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(2R,3R,4R,5S)-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-bis<(methylsulfonyl)oxy>ethyl>-4-methyl-4-vinyltetrahydrofuran

(2R,3R,4R,5S)-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-bis<(methylsulfonyl)oxy>ethyl>-4-methyl-4-vinyltetrahydrofuran

CAS号：103516-27-4

英文名：(2R,3R,4R,5S)-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-bis<(methylsulfonyl)oxy>ethyl>-4-methyl-4-vinyltetrahydrofuran

分子式：C14H24O9S2

分子量：400.465

合成路线

(Z)-3-deoxy-3-C-[(hydroxymethyl)methylene]-1,2:5,6-di-O-isopropylidene-α-D-ribo-hexofuranose

(Z)-3-deoxy-3-C-[(hydroxymethyl)methylene]-1,2:5,6-di-O-isopropylidene-α-D-ribo-hexofuranose

(2R,3R,4R,5S)-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-bis<(methylsulfonyl)oxy>ethyl>-4-methyl-4-vinyltetrahydrofuran

(2R,3R,4R,5S)-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-bis<(methylsulfonyl)oxy>ethyl>-4-methyl-4-vinyltetrahydrofuran

2-[(3aR,5S,6aR)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-dihydro-furo[2,3-d][1,3]dioxol-(6E)-ylidene]-ethanol

2-[(3aR,5S,6aR)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-dihydro-furo[2,3-d][1,3]dioxol-(6E)-ylidene]-ethanol

(2R,3R,4R,5S)-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-bis<(methylsulfonyl)oxy>ethyl>-4-methyl-4-vinyltetrahydrofuran

(2R,3R,4R,5S)-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-bis<(methylsulfonyl)oxy>ethyl>-4-methyl-4-vinyltetrahydrofuran

(2R,3R,4R,5S)-4-(formylmethyl)-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-(isopropylidenedioxy)ethyl>-4-vinyltetrahydrofuran

(2R,3R,4R,5S)-4-(formylmethyl)-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-(isopropylidenedioxy)ethyl>-4-vinyltetrahydrofuran

(2R,3R,4R,5S)-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-bis<(methylsulfonyl)oxy>ethyl>-4-methyl-4-vinyltetrahydrofuran

(2R,3R,4R,5S)-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-bis<(methylsulfonyl)oxy>ethyl>-4-methyl-4-vinyltetrahydrofuran

上游原料

2-[(3aR,5S,6aR)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-dihydro-furo[2,3-d][1,3]dioxol-(6E)-ylidene]-ethanol (2R,3R,4R,5S)-4-(formylmethyl)-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-(isopropylidenedioxy)ethyl>-4-vinyltetrahydrofuran (Z)-3-deoxy-3-C-[(hydroxymethyl)methylene]-1,2:5,6-di-O-isopropylidene-α-D-ribo-hexofuranose

下游产品

(S)-1-((3aR,5S,6R,6aR)-2,2,6-Trimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-ethane-1,2-diol 3-deoxy-1,2:5,6-di-O-isopropylidene-3-C-methyl-3-C-vinyl-β-L-talofuranose