百科

5-叠氮基-6-(叔-丁基二甲基硅烷基)-2,3-O-异亚丙基L-古洛糖酸-1,4-内酯

5-叠氮基-6-(叔-丁基二甲基硅烷基)-2,3-O-异亚丙基L-古洛糖酸-1,4-内酯

CAS号：118464-49-6

英文名：(3aS,6R,6aS)-6-[(1S)-1-azido-2-[tert-butyl(dimethyl)silyl]oxyethyl]-2,2-dimethyl-6,6a-dihydro-3aH-furo[3,4-d][1,3]dioxol-4-one

分子式：C15H27N3O5Si

分子量：357.477

合成路线

6-O-tert-butyldimethylsilyl-2,3-O-isopropylidene-L-gulonolactone

6-O-tert-butyldimethylsilyl-2,3-O-isopropylidene-L-gulonolactone

5-叠氮基-6-(叔-丁基二甲基硅烷基)-2,3-O-异亚丙基L-古洛糖酸-1,4-内酯

5-叠氮基-6-(叔-丁基二甲基硅烷基)-2,3-O-异亚丙基L-古洛糖酸-1,4-内酯

(S)-2-((tert-butyldimethylsilyl)oxy)-1-((3aS,4S,6aS)-2,2-dimethyl-6-oxotetrahydrofuro[3,4-d][1,3]dioxol-4-yl)ethyl trifluoromethanesulfonate

(S)-2-((tert-butyldimethylsilyl)oxy)-1-((3aS,4S,6aS)-2,2-dimethyl-6-oxotetrahydrofuro[3,4-d][1,3]dioxol-4-yl)ethyl trifluoromethanesulfonate

5-叠氮基-6-(叔-丁基二甲基硅烷基)-2,3-O-异亚丙基L-古洛糖酸-1,4-内酯

5-叠氮基-6-(叔-丁基二甲基硅烷基)-2,3-O-异亚丙基L-古洛糖酸-1,4-内酯

6-(2,2-二甲基-[1,3]二氧杂烷-4-基) -2,2-二甲基-二氢-呋喃并[3,4-d][1 ,3]二氧代-4-酮

6-(2,2-二甲基-[1,3]二氧杂烷-4-基) -2,2-二甲基-二氢-呋喃并[3,4-d][1 ,3]二氧代-4-酮

5-叠氮基-6-(叔-丁基二甲基硅烷基)-2,3-O-异亚丙基L-古洛糖酸-1,4-内酯

5-叠氮基-6-(叔-丁基二甲基硅烷基)-2,3-O-异亚丙基L-古洛糖酸-1,4-内酯

2,3-O-异亚丙基-L-古洛糖酸内酯

2,3-O-异亚丙基-L-古洛糖酸内酯

5-叠氮基-6-(叔-丁基二甲基硅烷基)-2,3-O-异亚丙基L-古洛糖酸-1,4-内酯

5-叠氮基-6-(叔-丁基二甲基硅烷基)-2,3-O-异亚丙基L-古洛糖酸-1,4-内酯

L-古洛糖酸-γ-内酯

L-古洛糖酸-γ-内酯

5-叠氮基-6-(叔-丁基二甲基硅烷基)-2,3-O-异亚丙基L-古洛糖酸-1,4-内酯

5-叠氮基-6-(叔-丁基二甲基硅烷基)-2,3-O-异亚丙基L-古洛糖酸-1,4-内酯

上游原料

L-古洛糖酸-γ-内酯 6-O-tert-butyldimethylsilyl-2,3-O-isopropylidene-L-gulonolactone (S)-2-((tert-butyldimethylsilyl)oxy)-1-((3aS,4S,6aS)-2,2-dimethyl-6-oxotetrahydrofuro[3,4-d][1,3]dioxol-4-yl)ethyl trifluoromethanesulfonate 6-(2,2-二甲基-[1,3]二氧杂烷-4-基) -2,2-二甲基-二氢-呋喃并[3,4-d][1 ,3]二氧代-4-酮 2,3-O-异亚丙基-L-古洛糖酸内酯

下游产品

(3aS,3bR,7aR,11aS,11bR)-2,2,5,5-四甲基六氢-3bH-[1,3]二恶英并[4,5-e][1,3]二氧杂环戊并[4,5-c]咪唑并[1,2-a]吡啶-9,10-二酮甘露糖酸-delta-内酰胺 2-[(氨基氧代乙酰基)氨基]-2-脱氧-1,3:4,5-二-O-(异丙亚基)-D-甘露醇 (5R,6R,7S,8R,8aS)-6,7,8-三羟基-5-(羟基甲基)-1,5,6,7,8,8a-六氢咪唑并[1,2-a]吡啶-2,3-二酮