百科

(3aα,4aS*,15bβ,15cα)-(+/-)-3a,4,6,7,9,10,15b,15c-octahydro-2,2-dimethyl-5H-[1,3]dioxolo[4,5-h]-1,3-dioxolo[4,5]cyclopenta[1,2-a]pyrrolo[2,1-b][3]-benzazepine

(3aα,4aS*,15bβ,15cα)-(+/-)-3a,4,6,7,9,10,15b,15c-octahydro-2,2-dimethyl-5H-[1,3]dioxolo[4,5-h]-1,3-dioxolo[4,5]cyclopenta[1,2-a]pyrrolo[2,1-b][3]-benzazepine

CAS号：113668-89-6

英文名：(3aα,4aS*,15bβ,15cα)-(+/-)-3a,4,6,7,9,10,15b,15c-octahydro-2,2-dimethyl-5H-[1,3]dioxolo[4,5-h]-1,3-dioxolo[4,5]cyclopenta[1,2-a]pyrrolo[2,1-b][3]-benzazepine

分子式：C20H25NO4

分子量：343.417

合成路线

(3aα,4aS*,15bβ,15cα)-(+/-)-3a,10,15b,15c-tetrahydro-2,2-dimethyl-7H-[1,3]dioxolo[4,5-h]-1,3-dioxolo[4,5]cyclopenta[1,2-a]-[3]pyrrolo[2,1-b][3]benzazapin-9(4H)-one

(3aα,4aS*,15bβ,15cα)-(+/-)-3a,10,15b,15c-tetrahydro-2,2-dimethyl-7H-[1,3]dioxolo[4,5-h]-1,3-dioxolo[4,5]cyclopenta[1,2-a]-[3]pyrrolo[2,1-b][3]benzazapin-9(4H)-one

(3aα,4aS*,15bβ,15cα)-(+/-)-3a,4,6,7,9,10,15b,15c-octahydro-2,2-dimethyl-5H-[1,3]dioxolo[4,5-h]-1,3-dioxolo[4,5]cyclopenta[1,2-a]pyrrolo[2,1-b][3]-benzazepine

(3aα,4aS*,15bβ,15cα)-(+/-)-3a,4,6,7,9,10,15b,15c-octahydro-2,2-dimethyl-5H-[1,3]dioxolo[4,5-h]-1,3-dioxolo[4,5]cyclopenta[1,2-a]pyrrolo[2,1-b][3]-benzazepine

(2S,3R)-rac-2,3-(isopropylidenedioxy)-5-(phenylsulfonyl)-4-cyclopentene

(2S,3R)-rac-2,3-(isopropylidenedioxy)-5-(phenylsulfonyl)-4-cyclopentene

(3aα,4aS*,15bβ,15cα)-(+/-)-3a,4,6,7,9,10,15b,15c-octahydro-2,2-dimethyl-5H-[1,3]dioxolo[4,5-h]-1,3-dioxolo[4,5]cyclopenta[1,2-a]pyrrolo[2,1-b][3]-benzazepine

(3aα,4aS*,15bβ,15cα)-(+/-)-3a,4,6,7,9,10,15b,15c-octahydro-2,2-dimethyl-5H-[1,3]dioxolo[4,5-h]-1,3-dioxolo[4,5]cyclopenta[1,2-a]pyrrolo[2,1-b][3]-benzazepine

上游原料

(3aα,4aS*,15bβ,15cα)-(+/-)-3a,10,15b,15c-tetrahydro-2,2-dimethyl-7H-[1,3]dioxolo[4,5-h]-1,3-dioxolo[4,5]cyclopenta[1,2-a]-[3]pyrrolo[2,1-b][3]benzazapin-9(4H)-one (2S,3R)-rac-2,3-(isopropylidenedioxy)-5-(phenylsulfonyl)-4-cyclopentene

下游产品

(±)-三尖杉碱