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(3aS,7R,7aR)-methyl 7-hydroxy-2,2-dimethyl-3a,6,7,7a-tetrahydrobenzo[d][1,3]dioxole-5-carboxylate

(3aS,7R,7aR)-methyl 7-hydroxy-2,2-dimethyl-3a,6,7,7a-tetrahydrobenzo[d][1,3]dioxole-5-carboxylate

CAS号：109430-30-0

英文名：(3aS,7R,7aR)-methyl 7-hydroxy-2,2-dimethyl-3a,6,7,7a-tetrahydrobenzo[d][1,3]dioxole-5-carboxylate

分子式：C11H16O5

分子量：228.242

合成路线

3,4-isopropylidenequinide

3,4-isopropylidenequinide

(3aS,7R,7aR)-methyl 7-hydroxy-2,2-dimethyl-3a,6,7,7a-tetrahydrobenzo[d][1,3]dioxole-5-carboxylate

(3aS,7R,7aR)-methyl 7-hydroxy-2,2-dimethyl-3a,6,7,7a-tetrahydrobenzo[d][1,3]dioxole-5-carboxylate

methyl 3,4-O-isopropylidene-5-oxoquinate

methyl 3,4-O-isopropylidene-5-oxoquinate

(3aS,7R,7aR)-methyl 7-hydroxy-2,2-dimethyl-3a,6,7,7a-tetrahydrobenzo[d][1,3]dioxole-5-carboxylate

(3aS,7R,7aR)-methyl 7-hydroxy-2,2-dimethyl-3a,6,7,7a-tetrahydrobenzo[d][1,3]dioxole-5-carboxylate

(1'R,2'S,5'R)-Menthyl (1S,2R,3S,4S,5S,6S)-5,6-dihydroxy-3-(2-pyridylthio)-7-oxabicyclo<2.2.1>heptane-2-carboxylate

(1'R,2'S,5'R)-Menthyl (1S,2R,3S,4S,5S,6S)-5,6-dihydroxy-3-(2-pyridylthio)-7-oxabicyclo<2.2.1>heptane-2-carboxylate

(3aS,7R,7aR)-methyl 7-hydroxy-2,2-dimethyl-3a,6,7,7a-tetrahydrobenzo[d][1,3]dioxole-5-carboxylate

(3aS,7R,7aR)-methyl 7-hydroxy-2,2-dimethyl-3a,6,7,7a-tetrahydrobenzo[d][1,3]dioxole-5-carboxylate

Methyl (1R,2R,3S,4S,5R)-2,3-O,O-isopropylidene-2,3-dihydroxy-7-oxabicyclo<2.2.1>heptane-5-carboxylate

Methyl (1R,2R,3S,4S,5R)-2,3-O,O-isopropylidene-2,3-dihydroxy-7-oxabicyclo<2.2.1>heptane-5-carboxylate

(3aS,7R,7aR)-methyl 7-hydroxy-2,2-dimethyl-3a,6,7,7a-tetrahydrobenzo[d][1,3]dioxole-5-carboxylate

(3aS,7R,7aR)-methyl 7-hydroxy-2,2-dimethyl-3a,6,7,7a-tetrahydrobenzo[d][1,3]dioxole-5-carboxylate

(1R,2R,3S,4S)-3-((S)-Pyridine-2-sulfinyl)-7-oxa-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester

(1R,2R,3S,4S)-3-((S)-Pyridine-2-sulfinyl)-7-oxa-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester

(3aS,7R,7aR)-methyl 7-hydroxy-2,2-dimethyl-3a,6,7,7a-tetrahydrobenzo[d][1,3]dioxole-5-carboxylate

(3aS,7R,7aR)-methyl 7-hydroxy-2,2-dimethyl-3a,6,7,7a-tetrahydrobenzo[d][1,3]dioxole-5-carboxylate

(1'R,2'S,5'R)-Menthyl (1R,2R,3S,4S)-3-(2-pyridylthio)-7-oxabicyclo<2.2.1>hept-5-ene-2-carboxylate

