百科

(5S,6R,8S)-2,2,3,3,5,12,12-heptamethyl-11,11-diphenyl-4,10-dioxa-3,11-disilatridecane-6,8-diol

(5S,6R,8S)-2,2,3,3,5,12,12-heptamethyl-11,11-diphenyl-4,10-dioxa-3,11-disilatridecane-6,8-diol

CAS号：1065585-60-5

英文名：(5S,6R,8S)-2,2,3,3,5,12,12-heptamethyl-11,11-diphenyl-4,10-dioxa-3,11-disilatridecane-6,8-diol

分子式：C28H46O4Si2

分子量：502.833

合成路线

2-{(2S,3R)-3-[(S)-1-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-oxiranyl}-ethanol

2-{(2S,3R)-3-[(S)-1-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-oxiranyl}-ethanol

(5S,6R,8S)-2,2,3,3,5,12,12-heptamethyl-11,11-diphenyl-4,10-dioxa-3,11-disilatridecane-6,8-diol

(5S,6R,8S)-2,2,3,3,5,12,12-heptamethyl-11,11-diphenyl-4,10-dioxa-3,11-disilatridecane-6,8-diol

(E)-5-dimethyl-t-butylsilyloxy-2-hexene-1,4-diol

(E)-5-dimethyl-t-butylsilyloxy-2-hexene-1,4-diol

(5S,6R,8S)-2,2,3,3,5,12,12-heptamethyl-11,11-diphenyl-4,10-dioxa-3,11-disilatridecane-6,8-diol

(5S,6R,8S)-2,2,3,3,5,12,12-heptamethyl-11,11-diphenyl-4,10-dioxa-3,11-disilatridecane-6,8-diol

上游原料

2-{(2S,3R)-3-[(S)-1-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-oxiranyl}-ethanol (E)-5-dimethyl-t-butylsilyloxy-2-hexene-1,4-diol

下游产品

(1Z,3S,5R,6S)-5,6-dihydro-6R-[3,5,6-tris(acetoxy)-1-heptenyl]-2H-pyran-2-one