百科

4-Oxo-pentanoic acid (2R,3R,4S,5R,6R)-2-((R)-2,2-dimethyl-[1,3]dioxolan-4-ylmethoxy)-3,5-bis-(4-oxo-pentanoyloxy)-6-(4-oxo-pentanoyloxymethyl)-tetrahydro-pyran-4-yl ester

4-Oxo-pentanoic acid (2R,3R,4S,5R,6R)-2-((R)-2,2-dimethyl-[1,3]dioxolan-4-ylmethoxy)-3,5-bis-(4-oxo-pentanoyloxy)-6-(4-oxo-pentanoyloxymethyl)-tetrahydro-pyran-4-yl ester

CAS号：102728-39-2

英文名：4-Oxo-pentanoic acid (2R,3R,4S,5R,6R)-2-((R)-2,2-dimethyl-[1,3]dioxolan-4-ylmethoxy)-3,5-bis-(4-oxo-pentanoyloxy)-6-(4-oxo-pentanoyloxymethyl)-tetrahydro-pyran-4-yl ester

分子式：C32H46O16

分子量：686.698

合成路线

(2R)-1-O-(2′,3′,4′,6′-tetra-O-acetyl-β-D-glucopyranosyl)glycerol

(2R)-1-O-(2′,3′,4′,6′-tetra-O-acetyl-β-D-glucopyranosyl)glycerol

4-Oxo-pentanoic acid (2R,3R,4S,5R,6R)-2-((R)-2,2-dimethyl-[1,3]dioxolan-4-ylmethoxy)-3,5-bis-(4-oxo-pentanoyloxy)-6-(4-oxo-pentanoyloxymethyl)-tetrahydro-pyran-4-yl ester

4-Oxo-pentanoic acid (2R,3R,4S,5R,6R)-2-((R)-2,2-dimethyl-[1,3]dioxolan-4-ylmethoxy)-3,5-bis-(4-oxo-pentanoyloxy)-6-(4-oxo-pentanoyloxymethyl)-tetrahydro-pyran-4-yl ester

<(4R)-2,2-dimethyl-1,3-dioxolan-4-yl>methyl tetra-O-acetyl-β-D-glucopyranoside

<(4R)-2,2-dimethyl-1,3-dioxolan-4-yl>methyl tetra-O-acetyl-β-D-glucopyranoside

4-Oxo-pentanoic acid (2R,3R,4S,5R,6R)-2-((R)-2,2-dimethyl-[1,3]dioxolan-4-ylmethoxy)-3,5-bis-(4-oxo-pentanoyloxy)-6-(4-oxo-pentanoyloxymethyl)-tetrahydro-pyran-4-yl ester

4-Oxo-pentanoic acid (2R,3R,4S,5R,6R)-2-((R)-2,2-dimethyl-[1,3]dioxolan-4-ylmethoxy)-3,5-bis-(4-oxo-pentanoyloxy)-6-(4-oxo-pentanoyloxymethyl)-tetrahydro-pyran-4-yl ester

上游原料

(2R)-1-O-(2′,3′,4′,6′-tetra-O-acetyl-β-D-glucopyranosyl)glycerol <(4R)-2,2-dimethyl-1,3-dioxolan-4-yl>methyl tetra-O-acetyl-β-D-glucopyranoside

下游产品

3-O-(2,3,4,6-tetra-O-levulinoyl-β-D-glucopyranosyl)-sn-glycerol 3-O-<4,6-O-(tetraisopropyldisiloxane-1,3-diyl)-β-D-glucopyranosyl>-1,2-di-O-oleoyl-sn-glycerol (Z)-Octadec-9-enoic acid (R)-1-((Z)-octadec-9-enoyloxymethyl)-2-[(2R,3R,4S,5R,6R)-3,4,5-tris-(4-oxo-pentanoyloxy)-6-(4-oxo-pentanoyloxymethyl)-tetrahydro-pyran-2-yloxy]-ethyl ester