百科

(1aR,3aR,3bS,5aR,6R,8aS,8bS,10R,10aR)-10-methoxy-3a,5a-dimethyl-6-((R,E)-6-methyl-5-(tosylmethylene)heptan-2-yl)hexadecahydrocyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalene

(1aR,3aR,3bS,5aR,6R,8aS,8bS,10R,10aR)-10-methoxy-3a,5a-dimethyl-6-((R,E)-6-methyl-5-(tosylmethylene)heptan-2-yl)hexadecahydrocyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalene

CAS号：105395-37-7

英文名：(1aR,3aR,3bS,5aR,6R,8aS,8bS,10R,10aR)-10-methoxy-3a,5a-dimethyl-6-((R,E)-6-methyl-5-(tosylmethylene)heptan-2-yl)hexadecahydrocyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalene

分子式：C36H54O3S

分子量：566.877

合成路线

Se-phenyl-paratolueneselenosulfonate

Se-phenyl-paratolueneselenosulfonate

(1aR,3aR,3bS,5aR,6R,8aS,8bS,10R,10aR)-10-methoxy-3a,5a-dimethyl-6-((R,E)-6-methyl-5-(tosylmethylene)heptan-2-yl)hexadecahydrocyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalene

(1aR,3aR,3bS,5aR,6R,8aS,8bS,10R,10aR)-10-methoxy-3a,5a-dimethyl-6-((R,E)-6-methyl-5-(tosylmethylene)heptan-2-yl)hexadecahydrocyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalene

(1aR,3aR,3bS,5aR,6R,8aS,8bS,10R,10aR)-6-((R)-hex-5-yn-2-yl)-10-methoxy-3a,5a-dimethylhexadecahydrocyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalene

(1aR,3aR,3bS,5aR,6R,8aS,8bS,10R,10aR)-6-((R)-hex-5-yn-2-yl)-10-methoxy-3a,5a-dimethylhexadecahydrocyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalene

(1aR,3aR,3bS,5aR,6R,8aS,8bS,10R,10aR)-10-methoxy-3a,5a-dimethyl-6-((R,E)-6-methyl-5-(tosylmethylene)heptan-2-yl)hexadecahydrocyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalene

(1aR,3aR,3bS,5aR,6R,8aS,8bS,10R,10aR)-10-methoxy-3a,5a-dimethyl-6-((R,E)-6-methyl-5-(tosylmethylene)heptan-2-yl)hexadecahydrocyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalene

((R,E)-5-((1aR,3aR,3bS,5aR,6R,8aS,8bS,10R,10aR)-10-methoxy-3a,5a-dimethylhexadecahydrocyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalen-6-yl)-1-tosylhex-1-en-2-yl)(phenyl)selane

((R,E)-5-((1aR,3aR,3bS,5aR,6R,8aS,8bS,10R,10aR)-10-methoxy-3a,5a-dimethylhexadecahydrocyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalen-6-yl)-1-tosylhex-1-en-2-yl)(phenyl)selane

(1aR,3aR,3bS,5aR,6R,8aS,8bS,10R,10aR)-6-((R)-hex-5-yn-2-yl)-10-methoxy-3a,5a-dimethylhexadecahydrocyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalene

(1aR,3aR,3bS,5aR,6R,8aS,8bS,10R,10aR)-6-((R)-hex-5-yn-2-yl)-10-methoxy-3a,5a-dimethylhexadecahydrocyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalene

(1aR,3aR,3bS,5aR,6R,8aS,8bS,10R,10aR)-10-methoxy-3a,5a-dimethyl-6-((R,E)-6-methyl-5-(tosylmethylene)heptan-2-yl)hexadecahydrocyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalene

(1aR,3aR,3bS,5aR,6R,8aS,8bS,10R,10aR)-10-methoxy-3a,5a-dimethyl-6-((R,E)-6-methyl-5-(tosylmethylene)heptan-2-yl)hexadecahydrocyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalene

上游原料

(1aR,3aR,3bS,5aR,6R,8aS,8bS,10R,10aR)-6-((R)-hex-5-yn-2-yl)-10-methoxy-3a,5a-dimethylhexadecahydrocyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalene Se-phenyl-paratolueneselenosulfonate ((R,E)-5-((1aR,3aR,3bS,5aR,6R,8aS,8bS,10R,10aR)-10-methoxy-3a,5a-dimethylhexadecahydrocyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalen-6-yl)-1-tosylhex-1-en-2-yl)(phenyl)selane

下游产品

(1aR,3aR,3bS,5aR,6R,8aS,8bS,10R,10aR)-6-((R)-hex-5-yn-2-yl)-10-methoxy-3a,5a-dimethylhexadecahydrocyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalene 5,24(28)-胆甾二烯-24-亚甲基-3beta-醇