上游原料
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(1R*(1Z),2R*,3R*,4R*,5R*,6S*)-4,6-bis((tert-butyldimethylsilyl)oxy)-1-(3,3-dimethoxy-2-methyl-1-butenyl)-3,5-dimethylcyclohexan-1,2-diol
CAS号：103383-26-2
英文名：(1R*(1Z),2R*,3R*,4R*,5R*,6S*)-4,6-bis((tert-butyldimethylsilyl)oxy)-1-(3,3-dimethoxy-2-methyl-1-butenyl)-3,5-dimethylcyclohexan-1,2-diol
分子式：C27H56O6Si2
分子量：532.901
上游原料
(Z)-tributyl(3,3-dimethoxy-2-methyl-1-butenyl)stannane
(3R*,4R*,5R*,6S*)-<(3,5-dimethyl-4,6-bis((tert-butyldimethylsilyl)oxy)-1-cyclohexenyl)oxy>trimethylsilane
(1R*,2R*,3S*,5R*,6S*)-tert-butyldimethyl<(3-((tert-butyldimethylsilyl)oxy)-2,6-dimethyl-5-((trimethylsilyl)oxy)-4-oxo-1-cyclohexyl)oxy>silane
(3R*,4S*,5S*)-<(3,5-dimethyl-4-((tert-butyldimethylsilysl)oxy)-1-cyclohexenyl)oxy>trimethylsilane
(1R*,2S*,3S*,5R*,6R*)-tert-butyldimethyl<(3-((tert-butyldimethylsilyl)oxy)-2,6-dimethyl-5-hydroxy-4-oxo-1-cyclohexyl)oxy>silane
(7R,8s,9S)-tert-butyldimethyl<(7,9-dimethyl-1,4-dioxaspiro<4.5>decan-8-oyl)oxy>silane
(Z)-1-bromo-3,3-dimethoxy-2-methyl-1-butene
(7α,8α,9α)-7,9-dimethyl-1,4-dioxaspiro[4.5]decan-8-ol
(1R*(1Z),2S*,3R*,4R*,5S*,6R*)-2,4-bis((tert-butyldimethylsilyl)oxy)-1-(3,3-dimethoxy-2-methyl-1-butenyl)-3,5-dimethyl-6-((trimethylsilyl)oxy)cyclohexan-1-ol
(1s,2R,6S)-tert-butyldimethyl<(2,6-dimethyl-4-oxo-1-cyclohexyl)oxy>silane
(1R*,2S*,3S*,6R*)-tert-butyldimethyl<(2,6-dimethyl-3-hydroxy-4-oxocyclohexyl)oxy>silane
(1R*,2R*,3S*,6R*)-tert-butyldimethyl<(3-((tert-butyldimethylsilyl)oxy)-2,6-dimethyl-4-oxo-1-cyclohexyl)oxy>silane
下游产品
(2E*,4R*,5R*,6R*,7S*,9Z)-5,7-bis((tert-butyldimethylsilyl)oxy)-11,11-dimethoxy-2,4,6,10-tetramethyl-8-oxo-2,9-dodecadienyl acetate
(2R*,3R*,4S*,5R*,7Z)-3,5-bis((tert-butyldimethylsilyl)oxy)-9,9-dimethoxy-2,4,8-trimethyl-6-oxo-7-decenal
<1R*-<1β,2α,4α,6β,7α,8β(1E,2E,4E,6R*)>>-1-(2,4-dimethoxybenzyl)-3-<1-hydroxy-4-methyl-6-(1,2,7-trimethyl-5-oxo-3,9,10-trioxatricyclo<4.3.1.0(2,4)>dec-8-yl)-2,4-heptadienylidene>-2,4-pyrrolidinedione
(2E*,4R*,5R*,6R*,7S*,9Z)-5,7-bis((tert-butyldimethylsilyl)oxy)-11,11-dimethoxy-2,4,6,10-tetramethyl-8-oxo-2,9-dodecadienal
<4R*(1S*,2S*,4R*,6S*,7R*,8R*),2E>-2-methyl-4-(1,2,7-trimethyl-5-oxo-3,9,10-trioxatricyclo<4.3.1.0(2,4)>dec-8-yl)-2-pentenal
(2E*,4R*,5R*,6R*,7S*,9Z)-5,7-bis((tert-butyldimethylsilyl)oxy)-11,11-dimethoxy-2,4,6,10-tetramethyl-8-oxo-2,9-dodecadienol
Acetic acid (2E,9Z)-(4S,5S,6S,7R)-5,7-dihydroxy-11,11-dimethoxy-2,4,6,10-tetramethyl-8-oxo-dodeca-2,9-dienyl ester
(+/-)-tirandamycin A
<4R*(1S*,5S*,6R*,7R*),2E>-2-methyl-4-(1,2,6-trimethyl-4-oxo-8,9-dioxabicyclo<3.3.1>non-2-en-7-yl)-2-penten-1-yl acetate
(1R,2R,4S,6R,7S,8S)-8-((E)-(S)-4-Hydroxy-1,3-dimethyl-but-2-enyl)-1,2,7-trimethyl-3,9,10-trioxa-tricyclo[4.3.1.02,4]decan-5-one
<4R*(1S*,2S*,4R*,6S*,7R*,8R*),2E>-2-methyl-4-(1,2,7-trimethyl-5-oxo-3,9,10-trioxatricyclo<4.3.1.0(2,4)>dec-8-yl)-2-penten-1-yl acetate
