百科

(2R,3S,4R,5R,6R)-3-((S)-2-(benzoyloxy)-1-hydroxyethyl)-2-methyl-3-(methylthio)-6-((2-nitrobenzyl)oxy)-5-((2-(trimethylsilyl)ethoxy)methoxy)tetrahydro-2H-pyran-4-yl benzoate

CAS号：1053557-54-2

英文名：(2R,3S,4R,5R,6R)-3-((S)-2-(benzoyloxy)-1-hydroxyethyl)-2-methyl-3-(methylthio)-6-((2-nitrobenzyl)oxy)-5-((2-(trimethylsilyl)ethoxy)methoxy)tetrahydro-2H-pyran-4-yl benzoate

分子式：C36H45NO11SSi

分子量：727.893

合成路线

222406-49-7

4-hydroxy-2-methyl-6-(2-nitrobenzyloxy)-5-<2-(trimethylsilyl)ethoxymethoxy>tetrahydropyran-3-one

1053557-54-2

(2R,3S,4R,5R,6R)-3-((S)-2-(benzoyloxy)-1-hydroxyethyl)-2-methyl-3-(methylthio)-6-((2-nitrobenzyl)oxy)-5-((2-(trimethylsilyl)ethoxy)methoxy)tetrahydro-2H-pyran-4-yl benzoate

222406-50-0

<4-hydroxy-2-methyl-6-(2-nitrobenzyloxy)-5-<2-(trimethylsilyl)ethoxymethoxy>tetrahydropyran-3-ylidene>acetic acid methyl ester

1053557-54-2

(2R,3S,4R,5R,6R)-3-((S)-2-(benzoyloxy)-1-hydroxyethyl)-2-methyl-3-(methylthio)-6-((2-nitrobenzyl)oxy)-5-((2-(trimethylsilyl)ethoxy)methoxy)tetrahydro-2H-pyran-4-yl benzoate

222406-53-3

3a-(2-hydroxyethyl)-4-methyl-6-(2-nitrobenzyloxy)-7-<2-(trimethylsilyl)ethoxymethoxy>tetrahydro<1,3>oxathiolo<4,5-c>pyran-2-thione

1053557-54-2

(2R,3S,4R,5R,6R)-3-((S)-2-(benzoyloxy)-1-hydroxyethyl)-2-methyl-3-(methylthio)-6-((2-nitrobenzyl)oxy)-5-((2-(trimethylsilyl)ethoxy)methoxy)tetrahydro-2H-pyran-4-yl benzoate

132938-43-3

(3aS,4R,6R,7R,7aR)-7-Hydroxy-4-methyl-6-(2-nitro-benzyloxy)-tetrahydro-[1,3]dioxolo[4,5-c]pyran-2-one

1053557-54-2

(2R,3S,4R,5R,6R)-3-((S)-2-(benzoyloxy)-1-hydroxyethyl)-2-methyl-3-(methylthio)-6-((2-nitrobenzyl)oxy)-5-((2-(trimethylsilyl)ethoxy)methoxy)tetrahydro-2H-pyran-4-yl benzoate

222406-51-1

<4-methyl-6-(2-nitrobenzyloxy)-2-thioxo-7-<2-(trimethylsilyl)ethoxymethoxy>tetrahydro<1,3>oxathiolo<4,5-c>pyran-3a-yl>acetic acid methyl ester

1053557-54-2

(2R,3S,4R,5R,6R)-3-((S)-2-(benzoyloxy)-1-hydroxyethyl)-2-methyl-3-(methylthio)-6-((2-nitrobenzyl)oxy)-5-((2-(trimethylsilyl)ethoxy)methoxy)tetrahydro-2H-pyran-4-yl benzoate

上游原料

<4-hydroxy-2-methyl-6-(2-nitrobenzyloxy)-5-<2-(trimethylsilyl)ethoxymethoxy>tetrahydropyran-3-ylidene>acetic acid methyl ester <4-methyl-6-(2-nitrobenzyloxy)-2-thioxo-7-<2-(trimethylsilyl)ethoxymethoxy>tetrahydro<1,3>oxathiolo<4,5-c>pyran-3a-yl>acetic acid methyl ester 4-hydroxy-2-methyl-6-(2-nitrobenzyloxy)-5-<2-(trimethylsilyl)ethoxymethoxy>tetrahydropyran-3-one 3a-(2-hydroxyethyl)-4-methyl-6-(2-nitrobenzyloxy)-7-<2-(trimethylsilyl)ethoxymethoxy>tetrahydro<1,3>oxathiolo<4,5-c>pyran-2-thione (3aS,4R,6R,7R,7aR)-7-Hydroxy-4-methyl-6-(2-nitro-benzyloxy)-tetrahydro-[1,3]dioxolo[4,5-c]pyran-2-one

下游产品

Benzoic acid (S)-2-hydroxy-2-[(2R,3R,4R,5R,6R)-4-hydroxy-2-methyl-3-methylsulfanyl-6-(2-nitro-benzyloxy)-5-(2-trimethylsilanyl-ethoxymethoxy)-tetrahydro-pyran-3-yl]-ethyl ester