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5(S)-<<(tert-butyldiphenylsilyl)oxy>methyl>-4(S)-methyldihydro-2-furanone

5(S)-<<(tert-butyldiphenylsilyl)oxy>methyl>-4(S)-methyldihydro-2-furanone

CAS号：103233-14-3

英文名：5(S)-<<(tert-butyldiphenylsilyl)oxy>methyl>-4(S)-methyldihydro-2-furanone

分子式：C23H28O3

分子量：352.467

合成路线

3-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-butyric acid ethyl ester

3-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-butyric acid ethyl ester

5(S)-<<(tert-butyldiphenylsilyl)oxy>methyl>-4(S)-methyldihydro-2-furanone

5(S)-<<(tert-butyldiphenylsilyl)oxy>methyl>-4(S)-methyldihydro-2-furanone

(E)-(S)-4,5-Dihydroxy-pent-2-enoic acid methyl ester

(E)-(S)-4,5-Dihydroxy-pent-2-enoic acid methyl ester

5(S)-<<(tert-butyldiphenylsilyl)oxy>methyl>-4(S)-methyldihydro-2-furanone

5(S)-<<(tert-butyldiphenylsilyl)oxy>methyl>-4(S)-methyldihydro-2-furanone

5-O-(tert-butyldiphenylsilyl)-3-deoxy-2-Se-phenyl-2-seleno-D-erythro-pentonic acid γ-lactone

5-O-(tert-butyldiphenylsilyl)-3-deoxy-2-Se-phenyl-2-seleno-D-erythro-pentonic acid γ-lactone

5(S)-<<(tert-butyldiphenylsilyl)oxy>methyl>-4(S)-methyldihydro-2-furanone

5(S)-<<(tert-butyldiphenylsilyl)oxy>methyl>-4(S)-methyldihydro-2-furanone

上游原料

5-O-(tert-butyldiphenylsilyl)-3-deoxy-2-Se-phenyl-2-seleno-D-erythro-pentonic acid γ-lactone 3-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-butyric acid ethyl ester (E)-(S)-4,5-Dihydroxy-pent-2-enoic acid methyl ester

下游产品

(4R,5R)-5-Bromomethyl-4-methyl-dihydro-furan-2-one 2,3-dideoxy-3-C-methyl-5-O-tert-butyldiphenylsilyl-D-glycero-pent-2-eno-1,4-lactone 2,3-dideoxy-3-C-methyl-5-O-tert-butyldiphenylsilyl-D-threo-pentono-1,4-lactone 1-<3-C-methyl-5-O-(tert-butyldiphenylsilyl)-2,3-dideoxy-α-D-erythro-pentofuranosyl>thymine (2S,3S)-1-(tert-Butyl-diphenyl-silanyloxy)-3-methyl-5-trityloxy-pentan-2-ol (3S,4S,5S)-1-(tert-Butyl-diphenyl-silanyloxy)-3,5-dimethyl-7-trityloxy-heptan-4-ol (2R,3R,4S)-5-[(tert-butyldiphenylsilyl)oxy]-2-hydroxy-3-methyl-4-pentanolide 1-<3-C-methyl-5-O-(tert-butyldiphenylsilyl)-2,3-dideoxy-β-D-erythro-pentofuranosyl>thymine