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(2R,3R,4R,5S)-4-(2-hydroxyethyl)-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-(isopropylidenedioxy)ethyl>-4-vinyltetrahydrofuran

CAS号：103537-73-1

英文名：(2R,3R,4R,5S)-4-(2-hydroxyethyl)-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-(isopropylidenedioxy)ethyl>-4-vinyltetrahydrofuran

分子式：C16H26O6

分子量：314.374

合成路线

103516-12-7

(Z)-3-deoxy-3-C-[(hydroxymethyl)methylene]-1,2:5,6-di-O-isopropylidene-α-D-ribo-hexofuranose

103537-73-1

(2R,3R,4R,5S)-4-(2-hydroxyethyl)-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-(isopropylidenedioxy)ethyl>-4-vinyltetrahydrofuran

103516-13-8

2-[(3aR,5S,6aR)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-dihydro-furo[2,3-d][1,3]dioxol-(6E)-ylidene]-ethanol

103537-73-1

(2R,3R,4R,5S)-4-(2-hydroxyethyl)-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-(isopropylidenedioxy)ethyl>-4-vinyltetrahydrofuran

上游原料

2-[(3aR,5S,6aR)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-dihydro-furo[2,3-d][1,3]dioxol-(6E)-ylidene]-ethanol (Z)-3-deoxy-3-C-[(hydroxymethyl)methylene]-1,2:5,6-di-O-isopropylidene-α-D-ribo-hexofuranose

下游产品

(3aS,4R,7aR)-4-Methyl-4-<<(tert-butyldiphenylsilyl)oxy>methyl>hexahydrobenzofuran-2(3H)-one (2S,3R)-3-Methyl-2-<2-<(tert-butyldiphenylsilyl)oxy>ethyl>-3-vinylcyclohexanone (3aS,4R,7aR)-4-(Hydroxymethyl)hexahydrobenzofuran-2(3H)-one (2R,3R,4R,5S)-4-(formylmethyl)-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-(isopropylidenedioxy)ethyl>-4-vinyltetrahydrofuran (3aS,4S,7aR)-4-Methyl-4-vinylhexahydrobenzofuran-2(3H)-one (3aS,4S,7aR)-4-Bis(ethylthio)methyl-4-<<(tert-butyldiphenylsilyl)oxy>methyl>hexahydrobenzofuran-2(3H)-one (3aS,4S,7aR)-4-<(1S)-1,2-Dihydroxyethyl>-4-<<(tert-butyldiphenylsilyl)oxy>methyl>hexahydrobenzofuran-2(3H)-one (3aS,4S,7aR)-4-Methyl-2-oxo-octahydro-benzofuran-4-carbaldehyde (3aS,4S,7aR)-4-<(1S)-2-(Benzyloxy)-1-hydroxyethyl>-4-(hydroxymethyl)hexahydrobenzofuran-2(3H)-one (1R,2S,3S)-2-(2-Hydroxyethyl)-3-methyl-3-vinylcyclohexanol (2R,3R,4R,5S)-5-<(1S)-2-(benzoyloxy)-1-hydroxyethyl>-2,3-(isopropylidenedioxy)-4-methyl-4-vinyltetrahydrofuran (3aS,4R,7aR)-4-Methyl-4-vinylhexahydrobenzofuran-2(3H)-one (1R,2S,3S)-2-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-3-methyl-3-vinyl-cyclohexanol (1R,2S,3S)-1,3-Dimethyl-2-<2-<(tert-butyldiphenylsilyl)oxy>ethyl>-3-vinylcyclohexanol Formic acid (S)-2-benzyloxy-1-((3aS,4R,7aR)-4-formyl-2-oxo-octahydro-benzofuran-4-yl)-ethyl ester (S)-1-((3aR,5S,6R,6aR)-2,2,6-trimethyl-6-vinyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)ethane-1,2-diyl dibenzoate (S)-1-((3aR,5S,6R,6aR)-2,2,6-Trimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-ethane-1,2-diol (2R,3R,4R,5S)-2,3-(Isopropylidenedioxy)-5-<(1R)-1,2-(isopropylidenedioxy)ethyl>-4-<(Z)-2-(methoxycarbonyl)ethenyl>-4-(4-oxobutyl)tetrahydrofuran (2R,3R,4R,5S)-2,3-(Isopropylidenedioxy)-5-<(1R)-1,2-(isopropylidenedioxy)ethyl>-4-<(Z)-2-(methoxycarbonyl)ethenyl>-4-<4-<(tert-butyldimethylsilyl)oxy>butyl>tetrahydrofuran (2R,3R,4R,5S)-2,3-(Isopropylidenedioxy)-5-<(1R)-1,2-(isopropylidenedioxy)ethyl>-4-<(Z)-2-(methoxycarbonyl)ethenyl>-4-(4-oxopentyl)tetrahydrofuran (1R,2S,3R)-1,3-Dimethyl-2-<2-<(tert-butyldiphenylsilyl)oxy>ethyl>-3-vinylcyclohexanol (2R,3R,4R,5S)-4-<(E)-2-(Ethoxycarbonyl)ethenyl>-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-(isopropylidenedioxy)ethyl>-4-(4-oxopentyl)tetrahydrofuran (1R,2S,3R)-2-(2-Hydroxyethyl)-3-methyl-3-vinylcyclohexanol (2R,3R,4R,5S)-4-(4-Hydroxybutyl)-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-(isopropylidenedioxy)ethyl>-4-<(Z)-2-(methoxycarbonyl)ethenyl>tetrahydrofuran (1R,2S,3R)-2-(2-Hydroxyethyl)-1,3-dimethyl-3-vinylcyclohexanol 3-deoxy-1,2:5,6-di-O-isopropylidene-3-C-methyl-3-C-vinyl-β-L-talofuranose