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(-)-4'-O-p-nitrobenzoyl-3'-N-trifluoroacetyl-7,9-bis-epi-11-deoxydaunomycin

(-)-4'-O-p-nitrobenzoyl-3'-N-trifluoroacetyl-7,9-bis-epi-11-deoxydaunomycin

CAS号：115043-56-6

英文名：(-)-4'-O-p-nitrobenzoyl-3'-N-trifluoroacetyl-7,9-bis-epi-11-deoxydaunomycin

分子式：C36H31F3N2O13

分子量：756.632

合成路线

(2S,3S,4S,6R)-6-(((1R,3R)-3,12-dihydroxy-10-methoxy-3-(2-methyl-1,3-dioxolan-2-yl)-6,11-dioxo-1,2,3,4,6,11-hexahydrotetracen-1-yl)oxy)-2-methyl-4-(2,2,2-trifluoroacetamido)tetrahydro-2H-pyran-3-yl 4-nitrobenzoate

(2S,3S,4S,6R)-6-(((1R,3R)-3,12-dihydroxy-10-methoxy-3-(2-methyl-1,3-dioxolan-2-yl)-6,11-dioxo-1,2,3,4,6,11-hexahydrotetracen-1-yl)oxy)-2-methyl-4-(2,2,2-trifluoroacetamido)tetrahydro-2H-pyran-3-yl 4-nitrobenzoate

(-)-4'-O-p-nitrobenzoyl-3'-N-trifluoroacetyl-7,9-bis-epi-11-deoxydaunomycin

(-)-4'-O-p-nitrobenzoyl-3'-N-trifluoroacetyl-7,9-bis-epi-11-deoxydaunomycin

(+/-)-9-[1,1-(ethylenedioxy)ethyl]-cis-6,7,9-trihydroxy-4-methoxy-7,8,9,10-tetrahydronaphthacene-5,12-dione

(+/-)-9-[1,1-(ethylenedioxy)ethyl]-cis-6,7,9-trihydroxy-4-methoxy-7,8,9,10-tetrahydronaphthacene-5,12-dione

(-)-4'-O-p-nitrobenzoyl-3'-N-trifluoroacetyl-7,9-bis-epi-11-deoxydaunomycin

(-)-4'-O-p-nitrobenzoyl-3'-N-trifluoroacetyl-7,9-bis-epi-11-deoxydaunomycin

(+/-)-9-[1,1-(ethylenedioxy)ethyl]-6,9-dihydroxy-4-methoxy-7,8,9,10-tetrahydronaphthacene-5,12-dione

(+/-)-9-[1,1-(ethylenedioxy)ethyl]-6,9-dihydroxy-4-methoxy-7,8,9,10-tetrahydronaphthacene-5,12-dione

(-)-4'-O-p-nitrobenzoyl-3'-N-trifluoroacetyl-7,9-bis-epi-11-deoxydaunomycin

(-)-4'-O-p-nitrobenzoyl-3'-N-trifluoroacetyl-7,9-bis-epi-11-deoxydaunomycin

(+/-)-6,9-dihydroxy-4-methoxy-9-(trimethylsilyl)ethynyl-7,8,9,10-tetrahydronaphthacene-5,12-dione

(+/-)-6,9-dihydroxy-4-methoxy-9-(trimethylsilyl)ethynyl-7,8,9,10-tetrahydronaphthacene-5,12-dione

(-)-4'-O-p-nitrobenzoyl-3'-N-trifluoroacetyl-7,9-bis-epi-11-deoxydaunomycin

(-)-4'-O-p-nitrobenzoyl-3'-N-trifluoroacetyl-7,9-bis-epi-11-deoxydaunomycin

上游原料

(+/-)-9-[1,1-(ethylenedioxy)ethyl]-cis-6,7,9-trihydroxy-4-methoxy-7,8,9,10-tetrahydronaphthacene-5,12-dione (+/-)-9-[1,1-(ethylenedioxy)ethyl]-6,9-dihydroxy-4-methoxy-7,8,9,10-tetrahydronaphthacene-5,12-dione (+/-)-6,9-dihydroxy-4-methoxy-9-(trimethylsilyl)ethynyl-7,8,9,10-tetrahydronaphthacene-5,12-dione (2S,3S,4S,6R)-6-(((1R,3R)-3,12-dihydroxy-10-methoxy-3-(2-methyl-1,3-dioxolan-2-yl)-6,11-dioxo-1,2,3,4,6,11-hexahydrotetracen-1-yl)oxy)-2-methyl-4-(2,2,2-trifluoroacetamido)tetrahydro-2H-pyran-3-yl 4-nitrobenzoate

下游产品

11-脱氧柔红霉素