百科

(2R,6R)-2-((1'E,3'Z,5'R,7'E,9'E,11'R,12'S,13'S,14'R,15'S)-14'-(tert-butyldimethylsilyloxy)-3'-ethyl-5',9',11',13',15'-pentamethyl-12'-trimethylsilyloxy-heptadeca-1',3',7',9'-tetraen-1'-yl)-6-isopropoxy-3,6-dihydro-2H-pyran

CAS号：1092482-14-8

英文名：(2R,6R)-2-((1'E,3'Z,5'R,7'E,9'E,11'R,12'S,13'S,14'R,15'S)-14'-(tert-butyldimethylsilyloxy)-3'-ethyl-5',9',11',13',15'-pentamethyl-12'-trimethylsilyloxy-heptadeca-1',3',7',9'-tetraen-1'-yl)-6-isopropoxy-3,6-dihydro-2H-pyran

分子式：C41H76O4Si2

分子量：689.211

合成路线

1092482-02-4

(2R,6R)-2-((5'R,1'E,3'Z)-3'-ethyl-5'-methylocta-1',3'-dien-7'-yn-1'-yl)-6-isopropoxy-3,6-dihydro-2H-pyran

1092482-03-5

(4S,5S,6R,7R,8S)-4,6,8-trimethyl-5-trimethylsilyloxy-7-(tert-butyldimethylsilyloxy)-2-decyne

1092482-14-8

(2R,6R)-2-((1'E,3'Z,5'R,7'E,9'E,11'R,12'S,13'S,14'R,15'S)-14'-(tert-butyldimethylsilyloxy)-3'-ethyl-5',9',11',13',15'-pentamethyl-12'-trimethylsilyloxy-heptadeca-1',3',7',9'-tetraen-1'-yl)-6-isopropoxy-3,6-dihydro-2H-pyran

上游原料

(4S,5S,6R,7R,8S)-4,6,8-trimethyl-5-trimethylsilyloxy-7-(tert-butyldimethylsilyloxy)-2-decyne (2R,6R)-2-((5'R,1'E,3'Z)-3'-ethyl-5'-methylocta-1',3'-dien-7'-yn-1'-yl)-6-isopropoxy-3,6-dihydro-2H-pyran

下游产品

(2R,6R)-6-((1E,3Z,5R,7E,9E,11R,12S,13R,14R,15S)-14-((tert-butyldimethylsilyl)oxy)-3-ethyl-12-hydroxy-5,9,11,13,15-pentamethylheptadeca-1,3,7,9-tetraen-1-yl)-5,6-dihydro-2H-pyran-2-ol