百科

tert-Butyl-{(3E,5E)-(1R,2S)-7-ethoxy-1-[(1S,2S)-2-(2-methoxy-ethoxymethoxy)-1-methyl-propyl]-2-methyl-hepta-3,5-dienyloxy}-dimethyl-silane

tert-Butyl-{(3E,5E)-(1R,2S)-7-ethoxy-1-[(1S,2S)-2-(2-methoxy-ethoxymethoxy)-1-methyl-propyl]-2-methyl-hepta-3,5-dienyloxy}-dimethyl-silane

CAS号：102614-39-1

英文名：tert-Butyl-{(3E,5E)-(1R,2S)-7-ethoxy-1-[(1S,2S)-2-(2-methoxy-ethoxymethoxy)-1-methyl-propyl]-2-methyl-hepta-3,5-dienyloxy}-dimethyl-silane

分子式：C24H48O5Si

分子量：444.72

合成路线

2(S)-(benzylamino)-3(S)-methyl-4(R)-<(tert-butyldimethylsilyl)-oxy>-5(S)-methylhept-6-en-1-ol

2(S)-(benzylamino)-3(S)-methyl-4(R)-<(tert-butyldimethylsilyl)-oxy>-5(S)-methylhept-6-en-1-ol

tert-Butyl-{(3E,5E)-(1R,2S)-7-ethoxy-1-[(1S,2S)-2-(2-methoxy-ethoxymethoxy)-1-methyl-propyl]-2-methyl-hepta-3,5-dienyloxy}-dimethyl-silane

tert-Butyl-{(3E,5E)-(1R,2S)-7-ethoxy-1-[(1S,2S)-2-(2-methoxy-ethoxymethoxy)-1-methyl-propyl]-2-methyl-hepta-3,5-dienyloxy}-dimethyl-silane

3(S)-methyl-4(R)-<(tert-butyldimethylsilyl)oxy>-5(S)-methylhept-6-en-2-one

3(S)-methyl-4(R)-<(tert-butyldimethylsilyl)oxy>-5(S)-methylhept-6-en-2-one

tert-Butyl-{(3E,5E)-(1R,2S)-7-ethoxy-1-[(1S,2S)-2-(2-methoxy-ethoxymethoxy)-1-methyl-propyl]-2-methyl-hepta-3,5-dienyloxy}-dimethyl-silane

tert-Butyl-{(3E,5E)-(1R,2S)-7-ethoxy-1-[(1S,2S)-2-(2-methoxy-ethoxymethoxy)-1-methyl-propyl]-2-methyl-hepta-3,5-dienyloxy}-dimethyl-silane

2-phenyl-4(S)-<4(S)-methyl-3(R)-hydroxyhex-5-en-2(S)-yl>-2-oxazoline

2-phenyl-4(S)-<4(S)-methyl-3(R)-hydroxyhex-5-en-2(S)-yl>-2-oxazoline

tert-Butyl-{(3E,5E)-(1R,2S)-7-ethoxy-1-[(1S,2S)-2-(2-methoxy-ethoxymethoxy)-1-methyl-propyl]-2-methyl-hepta-3,5-dienyloxy}-dimethyl-silane

tert-Butyl-{(3E,5E)-(1R,2S)-7-ethoxy-1-[(1S,2S)-2-(2-methoxy-ethoxymethoxy)-1-methyl-propyl]-2-methyl-hepta-3,5-dienyloxy}-dimethyl-silane

2-phenyl-4(S)-<4(S)-methyl-3(R)-<(tert-butyldimethylsilyl)oxy>hex-5-en-2(S)-yl>-2-oxazoline

2-phenyl-4(S)-<4(S)-methyl-3(R)-<(tert-butyldimethylsilyl)oxy>hex-5-en-2(S)-yl>-2-oxazoline

tert-Butyl-{(3E,5E)-(1R,2S)-7-ethoxy-1-[(1S,2S)-2-(2-methoxy-ethoxymethoxy)-1-methyl-propyl]-2-methyl-hepta-3,5-dienyloxy}-dimethyl-silane

tert-Butyl-{(3E,5E)-(1R,2S)-7-ethoxy-1-[(1S,2S)-2-(2-methoxy-ethoxymethoxy)-1-methyl-propyl]-2-methyl-hepta-3,5-dienyloxy}-dimethyl-silane

