百科

2-[(1S,4R,5R)-5-((E)-5-Benzenesulfonyl-3-methyl-pent-3-enyl)-4-((E)-4-chloro-3-methyl-but-2-enyl)-4-methyl-cyclopent-2-enyl]-2-methyl-[1,3]dioxolane

CAS号：1026459-62-0

英文名：2-[(1S,4R,5R)-5-((E)-5-Benzenesulfonyl-3-methyl-pent-3-enyl)-4-((E)-4-chloro-3-methyl-but-2-enyl)-4-methyl-cyclopent-2-enyl]-2-methyl-[1,3]dioxolane

分子式：C27H37ClO4S

分子量：493.098

合成路线

213816-83-2

Acetic acid (1S,2S,4R,5R,6R)-5-benzyloxymethyl-4-hydroxy-6-hydroxymethyl-5-methyl-bicyclo[2.2.1]hept-2-yl ester

1026459-62-0

2-[(1S,4R,5R)-5-((E)-5-Benzenesulfonyl-3-methyl-pent-3-enyl)-4-((E)-4-chloro-3-methyl-but-2-enyl)-4-methyl-cyclopent-2-enyl]-2-methyl-[1,3]dioxolane

213816-92-3

[(1R,2R,5S)-2-Benzyloxymethyl-2-methyl-5-(2-methyl-[1,3]dioxolan-2-yl)-cyclopent-3-enyl]-methanol

1026459-62-0

2-[(1S,4R,5R)-5-((E)-5-Benzenesulfonyl-3-methyl-pent-3-enyl)-4-((E)-4-chloro-3-methyl-but-2-enyl)-4-methyl-cyclopent-2-enyl]-2-methyl-[1,3]dioxolane

213816-80-9

[(1R,2R,3R,4S,5S)-5-(tert-Butyl-dimethyl-silanyloxy)-3-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-1-methoxymethoxy-2-methyl-bicyclo[2.2.1]hept-2-yl]-methanol

1026459-62-0

2-[(1S,4R,5R)-5-((E)-5-Benzenesulfonyl-3-methyl-pent-3-enyl)-4-((E)-4-chloro-3-methyl-but-2-enyl)-4-methyl-cyclopent-2-enyl]-2-methyl-[1,3]dioxolane

213816-79-6

(1R,2S,3R,4S,5S)-3-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-5-hydroxy-1-methoxymethoxy-2-methyl-bicyclo[2.2.1]heptane-2-carboxylic acid ethyl ester

1026459-62-0

2-[(1S,4R,5R)-5-((E)-5-Benzenesulfonyl-3-methyl-pent-3-enyl)-4-((E)-4-chloro-3-methyl-but-2-enyl)-4-methyl-cyclopent-2-enyl]-2-methyl-[1,3]dioxolane

213816-72-9

[(1R,4S,5R)-5-[(E)-5-((tert-butyldimethylsilanyl)oxy)-3-methyl-3-pentenyl]-1-methyl-4-(2-methyl-1,3-dioxolan-2-yl)-2-cyclopentenyl]methanol

1026459-62-0

2-[(1S,4R,5R)-5-((E)-5-Benzenesulfonyl-3-methyl-pent-3-enyl)-4-((E)-4-chloro-3-methyl-but-2-enyl)-4-methyl-cyclopent-2-enyl]-2-methyl-[1,3]dioxolane

213816-68-3

((1R,2R,5S)-2-(benzyloxy)methyl-2-methyl-5-(2-methyl-1,3-dioxolan-2-yl)cyclopent-3-enyl)methyl acetate

1026459-62-0

2-[(1S,4R,5R)-5-((E)-5-Benzenesulfonyl-3-methyl-pent-3-enyl)-4-((E)-4-chloro-3-methyl-but-2-enyl)-4-methyl-cyclopent-2-enyl]-2-methyl-[1,3]dioxolane

213816-63-8

[(1S,2S,4R,5R,6R)-5-benzyloxymethyl-6-((S)-2,2-dimethyl-1,3-dioxolan-4-yl)-4-methoxymethoxy-5-methylbicyclo[2.2.1]hept-2-yloxy]-tert-butyldimethylsilane

1026459-62-0

2-[(1S,4R,5R)-5-((E)-5-Benzenesulfonyl-3-methyl-pent-3-enyl)-4-((E)-4-chloro-3-methyl-but-2-enyl)-4-methyl-cyclopent-2-enyl]-2-methyl-[1,3]dioxolane

上游原料

[(1R,2R,3R,4S,5S)-5-(tert-Butyl-dimethyl-silanyloxy)-3-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-1-methoxymethoxy-2-methyl-bicyclo[2.2.1]hept-2-yl]-methanol [(1R,4S,5R)-5-[(E)-5-((tert-butyldimethylsilanyl)oxy)-3-methyl-3-pentenyl]-1-methyl-4-(2-methyl-1,3-dioxolan-2-yl)-2-cyclopentenyl]methanol ((1R,2R,5S)-2-(benzyloxy)methyl-2-methyl-5-(2-methyl-1,3-dioxolan-2-yl)cyclopent-3-enyl)methyl acetate (1R,2S,3R,4S,5S)-3-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-5-hydroxy-1-methoxymethoxy-2-methyl-bicyclo[2.2.1]heptane-2-carboxylic acid ethyl ester [(1R,2R,5S)-2-Benzyloxymethyl-2-methyl-5-(2-methyl-[1,3]dioxolan-2-yl)-cyclopent-3-enyl]-methanol [(1S,2S,4R,5R,6R)-5-benzyloxymethyl-6-((S)-2,2-dimethyl-1,3-dioxolan-4-yl)-4-methoxymethoxy-5-methylbicyclo[2.2.1]hept-2-yloxy]-tert-butyldimethylsilane Acetic acid (1S,2S,4R,5R,6R)-5-benzyloxymethyl-4-hydroxy-6-hydroxymethyl-5-methyl-bicyclo[2.2.1]hept-2-yl ester

下游产品

13-Keto-1(S),11(R)-dolabell-3(E),7(E),12(18)-triene