百科

(1S,4R,5R,7R,8R)-4,8-dimethyl-2,2-ethylenedioxy-7-p-toluenesulfonyloxybicyclo[3.3.0]octane

(1S,4R,5R,7R,8R)-4,8-dimethyl-2,2-ethylenedioxy-7-p-toluenesulfonyloxybicyclo[3.3.0]octane

CAS号：120657-94-5

英文名：(1S,4R,5R,7R,8R)-4,8-dimethyl-2,2-ethylenedioxy-7-p-toluenesulfonyloxybicyclo[3.3.0]octane

分子式：C19H26O5S

分子量：366.472

合成路线

(3R,4S)-3-methyl-4-(3-oxobutyl)cyclopentanone

(3R,4S)-3-methyl-4-(3-oxobutyl)cyclopentanone

(1S,4R,5R,7R,8R)-4,8-dimethyl-2,2-ethylenedioxy-7-p-toluenesulfonyloxybicyclo[3.3.0]octane

(1S,4R,5R,7R,8R)-4,8-dimethyl-2,2-ethylenedioxy-7-p-toluenesulfonyloxybicyclo[3.3.0]octane

(1S,4R,5R)-4,8-dimethyl-2,2-ethylenedioxybicyclo[3.3.0]oct-7-ene

(1S,4R,5R)-4,8-dimethyl-2,2-ethylenedioxybicyclo[3.3.0]oct-7-ene

(1S,4R,5R,7R,8R)-4,8-dimethyl-2,2-ethylenedioxy-7-p-toluenesulfonyloxybicyclo[3.3.0]octane

(1S,4R,5R,7R,8R)-4,8-dimethyl-2,2-ethylenedioxy-7-p-toluenesulfonyloxybicyclo[3.3.0]octane

(1S,4R,5R,7S,8S)-4,8-dimethyl-2,2-ethylenedioxy-7-hydroxybicyclo[3.3.0]octane

(1S,4R,5R,7S,8S)-4,8-dimethyl-2,2-ethylenedioxy-7-hydroxybicyclo[3.3.0]octane

(1S,4R,5R,7R,8R)-4,8-dimethyl-2,2-ethylenedioxy-7-p-toluenesulfonyloxybicyclo[3.3.0]octane

(1S,4R,5R,7R,8R)-4,8-dimethyl-2,2-ethylenedioxy-7-p-toluenesulfonyloxybicyclo[3.3.0]octane

(1S,4R,5R,8R)-4,8-dimethyl-2,2-ethylenedioxybicyclo[3.3.0]octan-7-one

(1S,4R,5R,8R)-4,8-dimethyl-2,2-ethylenedioxybicyclo[3.3.0]octan-7-one

(1S,4R,5R,7R,8R)-4,8-dimethyl-2,2-ethylenedioxy-7-p-toluenesulfonyloxybicyclo[3.3.0]octane

(1S,4R,5R,7R,8R)-4,8-dimethyl-2,2-ethylenedioxy-7-p-toluenesulfonyloxybicyclo[3.3.0]octane

(1S,4R,5R,8S)-4,8-dimethyl-2,2-ethylenedioxybicyclo[3.3.0]octan-7-one

(1S,4R,5R,8S)-4,8-dimethyl-2,2-ethylenedioxybicyclo[3.3.0]octan-7-one

(1S,4R,5R,7R,8R)-4,8-dimethyl-2,2-ethylenedioxy-7-p-toluenesulfonyloxybicyclo[3.3.0]octane

(1S,4R,5R,7R,8R)-4,8-dimethyl-2,2-ethylenedioxy-7-p-toluenesulfonyloxybicyclo[3.3.0]octane

上游原料

(1S,4R,5R,8S)-4,8-dimethyl-2,2-ethylenedioxybicyclo[3.3.0]octan-7-one (3R,4S)-3-methyl-4-(3-oxobutyl)cyclopentanone (1S,4R,5R,8R)-4,8-dimethyl-2,2-ethylenedioxybicyclo[3.3.0]octan-7-one (1S,4R,5R)-4,8-dimethyl-2,2-ethylenedioxybicyclo[3.3.0]oct-7-ene (1S,4R,5R,7S,8S)-4,8-dimethyl-2,2-ethylenedioxy-7-hydroxybicyclo[3.3.0]octane

下游产品

(1R,4R,5R,8S)-4,8-dimethylbicyclo[3.3.0]octan-2-one (1R,4S,5R,8S)-4,8-dimethyl-2-trimethylsilyloxybicyclo[3.3.0]oct-2-ene 假荆芥内酯