3(S)-methyl-4(R)-<(tert-butyldimethylsilyl)oxy>-5(S)-methylhept-6-en-2(S)-ol

3(S)-methyl-4(R)-<(tert-butyldimethylsilyl)oxy>-5(S)-methylhept-6-en-2(S)-ol

tert-Butyl-{(3E,5E)-(1R,2S)-7-ethoxy-1-[(1S,2S)-2-(2-methoxy-ethoxymethoxy)-1-methyl-propyl]-2-methyl-hepta-3,5-dienyloxy}-dimethyl-silane

tert-Butyl-{(3E,5E)-(1R,2S)-7-ethoxy-1-[(1S,2S)-2-(2-methoxy-ethoxymethoxy)-1-methyl-propyl]-2-methyl-hepta-3,5-dienyloxy}-dimethyl-silane

2(R)methyl-3(R)-<(tert-butyldimethylsilyl)oxy>-4(S)-methylhex-5-enal

2(R)methyl-3(R)-<(tert-butyldimethylsilyl)oxy>-4(S)-methylhex-5-enal

tert-Butyl-{(3E,5E)-(1R,2S)-7-ethoxy-1-[(1S,2S)-2-(2-methoxy-ethoxymethoxy)-1-methyl-propyl]-2-methyl-hepta-3,5-dienyloxy}-dimethyl-silane

tert-Butyl-{(3E,5E)-(1R,2S)-7-ethoxy-1-[(1S,2S)-2-(2-methoxy-ethoxymethoxy)-1-methyl-propyl]-2-methyl-hepta-3,5-dienyloxy}-dimethyl-silane

3(S)-methyl-4(R)-<(tert-butyldimethylsilyl)oxy>-5(S)-methyl-6-(S)-<(methoxyethoxymethyl)oxy>hept-1-ene

3(S)-methyl-4(R)-<(tert-butyldimethylsilyl)oxy>-5(S)-methyl-6-(S)-<(methoxyethoxymethyl)oxy>hept-1-ene

tert-Butyl-{(3E,5E)-(1R,2S)-7-ethoxy-1-[(1S,2S)-2-(2-methoxy-ethoxymethoxy)-1-methyl-propyl]-2-methyl-hepta-3,5-dienyloxy}-dimethyl-silane

tert-Butyl-{(3E,5E)-(1R,2S)-7-ethoxy-1-[(1S,2S)-2-(2-methoxy-ethoxymethoxy)-1-methyl-propyl]-2-methyl-hepta-3,5-dienyloxy}-dimethyl-silane

上游原料

3(S)-methyl-4(R)-<(tert-butyldimethylsilyl)oxy>-5(S)-methylhept-6-en-2-one 3(S)-methyl-4(R)-<(tert-butyldimethylsilyl)oxy>-5(S)-methyl-6-(S)-<(methoxyethoxymethyl)oxy>hept-1-ene 3(S)-methyl-4(R)-<(tert-butyldimethylsilyl)oxy>-5(S)-methylhept-6-en-2(S)-ol 2(R)methyl-3(R)-<(tert-butyldimethylsilyl)oxy>-4(S)-methylhex-5-enal 2-phenyl-4(S)-<4(S)-methyl-3(R)-<(tert-butyldimethylsilyl)oxy>hex-5-en-2(S)-yl>-2-oxazoline 2(S)-(benzylamino)-3(S)-methyl-4(R)-<(tert-butyldimethylsilyl)-oxy>-5(S)-methylhept-6-en-1-ol 2-phenyl-4(S)-<4(S)-methyl-3(R)-hydroxyhex-5-en-2(S)-yl>-2-oxazoline

下游产品

6(S)-methyl-7(R)-<(tert-butyldimethylsilyl)oxy>-8(S)-methyl-9-(S)<(methoxyethoxymethyl)oxy>deca-2,4-dienal 10(S)-methyl-11(R)-<(tert-butyldimethylsilyl)oxy>-12(S)-methyl-13(S)<(methoxyethoxymethyl)oxy>tetradeca-2,4,6,8-tetraenal