百科

4-Nitro-benzoic acid (E)-(1S,2S,3R)-1-[(E)-(S)-5-(tert-butyl-dimethyl-silanyloxy)-2-hydroxy-3-methyl-pent-3-enyl]-3-methoxy-6-(4-methoxy-benzyloxy)-2,4-dimethyl-hex-4-enyl ester

4-Nitro-benzoic acid (E)-(1S,2S,3R)-1-[(E)-(S)-5-(tert-butyl-dimethyl-silanyloxy)-2-hydroxy-3-methyl-pent-3-enyl]-3-methoxy-6-(4-methoxy-benzyloxy)-2,4-dimethyl-hex-4-enyl ester

CAS号：1027202-98-7

英文名：4-Nitro-benzoic acid (E)-(1S,2S,3R)-1-[(E)-(S)-5-(tert-butyl-dimethyl-silanyloxy)-2-hydroxy-3-methyl-pent-3-enyl]-3-methoxy-6-(4-methoxy-benzyloxy)-2,4-dimethyl-hex-4-enyl ester

分子式：C36H53NO9Si

分子量：671.893

合成路线

(E)-(2R,3R)-3-Methoxy-6-(4-methoxy-benzyloxy)-2,4-dimethyl-hex-4-enal

(E)-(2R,3R)-3-Methoxy-6-(4-methoxy-benzyloxy)-2,4-dimethyl-hex-4-enal

4-Nitro-benzoic acid (E)-(1S,2S,3R)-1-[(E)-(S)-5-(tert-butyl-dimethyl-silanyloxy)-2-hydroxy-3-methyl-pent-3-enyl]-3-methoxy-6-(4-methoxy-benzyloxy)-2,4-dimethyl-hex-4-enyl ester

4-Nitro-benzoic acid (E)-(1S,2S,3R)-1-[(E)-(S)-5-(tert-butyl-dimethyl-silanyloxy)-2-hydroxy-3-methyl-pent-3-enyl]-3-methoxy-6-(4-methoxy-benzyloxy)-2,4-dimethyl-hex-4-enyl ester

(2E)-4-[(4-methoxybenzyl)oxy]-2-methylbut-2-enal

(2E)-4-[(4-methoxybenzyl)oxy]-2-methylbut-2-enal

4-Nitro-benzoic acid (E)-(1S,2S,3R)-1-[(E)-(S)-5-(tert-butyl-dimethyl-silanyloxy)-2-hydroxy-3-methyl-pent-3-enyl]-3-methoxy-6-(4-methoxy-benzyloxy)-2,4-dimethyl-hex-4-enyl ester

4-Nitro-benzoic acid (E)-(1S,2S,3R)-1-[(E)-(S)-5-(tert-butyl-dimethyl-silanyloxy)-2-hydroxy-3-methyl-pent-3-enyl]-3-methoxy-6-(4-methoxy-benzyloxy)-2,4-dimethyl-hex-4-enyl ester

上游原料

(2E)-4-[(4-methoxybenzyl)oxy]-2-methylbut-2-enal (E)-(2R,3R)-3-Methoxy-6-(4-methoxy-benzyloxy)-2,4-dimethyl-hex-4-enal

下游产品

(Diethoxy-phosphoryl)-acetic acid (4E,6E)-(1S,3S,8R)-1-[(E)-(1S,2R)-2-methoxy-5-(4-methoxy-benzyloxy)-1,3-dimethyl-pent-3-enyl]-4-methyl-8-[(2R,4S)-6-oxo-4-(2-oxo-ethyl)-tetrahydro-pyran-2-yl]-3-triisopropylsilanyloxy-nona-4,6-dienyl ester O-triisopropylsilylrhizoxin D