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1,3-dimethyl-5-<2'-deoxy-5'-O-(tris(1-methylethyl)silyl)-β-D-erythro-pentofuranosyl>-2,4(1H,3H)-pyrimidinedione

1,3-dimethyl-5-<2'-deoxy-5'-O-(tris(1-methylethyl)silyl)-β-D-erythro-pentofuranosyl>-2,4(1H,3H)-pyrimidinedione

CAS号：103003-55-0

英文名：1,3-dimethyl-5-<2'-deoxy-5'-O-(tris(1-methylethyl)silyl)-β-D-erythro-pentofuranosyl>-2,4(1H,3H)-pyrimidinedione

分子式：C20H36N2O5Si

分子量：412.596

合成路线

(2'R)-cis-5-<2',5'-dihydro-4'-((tris(1-methylethyl)silyl)oxy)-5'-(((tris(1-methylethyl)silyl)oxy)methyl)-2'-furanyl>-1,3-dimethyl-2,4(1H,3H)pyrimidinedione

(2'R)-cis-5-<2',5'-dihydro-4'-((tris(1-methylethyl)silyl)oxy)-5'-(((tris(1-methylethyl)silyl)oxy)methyl)-2'-furanyl>-1,3-dimethyl-2,4(1H,3H)pyrimidinedione

1,3-dimethyl-5-<2'-deoxy-5'-O-(tris(1-methylethyl)silyl)-β-D-erythro-pentofuranosyl>-2,4(1H,3H)-pyrimidinedione

1,3-dimethyl-5-<2'-deoxy-5'-O-(tris(1-methylethyl)silyl)-β-D-erythro-pentofuranosyl>-2,4(1H,3H)-pyrimidinedione

(+)-triisopropyl(((2R,3S)-3-((triisopropylsilyl)oxy)-2,3-dihydrofuran-2-yl)methoxy)silane

(+)-triisopropyl(((2R,3S)-3-((triisopropylsilyl)oxy)-2,3-dihydrofuran-2-yl)methoxy)silane

1,3-dimethyl-5-<2'-deoxy-5'-O-(tris(1-methylethyl)silyl)-β-D-erythro-pentofuranosyl>-2,4(1H,3H)-pyrimidinedione

1,3-dimethyl-5-<2'-deoxy-5'-O-(tris(1-methylethyl)silyl)-β-D-erythro-pentofuranosyl>-2,4(1H,3H)-pyrimidinedione

上游原料

(+)-triisopropyl(((2R,3S)-3-((triisopropylsilyl)oxy)-2,3-dihydrofuran-2-yl)methoxy)silane (2'R)-cis-5-<2',5'-dihydro-4'-((tris(1-methylethyl)silyl)oxy)-5'-(((tris(1-methylethyl)silyl)oxy)methyl)-2'-furanyl>-1,3-dimethyl-2,4(1H,3H)pyrimidinedione

下游产品

(1R)-1,4-脱水-2-脱氧-1-(1,3-二甲基-2,4-二氧代-1,2,3,4-四氢-5-嘧啶基)-D-赤式-戊糖醇