
(S)-3-{(2R,13R)-2,13-Bis-methoxymethoxy-13-[(2R,5R,2'R,5'R)-5'-((S)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-tridecyl}-4-hydroxy-5-methyl-dihydro-furan-2-one
Benzoic acid (S)-4-{(2R,13R)-2,13-bis-methoxymethoxy-13-[(2R,5R,2'R,5'R)-5'-((S)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-tridecyl}-2-methyl-5-oxo-tetrahydro-furan-3-yl ester