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<3R*-<3α(1RS),4β,5α(1S*)>>-3-(1-ethoxyethoxy)-4-methyl-5-(1-methylbut-2-ynyl)dihydrofuran-2(3H)-one

<3R-<3α(1RS),4β,5α(1S)>>-3-(1-ethoxyethoxy)-4-methyl-5-(1-methylbut-2-ynyl)dihydrofuran-2(3H)-one

CAS号：103368-39-4

英文名：<3R*-<3α(1RS),4β,5α(1S*)>>-3-(1-ethoxyethoxy)-4-methyl-5-(1-methylbut-2-ynyl)dihydrofuran-2(3H)-one

分子式：C14H22O4

分子量：254.322

合成路线

(2R*,3R*,4R*,5S*)-methyl 4,5-epoxy-2-hydroxy-3-methylhexanoate

(2R*,3R*,4R*,5S*)-methyl 4,5-epoxy-2-hydroxy-3-methylhexanoate

<3R*-<3α(1RS),4β,5α(1S*)>>-3-(1-ethoxyethoxy)-4-methyl-5-(1-methylbut-2-ynyl)dihydrofuran-2(3H)-one

<3R*-<3α(1RS),4β,5α(1S*)>>-3-(1-ethoxyethoxy)-4-methyl-5-(1-methylbut-2-ynyl)dihydrofuran-2(3H)-one

<2R*,3S*,4Z>-2-hydroxy-3-methyl-4-hexenoic acid

<2R*,3S*,4Z>-2-hydroxy-3-methyl-4-hexenoic acid

<3R*-<3α(1RS),4β,5α(1S*)>>-3-(1-ethoxyethoxy)-4-methyl-5-(1-methylbut-2-ynyl)dihydrofuran-2(3H)-one

<3R*-<3α(1RS),4β,5α(1S*)>>-3-(1-ethoxyethoxy)-4-methyl-5-(1-methylbut-2-ynyl)dihydrofuran-2(3H)-one

<3R*,4R*,5S*(1S*)>-3-hydroxy-4-methyl-5-(1-iodoethyl)dihydro-2-(3H)-furanone

<3R*,4R*,5S*(1S*)>-3-hydroxy-4-methyl-5-(1-iodoethyl)dihydro-2-(3H)-furanone

<3R*-<3α(1RS),4β,5α(1S*)>>-3-(1-ethoxyethoxy)-4-methyl-5-(1-methylbut-2-ynyl)dihydrofuran-2(3H)-one

<3R*-<3α(1RS),4β,5α(1S*)>>-3-(1-ethoxyethoxy)-4-methyl-5-(1-methylbut-2-ynyl)dihydrofuran-2(3H)-one

<5R*-<1S*,2R*,3S*>>-2,2-bis(trifluoromethyl)-5-(2,3-epoxy-1-methylbutyl)-1,3-dioxolan-4-one

<5R*-<1S*,2R*,3S*>>-2,2-bis(trifluoromethyl)-5-(2,3-epoxy-1-methylbutyl)-1,3-dioxolan-4-one

<3R*-<3α(1RS),4β,5α(1S*)>>-3-(1-ethoxyethoxy)-4-methyl-5-(1-methylbut-2-ynyl)dihydrofuran-2(3H)-one

<3R*-<3α(1RS),4β,5α(1S*)>>-3-(1-ethoxyethoxy)-4-methyl-5-(1-methylbut-2-ynyl)dihydrofuran-2(3H)-one

上游原料

<3R*,4R*,5S*(1S*)>-3-hydroxy-4-methyl-5-(1-iodoethyl)dihydro-2-(3H)-furanone <2R*,3S*,4Z>-2-hydroxy-3-methyl-4-hexenoic acid <5R*-<1S*,2R*,3S*>>-2,2-bis(trifluoromethyl)-5-(2,3-epoxy-1-methylbutyl)-1,3-dioxolan-4-one (2R*,3R*,4R*,5S*)-methyl 4,5-epoxy-2-hydroxy-3-methylhexanoate

下游产品

(2S,3S,5S,6R)-2-((1R,2R,3R)-2-Hydroxy-1,3-dimethyl-hex-4-ynyl)-6-methoxy-5,6-dimethyl-tetrahydro-pyran-3-ol <2R*-<2α(1S*,2S*,3S*),3β,5β,6β>>-5,6-dimethyl-3-hydroxy-6-methoxy-2-(1,3-dimethyl-2-hydroxyhex-4-ynyl)tetrahydro-2H-pyran <2R*-<2α(1S*,2S*,3S*),5β,6β>>-5,6-dimethyl-6-methoxy-3-oxo-2-(acetoxy-1,3-dimethylhex-4-ynyl)tetrahydro-2H-pyran <2R*-<2α(1S*,2S*,3S*),5α,6β>>-5,6-dimethyl-6-methoxy-3-oxo-2-(acetoxy-1,3-dimethylhex-4-ynyl)tetrahydro-2H-pyran (3R,4S,5S)-3-(1-Ethoxy-ethoxy)-4-methyl-5-((S)-1-methyl-but-2-ynyl)-2-[2-(2-methyl-[1,3]dioxolan-2-yl)-propyl]-tetrahydro-furan-2-ol <2R*-<2α,6β(1R*,2R*,3R*)>>-2,3-dimethyl-6-(2-acetoxy-1,3-dimethylhex-4-ynyl)-2-methoxy-5,6-dihydro-2H-pyran-5-one <2R*-<2α(1S*,2S*,3S*),5β,6β>>-5,6-dimethyl-6-methoxy-3-((trimethylsilyl)oxy)-2-(2-acetoxy-1,3-dimethylhex-4-ynyl)-5,6-dihydro-2H-pyran <3RS,6R*-(1RS)-7S*,8S*,9S*>-8-acetoxy-6-(1-ethoxyethoxy)-2,2-(ethylenedioxy)-3,7,9-trimethyldodec-10-yn-5-one <6R*-(1S*,2S*,3S*)>-6-(2-acetoxy-1,3-dimethylhex-4-ynyl)-3-methyl-2-methylene-5,6-dihydro-2H-pyran-5-one