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(5R,6R)-5,6-Diacetoxy-7-[(R)-4-chloro-2-((Z)-oct-2-enyl)-5-oxo-2-trimethylsilanyloxy-cyclopent-3-enyl]-7-hydroxy-heptanoic acid methyl ester

(5R,6R)-5,6-Diacetoxy-7-[(R)-4-chloro-2-((Z)-oct-2-enyl)-5-oxo-2-trimethylsilanyloxy-cyclopent-3-enyl]-7-hydroxy-heptanoic acid methyl ester

CAS号：103384-61-8

英文名：(5R,6R)-5,6-Diacetoxy-7-[(R)-4-chloro-2-((Z)-oct-2-enyl)-5-oxo-2-trimethylsilanyloxy-cyclopent-3-enyl]-7-hydroxy-heptanoic acid methyl ester

分子式：C28H45ClO9Si

分子量：589.19

合成路线

(R)-2-Chloro-4-hydroxy-4-((Z)-oct-2-enyl)-cyclopent-2-enone

(R)-2-Chloro-4-hydroxy-4-((Z)-oct-2-enyl)-cyclopent-2-enone

(5R,6R)-5,6-Diacetoxy-7-[(R)-4-chloro-2-((Z)-oct-2-enyl)-5-oxo-2-trimethylsilanyloxy-cyclopent-3-enyl]-7-hydroxy-heptanoic acid methyl ester

(5R,6R)-5,6-Diacetoxy-7-[(R)-4-chloro-2-((Z)-oct-2-enyl)-5-oxo-2-trimethylsilanyloxy-cyclopent-3-enyl]-7-hydroxy-heptanoic acid methyl ester

(1R,4S)-4-(tert-Butyl-dimethyl-silanyloxy)-3-chloro-1-oct-2-ynyl-cyclopent-2-enol

(1R,4S)-4-(tert-Butyl-dimethyl-silanyloxy)-3-chloro-1-oct-2-ynyl-cyclopent-2-enol

(5R,6R)-5,6-Diacetoxy-7-[(R)-4-chloro-2-((Z)-oct-2-enyl)-5-oxo-2-trimethylsilanyloxy-cyclopent-3-enyl]-7-hydroxy-heptanoic acid methyl ester

(5R,6R)-5,6-Diacetoxy-7-[(R)-4-chloro-2-((Z)-oct-2-enyl)-5-oxo-2-trimethylsilanyloxy-cyclopent-3-enyl]-7-hydroxy-heptanoic acid methyl ester

(R)-2-Chloro-4-((Z)-oct-2-enyl)-4-trimethylsilanyloxy-cyclopent-2-enone

(R)-2-Chloro-4-((Z)-oct-2-enyl)-4-trimethylsilanyloxy-cyclopent-2-enone

(5R,6S)-5,6-Diacetoxy-7-oxo-heptanoic acid methyl ester

(5R,6S)-5,6-Diacetoxy-7-oxo-heptanoic acid methyl ester

(5R,6R)-5,6-Diacetoxy-7-[(R)-4-chloro-2-((Z)-oct-2-enyl)-5-oxo-2-trimethylsilanyloxy-cyclopent-3-enyl]-7-hydroxy-heptanoic acid methyl ester

(5R,6R)-5,6-Diacetoxy-7-[(R)-4-chloro-2-((Z)-oct-2-enyl)-5-oxo-2-trimethylsilanyloxy-cyclopent-3-enyl]-7-hydroxy-heptanoic acid methyl ester

(5R,6R)-5,6-Diacetoxy-7-hydroxy-heptanoic acid methyl ester

(5R,6R)-5,6-Diacetoxy-7-hydroxy-heptanoic acid methyl ester

(5R,6R)-5,6-Diacetoxy-7-[(R)-4-chloro-2-((Z)-oct-2-enyl)-5-oxo-2-trimethylsilanyloxy-cyclopent-3-enyl]-7-hydroxy-heptanoic acid methyl ester

(5R,6R)-5,6-Diacetoxy-7-[(R)-4-chloro-2-((Z)-oct-2-enyl)-5-oxo-2-trimethylsilanyloxy-cyclopent-3-enyl]-7-hydroxy-heptanoic acid methyl ester

methyl (5S,6S)-5,6-dihydroxy-7-<(tetrahydropyran-2-yl)oxy>heptanoate

methyl (5S,6S)-5,6-dihydroxy-7-<(tetrahydropyran-2-yl)oxy>heptanoate

(5R,6R)-5,6-Diacetoxy-7-[(R)-4-chloro-2-((Z)-oct-2-enyl)-5-oxo-2-trimethylsilanyloxy-cyclopent-3-enyl]-7-hydroxy-heptanoic acid methyl ester

(5R,6R)-5,6-Diacetoxy-7-[(R)-4-chloro-2-((Z)-oct-2-enyl)-5-oxo-2-trimethylsilanyloxy-cyclopent-3-enyl]-7-hydroxy-heptanoic acid methyl ester

(5R,6R)-5,6-Dihydroxy-7-(tetrahydro-pyran-2-yloxy)-heptanoic acid methyl ester

(5R,6R)-5,6-Dihydroxy-7-(tetrahydro-pyran-2-yloxy)-heptanoic acid methyl ester

(5R,6R)-5,6-Diacetoxy-7-[(R)-4-chloro-2-((Z)-oct-2-enyl)-5-oxo-2-trimethylsilanyloxy-cyclopent-3-enyl]-7-hydroxy-heptanoic acid methyl ester

