百科

{ (4S,5S)-5-[(R)-2-(tert-butyldimethylsilyloxy)propyl]-2,2-dimethyl-1,3-dioxolan-4-yl}methanol

{ (4S,5S)-5-[(R)-2-(tert-butyldimethylsilyloxy)propyl]-2,2-dimethyl-1,3-dioxolan-4-yl}methanol

CAS号：1031354-04-7

英文名：{ (4S,5S)-5-[(R)-2-(tert-butyldimethylsilyloxy)propyl]-2,2-dimethyl-1,3-dioxolan-4-yl}methanol

分子式：C15H32O4Si

分子量：304.498

合成路线

(3S,4S,6R)-6-(tert-butyldimethylsilyloxy)hept-1-ene-3,4-diol

(3S,4S,6R)-6-(tert-butyldimethylsilyloxy)hept-1-ene-3,4-diol

{ (4S,5S)-5-[(R)-2-(tert-butyldimethylsilyloxy)propyl]-2,2-dimethyl-1,3-dioxolan-4-yl}methanol

{ (4S,5S)-5-[(R)-2-(tert-butyldimethylsilyloxy)propyl]-2,2-dimethyl-1,3-dioxolan-4-yl}methanol

tert-butyl-(((R)-1-((4S,5S)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl)-propan-2-yl)oxy)dimethylsilane

tert-butyl-(((R)-1-((4S,5S)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl)-propan-2-yl)oxy)dimethylsilane

{ (4S,5S)-5-[(R)-2-(tert-butyldimethylsilyloxy)propyl]-2,2-dimethyl-1,3-dioxolan-4-yl}methanol

{ (4S,5S)-5-[(R)-2-(tert-butyldimethylsilyloxy)propyl]-2,2-dimethyl-1,3-dioxolan-4-yl}methanol

tert-butyldimethyl(((2R)-1-(oxiran-2-yl)propan-2-yl)oxy)silane

tert-butyldimethyl(((2R)-1-(oxiran-2-yl)propan-2-yl)oxy)silane

{ (4S,5S)-5-[(R)-2-(tert-butyldimethylsilyloxy)propyl]-2,2-dimethyl-1,3-dioxolan-4-yl}methanol

{ (4S,5S)-5-[(R)-2-(tert-butyldimethylsilyloxy)propyl]-2,2-dimethyl-1,3-dioxolan-4-yl}methanol

(3S,5R)-5-((tert-butyldimethylsilyl)oxy)-hex-1-en-3-ol

(3S,5R)-5-((tert-butyldimethylsilyl)oxy)-hex-1-en-3-ol

{ (4S,5S)-5-[(R)-2-(tert-butyldimethylsilyloxy)propyl]-2,2-dimethyl-1,3-dioxolan-4-yl}methanol

{ (4S,5S)-5-[(R)-2-(tert-butyldimethylsilyloxy)propyl]-2,2-dimethyl-1,3-dioxolan-4-yl}methanol

ethyl (4R,5S)-5-[(R)-2-(tert-butyldimethylsilyloxy)propyl]-2,2-dimethyl-1,3-dioxolane-4-carboxylate

ethyl (4R,5S)-5-[(R)-2-(tert-butyldimethylsilyloxy)propyl]-2,2-dimethyl-1,3-dioxolane-4-carboxylate

{ (4S,5S)-5-[(R)-2-(tert-butyldimethylsilyloxy)propyl]-2,2-dimethyl-1,3-dioxolan-4-yl}methanol

{ (4S,5S)-5-[(R)-2-(tert-butyldimethylsilyloxy)propyl]-2,2-dimethyl-1,3-dioxolan-4-yl}methanol

(2R)-1-(oxiran-2-yl)propan-2-ol

(2R)-1-(oxiran-2-yl)propan-2-ol

{ (4S,5S)-5-[(R)-2-(tert-butyldimethylsilyloxy)propyl]-2,2-dimethyl-1,3-dioxolan-4-yl}methanol

{ (4S,5S)-5-[(R)-2-(tert-butyldimethylsilyloxy)propyl]-2,2-dimethyl-1,3-dioxolan-4-yl}methanol

(1S,3R)-3-(tert-butyldimethylsilyloxy)-1-((S)-oxiran-2-yl)butan-1-ol

(1S,3R)-3-(tert-butyldimethylsilyloxy)-1-((S)-oxiran-2-yl)butan-1-ol

{ (4S,5S)-5-[(R)-2-(tert-butyldimethylsilyloxy)propyl]-2,2-dimethyl-1,3-dioxolan-4-yl}methanol

{ (4S,5S)-5-[(R)-2-(tert-butyldimethylsilyloxy)propyl]-2,2-dimethyl-1,3-dioxolan-4-yl}methanol

上游原料

(3S,5R)-5-((tert-butyldimethylsilyl)oxy)-hex-1-en-3-ol (2R)-1-(oxiran-2-yl)propan-2-ol (1S,3R)-3-(tert-butyldimethylsilyloxy)-1-((S)-oxiran-2-yl)butan-1-ol tert-butyl-(((R)-1-((4S,5S)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl)-propan-2-yl)oxy)dimethylsilane tert-butyldimethyl(((2R)-1-(oxiran-2-yl)propan-2-yl)oxy)silane (3S,4S,6R)-6-(tert-butyldimethylsilyloxy)hept-1-ene-3,4-diol ethyl (4R,5S)-5-[(R)-2-(tert-butyldimethylsilyloxy)propyl]-2,2-dimethyl-1,3-dioxolane-4-carboxylate

下游产品

tert-butyl { (R)-1-[(4S,5R)-5-(iodomethyl)-2,2-dimethyl-1,3-dioxolan-4-yl]propan-2yloxy}dimethylsilane