百科

(2R,3S,4R)-1-acetyl-3,4-bis(benzyloxy)-2-<(1S)-1-benzyloxy-3-carboxypropyl>pyrrolidine

(2R,3S,4R)-1-acetyl-3,4-bis(benzyloxy)-2-<(1S)-1-benzyloxy-3-carboxypropyl>pyrrolidine

CAS号：107650-91-9

英文名：(2R,3S,4R)-1-acetyl-3,4-bis(benzyloxy)-2-<(1S)-1-benzyloxy-3-carboxypropyl>pyrrolidine

分子式：C31H35NO6

分子量：517.613

合成路线

methyl 3-acetamido-2-O-acetyl-3-deoxy-6-O-tosyl-α-D-glucopyranoside

methyl 3-acetamido-2-O-acetyl-3-deoxy-6-O-tosyl-α-D-glucopyranoside

(2R,3S,4R)-1-acetyl-3,4-bis(benzyloxy)-2-<(1S)-1-benzyloxy-3-carboxypropyl>pyrrolidine

(2R,3S,4R)-1-acetyl-3,4-bis(benzyloxy)-2-<(1S)-1-benzyloxy-3-carboxypropyl>pyrrolidine

methyl 2,4-di-O-acetyl-3,6-acetylimino-3,6-dideoxy-α-D-glucopyranoside

methyl 2,4-di-O-acetyl-3,6-acetylimino-3,6-dideoxy-α-D-glucopyranoside

(2R,3S,4R)-1-acetyl-3,4-bis(benzyloxy)-2-<(1S)-1-benzyloxy-3-carboxypropyl>pyrrolidine

(2R,3S,4R)-1-acetyl-3,4-bis(benzyloxy)-2-<(1S)-1-benzyloxy-3-carboxypropyl>pyrrolidine

(2S,3S,4R)-1-acetyl-3,4-bis(benzyloxy)-2-<(1R)-1-benzyloxy-2,2-bis(ethylthio)ethyl>pyrrolidine

(2S,3S,4R)-1-acetyl-3,4-bis(benzyloxy)-2-<(1R)-1-benzyloxy-2,2-bis(ethylthio)ethyl>pyrrolidine

(2R,3S,4R)-1-acetyl-3,4-bis(benzyloxy)-2-<(1S)-1-benzyloxy-3-carboxypropyl>pyrrolidine

(2R,3S,4R)-1-acetyl-3,4-bis(benzyloxy)-2-<(1S)-1-benzyloxy-3-carboxypropyl>pyrrolidine

(2R,3S,4R)-1-acetyl-3,4-bis(benzyloxy)-2-<(1S,2E)-1-benzyloxy-3-ethoxycarbonyl-2-propenyl>pyrrolidine

(2R,3S,4R)-1-acetyl-3,4-bis(benzyloxy)-2-<(1S,2E)-1-benzyloxy-3-ethoxycarbonyl-2-propenyl>pyrrolidine

(2R,3S,4R)-1-acetyl-3,4-bis(benzyloxy)-2-<(1S)-1-benzyloxy-3-carboxypropyl>pyrrolidine

(2R,3S,4R)-1-acetyl-3,4-bis(benzyloxy)-2-<(1S)-1-benzyloxy-3-carboxypropyl>pyrrolidine

上游原料

methyl 2,4-di-O-acetyl-3,6-acetylimino-3,6-dideoxy-α-D-glucopyranoside (2R,3S,4R)-1-acetyl-3,4-bis(benzyloxy)-2-<(1S,2E)-1-benzyloxy-3-ethoxycarbonyl-2-propenyl>pyrrolidine (2S,3S,4R)-1-acetyl-3,4-bis(benzyloxy)-2-<(1R)-1-benzyloxy-2,2-bis(ethylthio)ethyl>pyrrolidine methyl 3-acetamido-2-O-acetyl-3-deoxy-6-O-tosyl-α-D-glucopyranoside

下游产品

(1S,2R,8S,8aR)-1,2,8-trihydroxy-octahydroindolizine (1S,2R,8S,8aR)-1,2,8-tri-O-acetyl-5-oxo-octahydroindolizine (1S,2R,8S,8aR)-1,2,8-triacetoxyindolizine