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Chloro-acetic acid (2R,3R,4S,5R,6R)-4-benzyloxy-5-hydroxy-6-hydroxymethyl-2-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-3-yl ester

Chloro-acetic acid (2R,3R,4S,5R,6R)-4-benzyloxy-5-hydroxy-6-hydroxymethyl-2-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-3-yl ester

CAS号：1054644-54-0

英文名：Chloro-acetic acid (2R,3R,4S,5R,6R)-4-benzyloxy-5-hydroxy-6-hydroxymethyl-2-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-3-yl ester

分子式：C20H31ClO7Si

分子量：446.994

合成路线

2,4,6-tri-O-acetyl-3-O-benzyl-alpha-D-glucopyranosyl chloride

2,4,6-tri-O-acetyl-3-O-benzyl-alpha-D-glucopyranosyl chloride

Chloro-acetic acid (2R,3R,4S,5R,6R)-4-benzyloxy-5-hydroxy-6-hydroxymethyl-2-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-3-yl ester

Chloro-acetic acid (2R,3R,4S,5R,6R)-4-benzyloxy-5-hydroxy-6-hydroxymethyl-2-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-3-yl ester

Acetic acid (2R,3R,4S,5R,6R)-5-acetoxy-6-acetoxymethyl-4-benzyloxy-2-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-3-yl ester

Acetic acid (2R,3R,4S,5R,6R)-5-acetoxy-6-acetoxymethyl-4-benzyloxy-2-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-3-yl ester

Chloro-acetic acid (2R,3R,4S,5R,6R)-4-benzyloxy-5-hydroxy-6-hydroxymethyl-2-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-3-yl ester

Chloro-acetic acid (2R,3R,4S,5R,6R)-4-benzyloxy-5-hydroxy-6-hydroxymethyl-2-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-3-yl ester

Chloro-acetic acid (2R,4aR,6R,7R,8S,8aR)-8-benzyloxy-2-(4-methoxy-phenyl)-6-(2-trimethylsilanyl-ethoxy)-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester

Chloro-acetic acid (2R,4aR,6R,7R,8S,8aR)-8-benzyloxy-2-(4-methoxy-phenyl)-6-(2-trimethylsilanyl-ethoxy)-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester

Chloro-acetic acid (2R,3R,4S,5R,6R)-4-benzyloxy-5-hydroxy-6-hydroxymethyl-2-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-3-yl ester

Chloro-acetic acid (2R,3R,4S,5R,6R)-4-benzyloxy-5-hydroxy-6-hydroxymethyl-2-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-3-yl ester

1,2,4,6-四-O-乙酰基-3-O-苄基-D-吡喃葡萄糖

1,2,4,6-四-O-乙酰基-3-O-苄基-D-吡喃葡萄糖

Chloro-acetic acid (2R,3R,4S,5R,6R)-4-benzyloxy-5-hydroxy-6-hydroxymethyl-2-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-3-yl ester

Chloro-acetic acid (2R,3R,4S,5R,6R)-4-benzyloxy-5-hydroxy-6-hydroxymethyl-2-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-3-yl ester

上游原料

Acetic acid (2R,3R,4S,5R,6R)-5-acetoxy-6-acetoxymethyl-4-benzyloxy-2-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-3-yl ester 1,2,4,6-四-O-乙酰基-3-O-苄基-D-吡喃葡萄糖 2,4,6-tri-O-acetyl-3-O-benzyl-alpha-D-glucopyranosyl chloride Chloro-acetic acid (2R,4aR,6R,7R,8S,8aR)-8-benzyloxy-2-(4-methoxy-phenyl)-6-(2-trimethylsilanyl-ethoxy)-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester

下游产品

Acetic acid (2R,3R,4S,5R,6R)-5-((2R,3R,4S,5R,6R)-5-acetoxy-6-acetoxymethyl-3-allyloxy-4-benzyloxy-tetrahydro-pyran-2-yloxy)-2-acetoxymethyl-4-benzyloxy-6-chloro-tetrahydro-pyran-3-yl ester Acetic acid (2R,3R,4R,5R,6R)-2-acetoxymethyl-4-benzyloxy-5-hydroxy-6-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-3-yl ester