(1'R,2'S,5'R)-Menthyl (1R,2R,3S,4S)-3-(2-pyridylthio)-7-oxabicyclo<2.2.1>hept-5-ene-2-carboxylate

(3aS,7R,7aR)-methyl 7-hydroxy-2,2-dimethyl-3a,6,7,7a-tetrahydrobenzo[d][1,3]dioxole-5-carboxylate

(3aS,7R,7aR)-methyl 7-hydroxy-2,2-dimethyl-3a,6,7,7a-tetrahydrobenzo[d][1,3]dioxole-5-carboxylate

(1S,2S,3S,4S,5S,6S)-2-Hydroxymethyl-5,6-O,O-isopropylidene-5,6-dihydroxy-3-(2-pyridylthio)-7-oxabicyclo<2.2.1>heptane

(1S,2S,3S,4S,5S,6S)-2-Hydroxymethyl-5,6-O,O-isopropylidene-5,6-dihydroxy-3-(2-pyridylthio)-7-oxabicyclo<2.2.1>heptane

(3aS,7R,7aR)-methyl 7-hydroxy-2,2-dimethyl-3a,6,7,7a-tetrahydrobenzo[d][1,3]dioxole-5-carboxylate

(3aS,7R,7aR)-methyl 7-hydroxy-2,2-dimethyl-3a,6,7,7a-tetrahydrobenzo[d][1,3]dioxole-5-carboxylate

(1'R,2'S,5'R)-Menthyl (1S,2R,3S,4S,5S,6S)-5,6-O,O-isopropylidene-5,6-dihydroxy-3-(2-pyridylthio)-7-oxabicyclo<2.2.1>heptane-2-carboxylate

(1'R,2'S,5'R)-Menthyl (1S,2R,3S,4S,5S,6S)-5,6-O,O-isopropylidene-5,6-dihydroxy-3-(2-pyridylthio)-7-oxabicyclo<2.2.1>heptane-2-carboxylate

(3aS,7R,7aR)-methyl 7-hydroxy-2,2-dimethyl-3a,6,7,7a-tetrahydrobenzo[d][1,3]dioxole-5-carboxylate

(3aS,7R,7aR)-methyl 7-hydroxy-2,2-dimethyl-3a,6,7,7a-tetrahydrobenzo[d][1,3]dioxole-5-carboxylate

上游原料

Methyl (1R,2R,3S,4S,5R)-2,3-O,O-isopropylidene-2,3-dihydroxy-7-oxabicyclo<2.2.1>heptane-5-carboxylate (1'R,2'S,5'R)-Menthyl (1S,2R,3S,4S,5S,6S)-5,6-O,O-isopropylidene-5,6-dihydroxy-3-(2-pyridylthio)-7-oxabicyclo<2.2.1>heptane-2-carboxylate methyl 3,4-O-isopropylidene-5-oxoquinate (1'R,2'S,5'R)-Menthyl (1S,2R,3S,4S,5S,6S)-5,6-dihydroxy-3-(2-pyridylthio)-7-oxabicyclo<2.2.1>heptane-2-carboxylate (1'R,2'S,5'R)-Menthyl (1R,2R,3S,4S)-3-(2-pyridylthio)-7-oxabicyclo<2.2.1>hept-5-ene-2-carboxylate 3,4-isopropylidenequinide (1S,2S,3S,4S,5S,6S)-2-Hydroxymethyl-5,6-O,O-isopropylidene-5,6-dihydroxy-3-(2-pyridylthio)-7-oxabicyclo<2.2.1>heptane (1R,2R,3S,4S)-3-((S)-Pyridine-2-sulfinyl)-7-oxa-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester

下游产品

(1R,2R,3S,4S,5R)-2-acetoxy-1-(acetoxymethyl)-5-(t-butyldimethylsiloxy)-3,4-(isopropylidenedioxy)cyclohexane