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7-O-(2,2,2-三氯乙氧基羰基)浆果赤霉素 III
CAS号：103150-33-0
英文名：7-{[(2,2,2,-Trichloroethyl)oxy]carbonyl} Baccatin III
分子式：C34H39Cl3O13
分子量：762.025
上游原料
(3aS,5S,9S,10S,13R,13bS)-9-(benzyloxy)-2,2-di-tert-butyl-5-((tert-butyldimethylsilyl)oxy)-6,14,14-trimethyl-5,8,9,10,11,12,13,13b-octahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3,2]dioxasilole-10,13-diol
(3aS,8R,9R,13bS)-9-(benzyloxy)-2,2-di-tert-butyl-6,14,14-trimethyl-8-(phenylthio)-9,11,12,13b-tetrahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3,2]dioxasilol-5(8H)-one
(2S,3aS,3a1S,7S,8aS,11aS,11bR,12R,14aS)-10,10-di-tert-butyl-7-((tert-butyldimethylsilyl)oxy)-6,16,16-trimethyl-2-phenyl-3a,4,7,8,12,13,14,14a-octahydro-11aH-1,3,9,11-tetraoxa-10-sila-3a1,11b:5,8a-dimethanocyclopenta[4,5]cyclodeca[1,2,3-de]naphthalen-12-ol
(5S,6S,11R,12R)-12-(benzyloxy)-5,6-dihydroxy-9,13,13-trimethyl-11-(phenylthio)-3,5,6,7,11,12-hexahydro-6,10-methanobenzo[10]annulen-8(2H)-one
(2S,3aS,5S,9S,9aS,10S,13bS)-6,9a,14,14-tetramethyl-2-phenyl-5,8,9,9a,10,11,12,13b-octahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3]dioxole-5,9,10,13-tetraol
(3aS,3a1S,7S,8aS,10S,11aS,11bS,14aS)-7-((tert-butyldimethylsilyl)oxy)-6,16,16-trimethyl-10-phenyl-3a,4,7,8,14,14a-hexahydro-11aH-1,3,9,11-tetraoxa-3a1,11b:5,8a-dimethanocyclopenta[4,5]cyclodeca[1,2,3-de]naphthalene-2,12(13H)-dione
(3aS,3a<sup>1</sup>S,7S,8aS,10S,11aS,11bR,14aS)-7-hydroxy-3a<sup>1</sup>,6,15,15-tetramethyl-2,10-diphenyl-3a,3a<sup>1</sup>,4,7,8,11a,11b,13,14,14a-decahydro-12H-1,3,9,11-tetraoxa-2-bora-5,8a-methanocyclopenta[4,5]cyclodeca[1,2,3-de]naphthalen-12-one
(2S,3aS,5S,9aS,10S,13aS,13bS)-5-((tert-butyldimethylsilyl)oxy)-10-((2-methoxypropan-2-yl)oxy)-6,9a,14,14-tetramethyl-2-phenyl-13-((trimethylsilyl)methyl)-5,8,10,11,13a,13b-hexahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3]dioxol-9(9aH)-one
(2S,3aS,5S,9aS,10S,13aR,13bS)-5-((tert-butyldimethylsilyl)oxy)-10-hydroxy-6,9a,14,14-tetramethyl-2-phenyl-5,8,9a,10,11,12,13a,13b-octahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3]dioxole-9,13-dione
(3aS,5S,9S,9aS,10S,13aS,13bS)-2,2-di-tert-butyl-5-((tert-butyldimethylsilyl)oxy)-9,10-dihydroxy-6,15,15-trimethyl-4,5,8,9,11,12-hexahydro-13bH-3a,7:9a,13a-dimethanobenzo[3,4]cyclodeca[1,2-d][1,3,2]dioxasilol-13(10H)-one
(2S,3aS,3a1S,7S,8aS,11aS,11bS,14aS)-10,10-di-tert-butyl-7-((tert-butyldimethylsilyl)oxy)-6,16,16-trimethyl-2-phenyl-3a,4,7,8,14,14a-hexahydro-11aH-1,3,9,11-tetraoxa-10-sila-3a1,11b:5,8a-dimethanocyclopenta[4,5]cyclodeca[1,2,3-de]naphthalen-12(13H)-one
氯甲酸-2,2,2-三氯乙酯
((2S,3aS,3a1R,7S,8aS,10S,11aS,14aS)-7,12-bis((tert-butyldimethylsilyl)oxy)-2-(4-methoxyphenyl)-6,15,15-trimethyl-10-phenyl-3a,4,7,8,11a,13,14,14a-octahydro-3a1H-1,3,9,11-tetraoxa-5,8a-methanocyclopenta[4,5]cyclodeca[1,2,3-de]naphthalen-3a1-yl)methanol
10-脱乙酰基巴卡丁 III
(3aS,3a1S,6aS,7S,8S,10S,13aS)-10-((tert-butyldimethylsilyl)oxy)-7,8-dihydroxy-11,14,14-trimethyl-4,5,7,8,9,10,13,13a-octahydro-1,3-dioxa-3a1,6a:8,12-dimethanocyclodeca[de]naphthalene-2,6(3aH)-dione
7-O-(三乙基硅烷基)-10-去乙酰基浆果赤霉素III
(3aS,7S,8aS,11aS,12R,14aS)-10,10-di-tert-butyl-7-((tert-butyldimethylsilyl)oxy)-6,15,15-trimethyl-2-phenyl-3a,7,8,11a,12,13,14,14a-octahydro-4H-1,3,9,11-tetraoxa-10-sila-5,8a-methanocyclopenta[4,5]cyclodeca[1,2,3-de]naphthalen-12-ol
