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<1R*-<1β,3β(1S*),4α,5β,8α>>-1,4,8-trimethyl-3-(1-methyl-2-butynyl)-6-((trimethylsylil)oxy)-2,9-dioxabicyclo<3.3.1>non-6-ene

<1R-<1β,3β(1S),4α,5β,8α>>-1,4,8-trimethyl-3-(1-methyl-2-butynyl)-6-((trimethylsylil)oxy)-2,9-dioxabicyclo<3.3.1>non-6-ene

CAS号：103368-32-7

英文名：<1R*-<1β,3β(1S*),4α,5β,8α>>-1,4,8-trimethyl-3-(1-methyl-2-butynyl)-6-((trimethylsylil)oxy)-2,9-dioxabicyclo<3.3.1>non-6-ene

分子式：C18H30O3Si

分子量：322.515

合成路线

<1R*-<1α,3α(1S*),4β,5α,6α,8β>>-6-hydroxy-3-(1-methylbut-2-ynyl)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonane

<1R*-<1α,3α(1S*),4β,5α,6α,8β>>-6-hydroxy-3-(1-methylbut-2-ynyl)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonane

<1R*-<1β,3β(1S*),4α,5β,8α>>-1,4,8-trimethyl-3-(1-methyl-2-butynyl)-6-((trimethylsylil)oxy)-2,9-dioxabicyclo<3.3.1>non-6-ene

<1R*-<1β,3β(1S*),4α,5β,8α>>-1,4,8-trimethyl-3-(1-methyl-2-butynyl)-6-((trimethylsylil)oxy)-2,9-dioxabicyclo<3.3.1>non-6-ene

<2R*-<2α(1S*,2S*,3S*),5β,6β>>-5,6-dimethyl-6-methoxy-3-oxo-2-(acetoxy-1,3-dimethylhex-4-ynyl)tetrahydro-2H-pyran

<2R*-<2α(1S*,2S*,3S*),5β,6β>>-5,6-dimethyl-6-methoxy-3-oxo-2-(acetoxy-1,3-dimethylhex-4-ynyl)tetrahydro-2H-pyran

<1R*-<1β,3β(1S*),4α,5β,8α>>-1,4,8-trimethyl-3-(1-methyl-2-butynyl)-6-((trimethylsylil)oxy)-2,9-dioxabicyclo<3.3.1>non-6-ene

<1R*-<1β,3β(1S*),4α,5β,8α>>-1,4,8-trimethyl-3-(1-methyl-2-butynyl)-6-((trimethylsylil)oxy)-2,9-dioxabicyclo<3.3.1>non-6-ene

(2S,3S,5S,6R)-2-((1R,2R,3R)-2-Hydroxy-1,3-dimethyl-hex-4-ynyl)-6-methoxy-5,6-dimethyl-tetrahydro-pyran-3-ol

(2S,3S,5S,6R)-2-((1R,2R,3R)-2-Hydroxy-1,3-dimethyl-hex-4-ynyl)-6-methoxy-5,6-dimethyl-tetrahydro-pyran-3-ol

<1R*-<1β,3β(1S*),4α,5β,8α>>-1,4,8-trimethyl-3-(1-methyl-2-butynyl)-6-((trimethylsylil)oxy)-2,9-dioxabicyclo<3.3.1>non-6-ene

<1R*-<1β,3β(1S*),4α,5β,8α>>-1,4,8-trimethyl-3-(1-methyl-2-butynyl)-6-((trimethylsylil)oxy)-2,9-dioxabicyclo<3.3.1>non-6-ene

<2R*-<2α(1S*,2S*,3S*),3β,5β,6β>>-5,6-dimethyl-3-hydroxy-6-methoxy-2-(1,3-dimethyl-2-hydroxyhex-4-ynyl)tetrahydro-2H-pyran

<2R*-<2α(1S*,2S*,3S*),3β,5β,6β>>-5,6-dimethyl-3-hydroxy-6-methoxy-2-(1,3-dimethyl-2-hydroxyhex-4-ynyl)tetrahydro-2H-pyran

<1R*-<1β,3β(1S*),4α,5β,8α>>-1,4,8-trimethyl-3-(1-methyl-2-butynyl)-6-((trimethylsylil)oxy)-2,9-dioxabicyclo<3.3.1>non-6-ene

<1R*-<1β,3β(1S*),4α,5β,8α>>-1,4,8-trimethyl-3-(1-methyl-2-butynyl)-6-((trimethylsylil)oxy)-2,9-dioxabicyclo<3.3.1>non-6-ene

上游原料

(2S,3S,5S,6R)-2-((1R,2R,3R)-2-Hydroxy-1,3-dimethyl-hex-4-ynyl)-6-methoxy-5,6-dimethyl-tetrahydro-pyran-3-ol <2R*-<2α(1S*,2S*,3S*),3β,5β,6β>>-5,6-dimethyl-3-hydroxy-6-methoxy-2-(1,3-dimethyl-2-hydroxyhex-4-ynyl)tetrahydro-2H-pyran <2R*-<2α(1S*,2S*,3S*),5β,6β>>-5,6-dimethyl-6-methoxy-3-oxo-2-(acetoxy-1,3-dimethylhex-4-ynyl)tetrahydro-2H-pyran <1R*-<1α,3α(1S*),4β,5α,6α,8β>>-6-hydroxy-3-(1-methylbut-2-ynyl)-1,4,8-trimethyl-2,9-dioxabicyclo<3.3.1>nonane

下游产品

<1R*-<1β,3β(1S*),4α,5β>>-1,4,8-trimethyl-3-(1-methyl-2-butynyl)-6-oxo-2,9-dioxabicyclo<3.3.1>non-7-ene