百科

benzyl (2R,4R,5R,5aR,10bS)-4-(((tert-butyldimethylsilyl)oxy)methyl)-9-methoxy-10b-methyl-1,2,4,5,5a,10b-hexahydro-6H-2,5-epoxyoxepino[4,5-b]indole-6-carboxylate

benzyl (2R,4R,5R,5aR,10bS)-4-(((tert-butyldimethylsilyl)oxy)methyl)-9-methoxy-10b-methyl-1,2,4,5,5a,10b-hexahydro-6H-2,5-epoxyoxepino[4,5-b]indole-6-carboxylate

CAS号：1053613-91-4

英文名：benzyl (2R,4R,5R,5aR,10bS)-4-(((tert-butyldimethylsilyl)oxy)methyl)-9-methoxy-10b-methyl-1,2,4,5,5a,10b-hexahydro-6H-2,5-epoxyoxepino[4,5-b]indole-6-carboxylate

分子式：C29H39NO6Si

分子量：525.709

合成路线

(1S,5S,7R)-7-(tert-Butyl-dimethyl-silanyloxymethyl)-3-methyl-6,8-dioxa-bicyclo[3.2.1]octan-2-one

(1S,5S,7R)-7-(tert-Butyl-dimethyl-silanyloxymethyl)-3-methyl-6,8-dioxa-bicyclo[3.2.1]octan-2-one

benzyl (2R,4R,5R,5aR,10bS)-4-(((tert-butyldimethylsilyl)oxy)methyl)-9-methoxy-10b-methyl-1,2,4,5,5a,10b-hexahydro-6H-2,5-epoxyoxepino[4,5-b]indole-6-carboxylate

benzyl (2R,4R,5R,5aR,10bS)-4-(((tert-butyldimethylsilyl)oxy)methyl)-9-methoxy-10b-methyl-1,2,4,5,5a,10b-hexahydro-6H-2,5-epoxyoxepino[4,5-b]indole-6-carboxylate

(1S,5S,7R)-7-(tert-Butyl-dimethyl-silanyloxymethyl)-6,8-dioxa-bicyclo[3.2.1]octan-2-one

(1S,5S,7R)-7-(tert-Butyl-dimethyl-silanyloxymethyl)-6,8-dioxa-bicyclo[3.2.1]octan-2-one

benzyl (2R,4R,5R,5aR,10bS)-4-(((tert-butyldimethylsilyl)oxy)methyl)-9-methoxy-10b-methyl-1,2,4,5,5a,10b-hexahydro-6H-2,5-epoxyoxepino[4,5-b]indole-6-carboxylate

benzyl (2R,4R,5R,5aR,10bS)-4-(((tert-butyldimethylsilyl)oxy)methyl)-9-methoxy-10b-methyl-1,2,4,5,5a,10b-hexahydro-6H-2,5-epoxyoxepino[4,5-b]indole-6-carboxylate

上游原料

(1S,5S,7R)-7-(tert-Butyl-dimethyl-silanyloxymethyl)-3-methyl-6,8-dioxa-bicyclo[3.2.1]octan-2-one (1S,5S,7R)-7-(tert-Butyl-dimethyl-silanyloxymethyl)-6,8-dioxa-bicyclo[3.2.1]octan-2-one

下游产品

3,3a,8,8a-tetrahydro-5-methoxy-3a-methyl-2H-furo<2,3-b>indole (2R,3S)-3-[2-(tert-Butoxycarbonyl-methyl-amino)-ethyl]-2-((S)-1-hydroxy-allyl)-5-methoxy-3-methyl-2,3-dihydro-indole-1-carboxylic acid benzyl ester (2R,3S)-2-((S)-1-Hydroxy-allyl)-5-methoxy-3-methyl-3-(2-methylamino-ethyl)-2,3-dihydro-indole-1-carboxylic acid benzyl ester (3aS,8aR)-5-Methoxy-1,3a-dimethyl-2,3,3a,8a-tetrahydro-1H-pyrrolo[2,3-b]indole-8-carboxylic acid benzyl ester (2R,3S)-2-((S)-1-Hydroxy-allyl)-3-(2-hydroxy-ethyl)-5-methoxy-3-methyl-2,3-dihydro-indole-1-carboxylic acid benzyl ester (1S,4aS,9aR)-3-Hydroxy-6-methoxy-4a-methyl-1-vinyl-3,4,4a,9a-tetrahydro-1H-pyrano[3,4-b]indole-9-carboxylic acid benzyl ester (S)-2-Acetoxy-3-[2-(tert-butoxycarbonyl-methyl-amino)-ethyl]-5-methoxy-3-methyl-2,3-dihydro-indole-1-carboxylic acid benzyl ester (3aS,8aS)-5-Methoxy-3a-methyl-2,3,3a,8a-tetrahydro-furo[2,3-b]indole-8-carboxylic acid benzyl ester (3aS,8aS)-5-methoxy-3a,8-dimethyl-3,3a,8,8a-tetrahydro-2H-furo[2,3-b]indole