百科

(3Z,5S,6S,7R,8R,9S,11Z,13S,14S,15S,16Z)-8,14-bis((tert-butyldimethylsilyl)oxy)-17-((4S,6S)-6-((R,E)-4-iodobut-3-en-2-yl)-2,2-dimethyl-1,3-dioxan-4-yl)-5,7,9,11,13,15-hexamethylheptadeca-1,3,11,16-tetraen-6-ol

(3Z,5S,6S,7R,8R,9S,11Z,13S,14S,15S,16Z)-8,14-bis((tert-butyldimethylsilyl)oxy)-17-((4S,6S)-6-((R,E)-4-iodobut-3-en-2-yl)-2,2-dimethyl-1,3-dioxan-4-yl)-5,7,9,11,13,15-hexamethylheptadeca-1,3,11,16-tetraen-6-ol

CAS号：1082395-55-8

英文名：(3Z,5S,6S,7R,8R,9S,11Z,13S,14S,15S,16Z)-8,14-bis((tert-butyldimethylsilyl)oxy)-17-((4S,6S)-6-((R,E)-4-iodobut-3-en-2-yl)-2,2-dimethyl-1,3-dioxan-4-yl)-5,7,9,11,13,15-hexamethylheptadeca-1,3,11,16-tetraen-6-ol

分子式：C45H83IO5Si2

分子量：887.213

合成路线

(5Z,13Z)-(2R,3R,4S,8S,9R,10R,11S,12S)-3,9-bis(tertbutyldimethylsilanyloxy)-11-hydroxy-2,4,6,8,10,12-hexamethylhexadeca-5,13,15-trienal

(5Z,13Z)-(2R,3R,4S,8S,9R,10R,11S,12S)-3,9-bis(tertbutyldimethylsilanyloxy)-11-hydroxy-2,4,6,8,10,12-hexamethylhexadeca-5,13,15-trienal

(3Z,5S,6S,7R,8R,9S,11Z,13S,14S,15S,16Z)-8,14-bis((tert-butyldimethylsilyl)oxy)-17-((4S,6S)-6-((R,E)-4-iodobut-3-en-2-yl)-2,2-dimethyl-1,3-dioxan-4-yl)-5,7,9,11,13,15-hexamethylheptadeca-1,3,11,16-tetraen-6-ol

(3Z,5S,6S,7R,8R,9S,11Z,13S,14S,15S,16Z)-8,14-bis((tert-butyldimethylsilyl)oxy)-17-((4S,6S)-6-((R,E)-4-iodobut-3-en-2-yl)-2,2-dimethyl-1,3-dioxan-4-yl)-5,7,9,11,13,15-hexamethylheptadeca-1,3,11,16-tetraen-6-ol

bis(2,2,2-trifluoroethyl) ((4S,5R,E)-7-iodo-4-((4-methoxybenzyl)oxy)-5-methyl-2-oxohept-6-en-1-yl)phosphonate

bis(2,2,2-trifluoroethyl) ((4S,5R,E)-7-iodo-4-((4-methoxybenzyl)oxy)-5-methyl-2-oxohept-6-en-1-yl)phosphonate

(3Z,5S,6S,7R,8R,9S,11Z,13S,14S,15S,16Z)-8,14-bis((tert-butyldimethylsilyl)oxy)-17-((4S,6S)-6-((R,E)-4-iodobut-3-en-2-yl)-2,2-dimethyl-1,3-dioxan-4-yl)-5,7,9,11,13,15-hexamethylheptadeca-1,3,11,16-tetraen-6-ol

(3Z,5S,6S,7R,8R,9S,11Z,13S,14S,15S,16Z)-8,14-bis((tert-butyldimethylsilyl)oxy)-17-((4S,6S)-6-((R,E)-4-iodobut-3-en-2-yl)-2,2-dimethyl-1,3-dioxan-4-yl)-5,7,9,11,13,15-hexamethylheptadeca-1,3,11,16-tetraen-6-ol

上游原料

bis(2,2,2-trifluoroethyl) ((4S,5R,E)-7-iodo-4-((4-methoxybenzyl)oxy)-5-methyl-2-oxohept-6-en-1-yl)phosphonate (5Z,13Z)-(2R,3R,4S,8S,9R,10R,11S,12S)-3,9-bis(tertbutyldimethylsilanyloxy)-11-hydroxy-2,4,6,8,10,12-hexamethylhexadeca-5,13,15-trienal

