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(1R,4S,5R,8S)-4,8-dimethyl-2-trimethylsilyloxybicyclo[3.3.0]oct-2-ene

(1R,4S,5R,8S)-4,8-dimethyl-2-trimethylsilyloxybicyclo[3.3.0]oct-2-ene

CAS号：120709-99-1

英文名：(1R,4S,5R,8S)-4,8-dimethyl-2-trimethylsilyloxybicyclo[3.3.0]oct-2-ene

分子式：C13H24OSi

分子量：224.415

合成路线

(3R,4S)-3-methyl-4-(3-oxobutyl)cyclopentanone

(3R,4S)-3-methyl-4-(3-oxobutyl)cyclopentanone

(1R,4S,5R,8S)-4,8-dimethyl-2-trimethylsilyloxybicyclo[3.3.0]oct-2-ene

(1R,4S,5R,8S)-4,8-dimethyl-2-trimethylsilyloxybicyclo[3.3.0]oct-2-ene

(1S,4R,5R)-4,8-dimethyl-2,2-ethylenedioxybicyclo[3.3.0]oct-7-ene

(1S,4R,5R)-4,8-dimethyl-2,2-ethylenedioxybicyclo[3.3.0]oct-7-ene

(1R,4S,5R,8S)-4,8-dimethyl-2-trimethylsilyloxybicyclo[3.3.0]oct-2-ene

(1R,4S,5R,8S)-4,8-dimethyl-2-trimethylsilyloxybicyclo[3.3.0]oct-2-ene

(1S,4R,5R,7R,8R)-4,8-dimethyl-2,2-ethylenedioxy-7-p-toluenesulfonyloxybicyclo[3.3.0]octane

(1S,4R,5R,7R,8R)-4,8-dimethyl-2,2-ethylenedioxy-7-p-toluenesulfonyloxybicyclo[3.3.0]octane

(1R,4S,5R,8S)-4,8-dimethyl-2-trimethylsilyloxybicyclo[3.3.0]oct-2-ene

(1R,4S,5R,8S)-4,8-dimethyl-2-trimethylsilyloxybicyclo[3.3.0]oct-2-ene

(1S,4R,5R,7S,8S)-4,8-dimethyl-2,2-ethylenedioxy-7-hydroxybicyclo[3.3.0]octane

(1S,4R,5R,7S,8S)-4,8-dimethyl-2,2-ethylenedioxy-7-hydroxybicyclo[3.3.0]octane

(1R,4S,5R,8S)-4,8-dimethyl-2-trimethylsilyloxybicyclo[3.3.0]oct-2-ene

(1R,4S,5R,8S)-4,8-dimethyl-2-trimethylsilyloxybicyclo[3.3.0]oct-2-ene

(1S,4R,5R,7R,8R)-4,8-dimethyl-2,2-ethylenedioxy-7-hydroxybicyclo[3.3.0]octane

(1S,4R,5R,7R,8R)-4,8-dimethyl-2,2-ethylenedioxy-7-hydroxybicyclo[3.3.0]octane

(1R,4S,5R,8S)-4,8-dimethyl-2-trimethylsilyloxybicyclo[3.3.0]oct-2-ene

(1R,4S,5R,8S)-4,8-dimethyl-2-trimethylsilyloxybicyclo[3.3.0]oct-2-ene

(1S,4R,5R,8R)-4,8-dimethyl-2,2-ethylenedioxybicyclo[3.3.0]octan-7-one

(1S,4R,5R,8R)-4,8-dimethyl-2,2-ethylenedioxybicyclo[3.3.0]octan-7-one

(1R,4S,5R,8S)-4,8-dimethyl-2-trimethylsilyloxybicyclo[3.3.0]oct-2-ene

(1R,4S,5R,8S)-4,8-dimethyl-2-trimethylsilyloxybicyclo[3.3.0]oct-2-ene

上游原料

(1S,4R,5R,7R,8R)-4,8-dimethyl-2,2-ethylenedioxy-7-hydroxybicyclo[3.3.0]octane (3R,4S)-3-methyl-4-(3-oxobutyl)cyclopentanone (1S,4R,5R,8R)-4,8-dimethyl-2,2-ethylenedioxybicyclo[3.3.0]octan-7-one (1S,4R,5R,7R,8R)-4,8-dimethyl-2,2-ethylenedioxy-7-p-toluenesulfonyloxybicyclo[3.3.0]octane (1S,4R,5R)-4,8-dimethyl-2,2-ethylenedioxybicyclo[3.3.0]oct-7-ene (1S,4R,5R,7S,8S)-4,8-dimethyl-2,2-ethylenedioxy-7-hydroxybicyclo[3.3.0]octane

下游产品

假荆芥内酯