百科

Acetic acid (4aR,5R,6S,8S,8aS)-6-(tert-butyl-dimethyl-silanyloxy)-5-(tert-butyl-dimethyl-silanyloxymethyl)-8-hydroxy-2,2,5-trimethyl-hexahydro-benzo[1,3]dioxin-8a-ylmethyl ester

Acetic acid (4aR,5R,6S,8S,8aS)-6-(tert-butyl-dimethyl-silanyloxy)-5-(tert-butyl-dimethyl-silanyloxymethyl)-8-hydroxy-2,2,5-trimethyl-hexahydro-benzo[1,3]dioxin-8a-ylmethyl ester

CAS号：1053613-26-5

英文名：Acetic acid (4aR,5R,6S,8S,8aS)-6-(tert-butyl-dimethyl-silanyloxy)-5-(tert-butyl-dimethyl-silanyloxymethyl)-8-hydroxy-2,2,5-trimethyl-hexahydro-benzo[1,3]dioxin-8a-ylmethyl ester

分子式：C27H54O7Si2

分子量：546.884

合成路线

[(S)-3-Benzyloxy-3-((4S,5R)-4-benzyloxymethyl-5-isopropenyl-2,2-dimethyl-[1,3]dioxan-4-yl)-propoxy]-tert-butyl-dimethyl-silane

[(S)-3-Benzyloxy-3-((4S,5R)-4-benzyloxymethyl-5-isopropenyl-2,2-dimethyl-[1,3]dioxan-4-yl)-propoxy]-tert-butyl-dimethyl-silane

Acetic acid (4aR,5R,6S,8S,8aS)-6-(tert-butyl-dimethyl-silanyloxy)-5-(tert-butyl-dimethyl-silanyloxymethyl)-8-hydroxy-2,2,5-trimethyl-hexahydro-benzo[1,3]dioxin-8a-ylmethyl ester

Acetic acid (4aR,5R,6S,8S,8aS)-6-(tert-butyl-dimethyl-silanyloxy)-5-(tert-butyl-dimethyl-silanyloxymethyl)-8-hydroxy-2,2,5-trimethyl-hexahydro-benzo[1,3]dioxin-8a-ylmethyl ester

(2R,3S,4S)-4-Benzyloxy-3-benzyloxymethyl-6-(tert-butyl-dimethyl-silanyloxy)-2-isopropenyl-hexane-1,3-diol

(2R,3S,4S)-4-Benzyloxy-3-benzyloxymethyl-6-(tert-butyl-dimethyl-silanyloxy)-2-isopropenyl-hexane-1,3-diol

Acetic acid (4aR,5R,6S,8S,8aS)-6-(tert-butyl-dimethyl-silanyloxy)-5-(tert-butyl-dimethyl-silanyloxymethyl)-8-hydroxy-2,2,5-trimethyl-hexahydro-benzo[1,3]dioxin-8a-ylmethyl ester

Acetic acid (4aR,5R,6S,8S,8aS)-6-(tert-butyl-dimethyl-silanyloxy)-5-(tert-butyl-dimethyl-silanyloxymethyl)-8-hydroxy-2,2,5-trimethyl-hexahydro-benzo[1,3]dioxin-8a-ylmethyl ester

上游原料

(2R,3S,4S)-4-Benzyloxy-3-benzyloxymethyl-6-(tert-butyl-dimethyl-silanyloxy)-2-isopropenyl-hexane-1,3-diol [(S)-3-Benzyloxy-3-((4S,5R)-4-benzyloxymethyl-5-isopropenyl-2,2-dimethyl-[1,3]dioxan-4-yl)-propoxy]-tert-butyl-dimethyl-silane

下游产品

(1S,2R,3R,4S,6R)-4-(tert-Butyl-dimethyl-silanyloxy)-3-(tert-butyl-dimethyl-silanyloxymethyl)-2-hydroxymethyl-3-methyl-7-oxa-bicyclo[4.2.0]octan-1-ol