(5R,6R)-5,6-Diacetoxy-7-[(R)-4-chloro-2-((Z)-oct-2-enyl)-5-oxo-2-trimethylsilanyloxy-cyclopent-3-enyl]-7-hydroxy-heptanoic acid methyl ester

(5R,6R)-5,6-Diacetoxy-7-(tetrahydro-pyran-2-yloxy)-heptanoic acid methyl ester

(5R,6R)-5,6-Diacetoxy-7-(tetrahydro-pyran-2-yloxy)-heptanoic acid methyl ester

(5R,6R)-5,6-Diacetoxy-7-[(R)-4-chloro-2-((Z)-oct-2-enyl)-5-oxo-2-trimethylsilanyloxy-cyclopent-3-enyl]-7-hydroxy-heptanoic acid methyl ester

(5R,6R)-5,6-Diacetoxy-7-[(R)-4-chloro-2-((Z)-oct-2-enyl)-5-oxo-2-trimethylsilanyloxy-cyclopent-3-enyl]-7-hydroxy-heptanoic acid methyl ester

(1R,3S)-4-Chloro-1-oct-2-ynyl-cyclopent-4-ene-1,3-diol

(1R,3S)-4-Chloro-1-oct-2-ynyl-cyclopent-4-ene-1,3-diol

(5R,6R)-5,6-Diacetoxy-7-[(R)-4-chloro-2-((Z)-oct-2-enyl)-5-oxo-2-trimethylsilanyloxy-cyclopent-3-enyl]-7-hydroxy-heptanoic acid methyl ester

(5R,6R)-5,6-Diacetoxy-7-[(R)-4-chloro-2-((Z)-oct-2-enyl)-5-oxo-2-trimethylsilanyloxy-cyclopent-3-enyl]-7-hydroxy-heptanoic acid methyl ester

(S)-3-chloro-4-(tert-butyldimethylsilyloxy)-2-cyclopentenone

(S)-3-chloro-4-(tert-butyldimethylsilyloxy)-2-cyclopentenone

(5R,6R)-5,6-Diacetoxy-7-[(R)-4-chloro-2-((Z)-oct-2-enyl)-5-oxo-2-trimethylsilanyloxy-cyclopent-3-enyl]-7-hydroxy-heptanoic acid methyl ester

(5R,6R)-5,6-Diacetoxy-7-[(R)-4-chloro-2-((Z)-oct-2-enyl)-5-oxo-2-trimethylsilanyloxy-cyclopent-3-enyl]-7-hydroxy-heptanoic acid methyl ester

(5R,6R)-5,6-Dihydroxy-7-(tetrahydro-pyran-2-yloxy)-heptanoic acid

(5R,6R)-5,6-Dihydroxy-7-(tetrahydro-pyran-2-yloxy)-heptanoic acid

(5R,6R)-5,6-Diacetoxy-7-[(R)-4-chloro-2-((Z)-oct-2-enyl)-5-oxo-2-trimethylsilanyloxy-cyclopent-3-enyl]-7-hydroxy-heptanoic acid methyl ester

(5R,6R)-5,6-Diacetoxy-7-[(R)-4-chloro-2-((Z)-oct-2-enyl)-5-oxo-2-trimethylsilanyloxy-cyclopent-3-enyl]-7-hydroxy-heptanoic acid methyl ester

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上游原料

(5R,6R)-5,6-Diacetoxy-7-hydroxy-heptanoic acid methyl ester (5R,6S)-5,6-Diacetoxy-7-oxo-heptanoic acid methyl ester (1R,3S)-4-Chloro-1-oct-2-ynyl-cyclopent-4-ene-1,3-diol (1R,3S)-4-Chloro-1-((Z)-oct-2-enyl)-cyclopent-4-ene-1,3-diol (R)-2-Chloro-4-hydroxy-4-((Z)-oct-2-enyl)-cyclopent-2-enone methyl (5S,6S)-5,6,7-trihydroxyheptanoate (1R,4S)-4-(tert-Butyl-dimethyl-silanyloxy)-3-chloro-1-oct-2-ynyl-cyclopent-2-enol (5R,6R)-5,6-Diacetoxy-7-(tetrahydro-pyran-2-yloxy)-heptanoic acid methyl ester (5R,6R)-5,6-Dihydroxy-7-(tetrahydro-pyran-2-yloxy)-heptanoic acid methyl ester (S)-3-chloro-4-(tert-butyldimethylsilyloxy)-2-cyclopentenone (R)-2-Chloro-4-((Z)-oct-2-enyl)-4-trimethylsilanyloxy-cyclopent-2-enone methyl (5S,6S)-5,6-dihydroxy-7-<(tetrahydropyran-2-yl)oxy>heptanoate (5R,6R)-5,6-Dihydroxy-7-(tetrahydro-pyran-2-yloxy)-heptanoic acid

下游产品

(5R,6R)-5,6-Diacetoxy-7-[(S)-4-chloro-2-hydroxy-2-((Z)-oct-2-enyl)-5-oxo-cyclopent-3-en-(E)-ylidene]-heptanoic acid methyl ester (5S,6R)-5,6-Diacetoxy-7-[(S)-4-chloro-2-hydroxy-2-((Z)-oct-2-enyl)-5-oxo-cyclopent-3-en-(Z)-ylidene]-heptanoic acid methyl ester (Z)-7,8-punaglandin 4