百科

4-{(4S,5S)-5-[(R)-4-Chloro-2-methoxymethoxy-2-((2Z,5Z)-octa-2,5-dienyl)-5-oxo-cyclopent-3-en-(E)-ylidenemethyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-butyric acid methyl ester

4-{(4S,5S)-5-[(R)-4-Chloro-2-methoxymethoxy-2-((2Z,5Z)-octa-2,5-dienyl)-5-oxo-cyclopent-3-en-(E)-ylidenemethyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-butyric acid methyl ester

CAS号：103477-49-2

英文名：4-{(4S,5S)-5-[(R)-4-Chloro-2-methoxymethoxy-2-((2Z,5Z)-octa-2,5-dienyl)-5-oxo-cyclopent-3-en-(E)-ylidenemethyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-butyric acid methyl ester

分子式：C26H37ClO7

分子量：497.021

合成路线

(S)-2-Chloro-4-methoxymethoxy-4-((2Z,5Z)-octa-2,5-dienyl)-cyclopent-2-enone

(S)-2-Chloro-4-methoxymethoxy-4-((2Z,5Z)-octa-2,5-dienyl)-cyclopent-2-enone

4-{(4S,5S)-5-[(R)-4-Chloro-2-methoxymethoxy-2-((2Z,5Z)-octa-2,5-dienyl)-5-oxo-cyclopent-3-en-(E)-ylidenemethyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-butyric acid methyl ester

4-{(4S,5S)-5-[(R)-4-Chloro-2-methoxymethoxy-2-((2Z,5Z)-octa-2,5-dienyl)-5-oxo-cyclopent-3-en-(E)-ylidenemethyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-butyric acid methyl ester

methyl (5S,6R)-5,6-isopropylidenedioxy-7-oxo-heptanoate

methyl (5S,6R)-5,6-isopropylidenedioxy-7-oxo-heptanoate

4-{(4S,5S)-5-[(R)-4-Chloro-2-methoxymethoxy-2-((2Z,5Z)-octa-2,5-dienyl)-5-oxo-cyclopent-3-en-(E)-ylidenemethyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-butyric acid methyl ester

4-{(4S,5S)-5-[(R)-4-Chloro-2-methoxymethoxy-2-((2Z,5Z)-octa-2,5-dienyl)-5-oxo-cyclopent-3-en-(E)-ylidenemethyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-butyric acid methyl ester

上游原料

methyl (5S,6R)-5,6-isopropylidenedioxy-7-oxo-heptanoate (S)-2-Chloro-4-methoxymethoxy-4-((2Z,5Z)-octa-2,5-dienyl)-cyclopent-2-enone

下游产品

(5S,6S)-5,6-Diacetoxy-7-[(R)-4-chloro-2-methoxymethoxy-2-((2Z,5Z)-octa-2,5-dienyl)-5-oxo-cyclopent-3-en-(E)-ylidene]-heptanoic acid methyl ester (5S,6S)-7-[(R)-4-Chloro-2-methoxymethoxy-2-((2Z,5Z)-octa-2,5-dienyl)-5-oxo-cyclopent-3-en-(E)-ylidene]-5,6-dihydroxy-heptanoic acid methyl ester