百科

rel-(2ξ,4S,5S)-4-[(E)-3-methyl-6-hydroxy-3-hexenyl]-5-[(E)-2-methyl-5-tert-butyldimethylsilyloxy-1-pentenyl]-2-methoxy-1-oxacyclopentane

rel-(2ξ,4S,5S)-4-[(E)-3-methyl-6-hydroxy-3-hexenyl]-5-[(E)-2-methyl-5-tert-butyldimethylsilyloxy-1-pentenyl]-2-methoxy-1-oxacyclopentane

CAS号：110965-92-9

英文名：rel-(2ξ,4S,5S)-4-[(E)-3-methyl-6-hydroxy-3-hexenyl]-5-[(E)-2-methyl-5-tert-butyldimethylsilyloxy-1-pentenyl]-2-methoxy-1-oxacyclopentane

分子式：C24H44O3Si

分子量：408.69

合成路线

(2E,6E)-6-methylnona-2,6,8-trien-1-ol

(2E,6E)-6-methylnona-2,6,8-trien-1-ol

rel-(2ξ,4S,5S)-4-[(E)-3-methyl-6-hydroxy-3-hexenyl]-5-[(E)-2-methyl-5-tert-butyldimethylsilyloxy-1-pentenyl]-2-methoxy-1-oxacyclopentane

rel-(2ξ,4S,5S)-4-[(E)-3-methyl-6-hydroxy-3-hexenyl]-5-[(E)-2-methyl-5-tert-butyldimethylsilyloxy-1-pentenyl]-2-methoxy-1-oxacyclopentane

(E)-acetic acid 6-hydroxy-3-methylhex-2-enyl ester

(E)-acetic acid 6-hydroxy-3-methylhex-2-enyl ester

rel-(2ξ,4S,5S)-4-[(E)-3-methyl-6-hydroxy-3-hexenyl]-5-[(E)-2-methyl-5-tert-butyldimethylsilyloxy-1-pentenyl]-2-methoxy-1-oxacyclopentane

rel-(2ξ,4S,5S)-4-[(E)-3-methyl-6-hydroxy-3-hexenyl]-5-[(E)-2-methyl-5-tert-butyldimethylsilyloxy-1-pentenyl]-2-methoxy-1-oxacyclopentane

methyl (E,E)-6-methyl-2,6,8-nonatrienonate

methyl (E,E)-6-methyl-2,6,8-nonatrienonate

rel-(2ξ,4S,5S)-4-[(E)-3-methyl-6-hydroxy-3-hexenyl]-5-[(E)-2-methyl-5-tert-butyldimethylsilyloxy-1-pentenyl]-2-methoxy-1-oxacyclopentane

rel-(2ξ,4S,5S)-4-[(E)-3-methyl-6-hydroxy-3-hexenyl]-5-[(E)-2-methyl-5-tert-butyldimethylsilyloxy-1-pentenyl]-2-methoxy-1-oxacyclopentane

methyl (E,E)-6-methyl-7-formyl-2,6-octadienoate

methyl (E,E)-6-methyl-7-formyl-2,6-octadienoate

rel-(2ξ,4S,5S)-4-[(E)-3-methyl-6-hydroxy-3-hexenyl]-5-[(E)-2-methyl-5-tert-butyldimethylsilyloxy-1-pentenyl]-2-methoxy-1-oxacyclopentane

rel-(2ξ,4S,5S)-4-[(E)-3-methyl-6-hydroxy-3-hexenyl]-5-[(E)-2-methyl-5-tert-butyldimethylsilyloxy-1-pentenyl]-2-methoxy-1-oxacyclopentane

(2E,6E)-methyl 8-hydroxy-6-methylocta-2,6-dienoate

(2E,6E)-methyl 8-hydroxy-6-methylocta-2,6-dienoate

rel-(2ξ,4S,5S)-4-[(E)-3-methyl-6-hydroxy-3-hexenyl]-5-[(E)-2-methyl-5-tert-butyldimethylsilyloxy-1-pentenyl]-2-methoxy-1-oxacyclopentane

rel-(2ξ,4S,5S)-4-[(E)-3-methyl-6-hydroxy-3-hexenyl]-5-[(E)-2-methyl-5-tert-butyldimethylsilyloxy-1-pentenyl]-2-methoxy-1-oxacyclopentane

(2E,6E)-methyl-8-acetoxy-6-methylocta-2,6-dienoate

(2E,6E)-methyl-8-acetoxy-6-methylocta-2,6-dienoate

rel-(2ξ,4S,5S)-4-[(E)-3-methyl-6-hydroxy-3-hexenyl]-5-[(E)-2-methyl-5-tert-butyldimethylsilyloxy-1-pentenyl]-2-methoxy-1-oxacyclopentane

rel-(2ξ,4S,5S)-4-[(E)-3-methyl-6-hydroxy-3-hexenyl]-5-[(E)-2-methyl-5-tert-butyldimethylsilyloxy-1-pentenyl]-2-methoxy-1-oxacyclopentane

N,N-diisopropyl (E,E)-6-methyl-2,6,8-nonatrienyl carbamate

N,N-diisopropyl (E,E)-6-methyl-2,6,8-nonatrienyl carbamate

rel-(2ξ,4S,5S)-4-[(E)-3-methyl-6-hydroxy-3-hexenyl]-5-[(E)-2-methyl-5-tert-butyldimethylsilyloxy-1-pentenyl]-2-methoxy-1-oxacyclopentane

rel-(2ξ,4S,5S)-4-[(E)-3-methyl-6-hydroxy-3-hexenyl]-5-[(E)-2-methyl-5-tert-butyldimethylsilyloxy-1-pentenyl]-2-methoxy-1-oxacyclopentane

上游原料

(E)-acetic acid 6-hydroxy-3-methylhex-2-enyl ester methyl (E,E)-6-methyl-7-formyl-2,6-octadienoate (2E,6E)-methyl 8-hydroxy-6-methylocta-2,6-dienoate (2E,6E)-6-methylnona-2,6,8-trien-1-ol methyl (E,E)-6-methyl-2,6,8-nonatrienonate (2E,6E)-methyl-8-acetoxy-6-methylocta-2,6-dienoate N,N-diisopropyl (E,E)-6-methyl-2,6,8-nonatrienyl carbamate

下游产品

(6E,10Z,14Z)-6,14-dimethyl-3-methylidene-2-oxo-3a,4,5,8,9,12,13,15a-octahydrocyclotetradeca[b]furan-10-carboxylic acid