下游产品

3-benzoylamino-3-phenyl-2-triethylsilanyloxy-propionic acid 14,20-bis(tert-butyl-dimethyl-silanyloxy)-10-hydroxy-7,13,15,17,19,21-hexamethyl-22-(1-methyl-penta-2,4-dienyl)-2-oxo-oxacyclodocosa-3,5,11,16-tetraen-8-yl ester 3-tert-butoxycarbonylamino-2-hydroxy-3-phenyl-propionic acid 8,14,20-trihydroxy-7,13,15,17,19,21-hexamethyl-22-(1-methyl-penta-2,4-dienyl)-2-oxo-oxacyclodocosa-3,5,11,16-tetraen-10-yl ester 3-benzoylamino-2-hydroxy-3-phenyl-propionic acid 8,14,20-trihydroxy-7,13,15,17,19,21-hexamethyl-22-(1-methyl-penta-2,4-dienyl)-2-oxo-oxacyclodocosa-3,5,11,16-tetraen-10-yl ester 3-tert-butoxycarbonylamino-3-phenyl-2-triethylsilanyloxy-propionic acid 14,20-bis(tert-butyl-dimethyl-silanyloxy)-8-methoxy-7,13,15,17,19,21-hexamethyl-22-(1-methyl-penta-2,4-dienyl)-2-oxo-oxacyclodocosa-3,5,11,16-tetraen-10-yl ester 3-tert-butoxycarbonylamino-2-hydroxy-3-phenyl-propionic acid 14,20-dihydroxy-8-methoxy-7,13,15,17,19,21-hexamethyl-22-(1-methyl-penta-2,4-dienyl)-2-oxo-oxacyclodocosa-3,5,11,16-tetraen-10-yl ester 3-benzoylamino-3-phenyl-2-triethylsilanyloxy-propionic acid 14,20-bis(tert-butyl-dimethyl-silanyloxy)-8-methoxy-7,13,15,17,19,21-hexamethyl-22-(1-methyl-penta-2,4-dienyl)-2-oxo-oxacyclodocosa-3,5,11,16-tetraen-10-yl ester 3-tert-butoxycarbonylamino-3-phenyl-2-triethylsilanyloxy-propionic acid 14,20-bis(tert-butyl-dimethyl-silanyloxy)-8-hydroxy-7,13,15,17,19,21-hexamethyl-22-(1-methyl-penta-2,4-dienyl)-2-oxo-oxacyclodocosa-3,5,11,16-tetraen-10-yl ester 3-benzoylamino-2-hydroxy-3-phenyl-propionic acid 14,20-dihydroxy-8-methoxy-7,13,15,17,19,21-hexamethyl-22-(1-methyl-penta-2,4-dienyl)-2-oxo-oxacyclodocosa-3,5,11,16-tetraen-10-yl ester 14,20-bis(tert-butyl-dimethyl-silanyloxy)-8-methoxy-7,13,15,17,19,21-hexamethyl-22-(1-methyl-penta-2,4-dienyl)-10-triethylsilanyloxy-oxacyclodocosa-3,5,11,16-tetraen-2-one 3-benzoylamino-3-phenyl-2-triethylsilanyloxy-propionic acid 14,20-bis(tert-butyl-dimethyl-silanyloxy)-8-hydroxy-7,13,15,17,19,21-hexamethyl-22-(1-methyl-penta-2,4-dienyl)-2-oxo-oxacyclodocosa-3,5,11,16-tetraen-10-yl ester 3-tert-butoxycarbonylamino-3-phenyl-2-triethylsilanyloxy-propionic acid 14,20-bis(tert-butyl-dimethyl-silanyloxy)-10-hydroxy-7,13,15,17,19,21-hexamethyl-22-(1-methyl-penta-2,4-dienyl)-2-oxo-oxacyclodocosa-3,5,11,16-tetraen-8-yl ester 3-tert-butoxycarbonylamino-2-hydroxy-3-phenyl-propionic acid 10,14,20-trihydroxy-7,13,15,17,19,21-hexamethyl-22-(1-methyl-penta-2,4-dienyl)-2-oxo-oxacyclodocosa-3,5,11,16-tetraen-8-yl ester 3-benzoylamino-2-hydroxy-3-phenyl-propionic acid 10,14,20-trihydroxy-7,13,15,17,19,21-hexamethyl-22-(1-methyl-penta-2,4-dienyl)-2-oxo-oxacyclodocosa-3,5,11,16-tetraen-8-yl ester 14,20-bis(tert-butyl-dimethyl-silanyloxy)-8,10-dihydroxy-7,13,15,17,19,21-hexamethyl-22-(1-methyl-penta-2,4-dienyl)-oxacyclodocosa-3,5,11,16-tetraen-2-one 14,20-bis(tert-butyl-dimethyl-silanyloxy)-10-hydroxy-8-methoxy-7,13,15,17,19,21-hexamethyl-22-(1-methyl-penta-2,4-dienyl)-oxacyclodocosa-3,5,11,16-tetraen-2-one