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(2E,4E)-(S)-4-Methyl-6-((3aR,5S,6S,6aR)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-hepta-2,4-dienoyl chloride

(2E,4E)-(S)-4-Methyl-6-((3aR,5S,6S,6aR)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-hepta-2,4-dienoyl chloride

CAS号：103368-63-4

英文名：(2E,4E)-(S)-4-Methyl-6-((3aR,5S,6S,6aR)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-hepta-2,4-dienoyl chloride

分子式：C16H23ClO4

分子量：314.804

合成路线

(2R*,3R*,4R*,5S*)-methyl 4,5-epoxy-2-hydroxy-3-methylhexanoate

(2R*,3R*,4R*,5S*)-methyl 4,5-epoxy-2-hydroxy-3-methylhexanoate

(2E,4E)-(S)-4-Methyl-6-((3aR,5S,6S,6aR)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-hepta-2,4-dienoyl chloride

(2E,4E)-(S)-4-Methyl-6-((3aR,5S,6S,6aR)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-hepta-2,4-dienoyl chloride

(2E,4E)-(S)-4-Methyl-6-((3aR,5S,6S,6aR)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-hepta-2,4-dienoic acid

(2E,4E)-(S)-4-Methyl-6-((3aR,5S,6S,6aR)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-hepta-2,4-dienoic acid

(2E,4E)-(S)-4-Methyl-6-((3aR,5S,6S,6aR)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-hepta-2,4-dienoyl chloride

(2E,4E)-(S)-4-Methyl-6-((3aR,5S,6S,6aR)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-hepta-2,4-dienoyl chloride

(3aR,5S,6S,6aR)-2,2,6-Trimethyl-5-((S)-1-methyl-but-2-ynyl)-tetrahydro-furo[2,3-d][1,3]dioxole

(3aR,5S,6S,6aR)-2,2,6-Trimethyl-5-((S)-1-methyl-but-2-ynyl)-tetrahydro-furo[2,3-d][1,3]dioxole

(2E,4E)-(S)-4-Methyl-6-((3aR,5S,6S,6aR)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-hepta-2,4-dienoyl chloride

(2E,4E)-(S)-4-Methyl-6-((3aR,5S,6S,6aR)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-hepta-2,4-dienoyl chloride

<3R*,4R*,5S*(1S*)>-3-hydroxy-4-methyl-5-(1-iodoethyl)dihydro-2-(3H)-furanone

<3R*,4R*,5S*(1S*)>-3-hydroxy-4-methyl-5-(1-iodoethyl)dihydro-2-(3H)-furanone

(2E,4E)-(S)-4-Methyl-6-((3aR,5S,6S,6aR)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-hepta-2,4-dienoyl chloride

(2E,4E)-(S)-4-Methyl-6-((3aR,5S,6S,6aR)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-hepta-2,4-dienoyl chloride

<5R*-<1S*,2R*,3S*>>-2,2-bis(trifluoromethyl)-5-(2,3-epoxy-1-methylbutyl)-1,3-dioxolan-4-one

<5R*-<1S*,2R*,3S*>>-2,2-bis(trifluoromethyl)-5-(2,3-epoxy-1-methylbutyl)-1,3-dioxolan-4-one

(2E,4E)-(S)-4-Methyl-6-((3aR,5S,6S,6aR)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-hepta-2,4-dienoyl chloride

(2E,4E)-(S)-4-Methyl-6-((3aR,5S,6S,6aR)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-hepta-2,4-dienoyl chloride

<2R*,3S*,4Z>-2-hydroxy-3-methyl-4-hexenoic acid

<2R*,3S*,4Z>-2-hydroxy-3-methyl-4-hexenoic acid

(2E,4E)-(S)-4-Methyl-6-((3aR,5S,6S,6aR)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-hepta-2,4-dienoyl chloride

(2E,4E)-(S)-4-Methyl-6-((3aR,5S,6S,6aR)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-hepta-2,4-dienoyl chloride

(3aR,5S,6S,6aR)-5-((E)-(S)-3-Bromo-1-methyl-but-2-enyl)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxole

(3aR,5S,6S,6aR)-5-((E)-(S)-3-Bromo-1-methyl-but-2-enyl)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxole

(2E,4E)-(S)-4-Methyl-6-((3aR,5S,6S,6aR)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-hepta-2,4-dienoyl chloride

(2E,4E)-(S)-4-Methyl-6-((3aR,5S,6S,6aR)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-hepta-2,4-dienoyl chloride

<3R*-<3α,4β,5α(1S*)>>-3-hydroxy-4-methyl-5-(1-methyl-2-butynyl)-dihydrofuran-2(3H)-one

<3R*-<3α,4β,5α(1S*)>>-3-hydroxy-4-methyl-5-(1-methyl-2-butynyl)-dihydrofuran-2(3H)-one

(2E,4E)-(S)-4-Methyl-6-((3aR,5S,6S,6aR)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-hepta-2,4-dienoyl chloride

(2E,4E)-(S)-4-Methyl-6-((3aR,5S,6S,6aR)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-hepta-2,4-dienoyl chloride

103421-42-7

(2E,4E)-(S)-4-Methyl-6-((3aR,5S,6S,6aR)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-hepta-2,4-dienoyl chloride

(2E,4E)-(S)-4-Methyl-6-((3aR,5S,6S,6aR)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-hepta-2,4-dienoyl chloride

103421-43-8

(2E,4E)-(S)-4-Methyl-6-((3aR,5S,6S,6aR)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-hepta-2,4-dienoyl chloride

(2E,4E)-(S)-4-Methyl-6-((3aR,5S,6S,6aR)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-hepta-2,4-dienoyl chloride

上游原料

(2E,4E)-(S)-4-Methyl-6-((3aR,5S,6S,6aR)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-hepta-2,4-dienoic acid <3R*,4R*,5S*(1S*)>-3-hydroxy-4-methyl-5-(1-iodoethyl)dihydro-2-(3H)-furanone <2R*,3S*,4Z>-2-hydroxy-3-methyl-4-hexenoic acid (3aR,5S,6S,6aR)-5-((E)-(S)-3-Bromo-1-methyl-but-2-enyl)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxole (3aR,5S,6S,6aR)-2,2,6-Trimethyl-5-((S)-1-methyl-but-2-ynyl)-tetrahydro-furo[2,3-d][1,3]dioxole <5R*-<1S*,2R*,3S*>>-2,2-bis(trifluoromethyl)-5-(2,3-epoxy-1-methylbutyl)-1,3-dioxolan-4-one (2R*,3R*,4R*,5S*)-methyl 4,5-epoxy-2-hydroxy-3-methylhexanoate <3R*-<3α,4β,5α(1S*)>>-3-hydroxy-4-methyl-5-(1-methyl-2-butynyl)-dihydrofuran-2(3H)-one

下游产品

{(2,4-Dimethoxy-benzyl)-[(4E,6E)-(S)-6-methyl-3-oxo-8-((3aR,5S,6S,6aR)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-nona-4,6-dienoyl]-amino}-acetic acid ethyl ester 1-(2,4-Dimethoxy-benzyl)-3-[(2E,4E)-(S)-1-hydroxy-4-methyl-6-((3aR,5S,6S,6aR)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-hepta-2,4-dien-(Z)-ylidene]-pyrrolidine-2,4-dione