(3aS,5S,8R,9R,10S,13R,13bS)-9-(benzyloxy)-2,2-di-tert-butyl-5-((tert-butyldimethylsilyl)oxy)-6,16,16-trimethyl-8-(phenylthio)-5,8,9,10,11,12,13,13b-octahydro-4H-10,13-epidioxy-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3,2]dioxasilole
巴卡丁 III
(3aS,5S,9S,10S,13R,13bS)-2,2-di-tert-butyl-5-((tert-butyldimethylsilyl)oxy)-6,14,14-trimethyl-5,8,9,10,11,12,13,13b-octahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3,2]dioxasilole-9,10,13-triol
(3aS,5S,8R,9R,13bS)-9-(benzyloxy)-2,2-di-tert-butyl-5-((tert-butyldimethylsilyl)oxy)-6,14,14-trimethyl-8-(phenylthio)-5,8,9,11,12,13b-hexahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3,2]dioxasilole
(2aR,4S,4aS,6R,9S,11S,12S,12aR,12bS)-9-((tert-butyldimethylsilyl)oxy)-11,12,12b-trihydroxy-4a,8,13,13-tetramethyl-5-oxo-4-((triethylsilyl)oxy)-2a,3,4,4a,5,6,9,10,11,12,12a,12b-dodecahydro-1H-7,11-methanocyclodeca[3,4]benzo[1,2-b]oxet-6-yl acetate
(2S,3aS,5S,9S,9aS,10S,13aS,13bS)-5-((tert-butyldimethylsilyl)oxy)-9,10-dihydroxy-6,15,15-trimethyl-2-phenyl-4,5,8,9,11,12-hexahydro-13bH-3a,7:9a,13a-dimethanobenzo[3,4]cyclodeca[1,2-d][1,3]dioxol-13(10H)-one
(3aS,5S,8R,9R,13bS)-9-(benzyloxy)-2,2-di-tert-butyl-6,14,14-trimethyl-8-(phenylthio)-5,8,9,11,12,13b-hexahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3,2]dioxasilol-5-ol
(2S,3aS,5S,9S,9aS,10S,13aR,13bS)-5,9,10-trihydroxy-6,9a,14,14-tetramethyl-2-phenyl-4,5,8,9,9a,10,11,12,13a,13b-decahydro-13H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3]dioxol-13-one
(2S,3aS,5S,9aS,10S,13aR,13bS)-5-((tert-butyldimethylsilyl)oxy)-10-((2-methoxypropan-2-yl)oxy)-6,9a,14,14-tetramethyl-9-oxo-2-phenyl-5,8,9,9a,10,11,13a,13b-octahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3]dioxol-13-yl trifluoromethanesulfonate
(S)-1-((S)-(6-(bis(benzyloxy)methyl)cyclohexa-1,5-dien-1-yl)(hydroxy)methyl)-4,6,6-trimethyl-5-((phenylthio)methylene)-3-((triisopropylsilyl)oxy)cyclohex-3-en-1-ol
(S)-1-Hydroxy-4,6,6-trimethyl-5-[1-phenylsulfanyl-meth-(E)-ylidene]-3-triisopropylsilanyloxy-cyclohex-3-enecarbaldehyde
(2S,3aS,5S,9S,9aS,10S,13bS)-5-((tert-butyldimethylsilyl)oxy)-6,9a,14,14-tetramethyl-2-phenyl-5,8,9,9a,10,11,12,13b-octahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3]dioxole-9,10,13-triol
(3aS,3a1S,7S,8aS,10S,11aS,11bR,14aS)-7-((tert-butyldimethylsilyl)oxy)-3a1,6,15,15-tetramethyl-2,10-diphenyl-3a,3a1,4,7,8,11a,11b,13,14,14a-decahydro-12H-1,3,9,11-tetraoxa-2-bora-5,8a-methanocyclopenta[4,5]cyclodeca[1,2,3-de]naphthalen-12-one
(2S,3aS,5S,9aS,10S,12S,13aS,13bS)-5-((tert-butyldimethylsilyl)oxy)-12-chloro-10-((2-methoxypropan-2-yl)oxy)-6,9a,14,14-tetramethyl-13-methylene-2-phenyl-5,8,10,11,12,13,13a,13b-octahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3]dioxol-9(9aH)-one
(2S,3aS,5S,9aS,10S,13aR,13bS)-5-((tert-butyldimethylsilyl)oxy)-10-((2-methoxypropan-2-yl)oxy)-6,9a,14,14-tetramethyl-2-phenyl-5,8,9a,10,11,12,13a,13b-octahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3]dioxole-9,13-dione
(3aS,3a1S,7S,8aS,11aS,11bS,14aS)-10,10-di-tert-butyl-7-((tert-butyldimethylsilyl)oxy)-6,16,16-trimethyl-3a,4,7,8,14,14a-hexahydro-11aH-1,3,9,11-tetraoxa-10-sila-3a1,11b:5,8a-dimethanocyclopenta[4,5]cyclodeca[1,2,3-de]naphthalene-2,12(13H)-dione
(2aR,4S,4aS,6R,9S,11S,12S,12aR,12bS)-12-(benzoyloxy)-9-((tert-butyldimethylsilyl)oxy)-4,11-dihydroxy-4a,8,13,13-tetramethyl-5-oxo-3,4,4a,5,6,9,10,11,12,12a-decahydro-1H-7,11-methanocyclodeca[3,4]benzo[1,2-b]oxete-6,12b(2aH)-diyl diacetate
