百科

(R)-2-((1R,2S,3R,5R,7R)-5-(3,4-dimethoxyphenyl)-2-hydroxy-3-(tosyloxy)-6,8-dioxabicyclo[3.2.1]octan-7-yl)-2-hydroxyethyl 4-methylbenzenesulfonate

(R)-2-((1R,2S,3R,5R,7R)-5-(3,4-dimethoxyphenyl)-2-hydroxy-3-(tosyloxy)-6,8-dioxabicyclo[3.2.1]octan-7-yl)-2-hydroxyethyl 4-methylbenzenesulfonate

CAS号：1053245-48-9

英文名：(R)-2-((1R,2S,3R,5R,7R)-5-(3,4-dimethoxyphenyl)-2-hydroxy-3-(tosyloxy)-6,8-dioxabicyclo[3.2.1]octan-7-yl)-2-hydroxyethyl 4-methylbenzenesulfonate

分子式：C30H34O12S2

分子量：650.714

合成路线

(1R,5R,7R)-5-(3,4-Dimethoxy-phenyl)-7-vinyl-6,8-dioxa-bicyclo[3.2.1]oct-2-ene

(1R,5R,7R)-5-(3,4-Dimethoxy-phenyl)-7-vinyl-6,8-dioxa-bicyclo[3.2.1]oct-2-ene

(R)-2-((1R,2S,3R,5R,7R)-5-(3,4-dimethoxyphenyl)-2-hydroxy-3-(tosyloxy)-6,8-dioxabicyclo[3.2.1]octan-7-yl)-2-hydroxyethyl 4-methylbenzenesulfonate

(R)-2-((1R,2S,3R,5R,7R)-5-(3,4-dimethoxyphenyl)-2-hydroxy-3-(tosyloxy)-6,8-dioxabicyclo[3.2.1]octan-7-yl)-2-hydroxyethyl 4-methylbenzenesulfonate

(4R,5R)-2-Allyl-2-(3,4-dimethoxy-phenyl)-4,5-divinyl-[1,3]dioxolane

(4R,5R)-2-Allyl-2-(3,4-dimethoxy-phenyl)-4,5-divinyl-[1,3]dioxolane

(R)-2-((1R,2S,3R,5R,7R)-5-(3,4-dimethoxyphenyl)-2-hydroxy-3-(tosyloxy)-6,8-dioxabicyclo[3.2.1]octan-7-yl)-2-hydroxyethyl 4-methylbenzenesulfonate

(R)-2-((1R,2S,3R,5R,7R)-5-(3,4-dimethoxyphenyl)-2-hydroxy-3-(tosyloxy)-6,8-dioxabicyclo[3.2.1]octan-7-yl)-2-hydroxyethyl 4-methylbenzenesulfonate

(3R,4R)-3,4-二-O-苄基-1,5-己二烯-3,4-二醇

(3R,4R)-3,4-二-O-苄基-1,5-己二烯-3,4-二醇

(R)-2-((1R,2S,3R,5R,7R)-5-(3,4-dimethoxyphenyl)-2-hydroxy-3-(tosyloxy)-6,8-dioxabicyclo[3.2.1]octan-7-yl)-2-hydroxyethyl 4-methylbenzenesulfonate

(R)-2-((1R,2S,3R,5R,7R)-5-(3,4-dimethoxyphenyl)-2-hydroxy-3-(tosyloxy)-6,8-dioxabicyclo[3.2.1]octan-7-yl)-2-hydroxyethyl 4-methylbenzenesulfonate

上游原料

(3R,4R)-3,4-二-O-苄基-1,5-己二烯-3,4-二醇 (1R,5R,7R)-5-(3,4-Dimethoxy-phenyl)-7-vinyl-6,8-dioxa-bicyclo[3.2.1]oct-2-ene (4R,5R)-2-Allyl-2-(3,4-dimethoxy-phenyl)-4,5-divinyl-[1,3]dioxolane

下游产品

methyl (methyl 4,5,7,8,9-penta-O-acetyl-3-deoxy-D-glycero-β-D-galacto-non-2-ulopyranosid)onate Acetic acid (1S,2R,3S,5R,7R)-2-acetoxy-7-((R)-1,2-diacetoxy-ethyl)-5-(3,4-dimethoxy-phenyl)-6,8-dioxa-bicyclo[3.2.1]oct-3-yl ester Acetic acid (2S,4S,5R,6R)-5-acetoxy-2-(3,4-dimethoxy-phenyl)-2-methoxy-6-((1R,2R)-1,2,3-triacetoxy-propyl)-tetrahydro-pyran-4-yl ester