百科

(2R,6R)-2-((5'R,1'E,3'Z)-3'-ethyl-5'-methyl-8'-trimethylsilyl-octa-1',3'-dien-7'-yn-1'-yl)-6-isopropoxy-3,6-dihydro-2H-pyran

(2R,6R)-2-((5'R,1'E,3'Z)-3'-ethyl-5'-methyl-8'-trimethylsilyl-octa-1',3'-dien-7'-yn-1'-yl)-6-isopropoxy-3,6-dihydro-2H-pyran

CAS号：1092482-05-7

英文名：(2R,6R)-2-((5'R,1'E,3'Z)-3'-ethyl-5'-methyl-8'-trimethylsilyl-octa-1',3'-dien-7'-yn-1'-yl)-6-isopropoxy-3,6-dihydro-2H-pyran

分子式：C22H36O2Si

分子量：360.606

合成路线

(4R,5Z)-1-trimethylsilyl-4-methyl-6-iodo-5-octen-1-yne

(4R,5Z)-1-trimethylsilyl-4-methyl-6-iodo-5-octen-1-yne

(2R,6R,2'E)-2-(2'-iodovinyl)-6-isopropoxy-3,6-dihydro-2H-pyran

(2R,6R,2'E)-2-(2'-iodovinyl)-6-isopropoxy-3,6-dihydro-2H-pyran

(2R,6R)-2-((5'R,1'E,3'Z)-3'-ethyl-5'-methyl-8'-trimethylsilyl-octa-1',3'-dien-7'-yn-1'-yl)-6-isopropoxy-3,6-dihydro-2H-pyran

(2R,6R)-2-((5'R,1'E,3'Z)-3'-ethyl-5'-methyl-8'-trimethylsilyl-octa-1',3'-dien-7'-yn-1'-yl)-6-isopropoxy-3,6-dihydro-2H-pyran

上游原料

(2R,6R,2'E)-2-(2'-iodovinyl)-6-isopropoxy-3,6-dihydro-2H-pyran (4R,5Z)-1-trimethylsilyl-4-methyl-6-iodo-5-octen-1-yne

下游产品

(2R,6R)-2-((5'R,1'E,3'Z)-3'-ethyl-5'-methylocta-1',3'-dien-7'-yn-1'-yl)-6-isopropoxy-3,6-dihydro-2H-pyran