百科

<(+/-)-(1α,2β,3α,4α,4aα,11bα)>-1,2,3,4,4a,11b-Hexahydro-3,4-dihydroxy-1-acetoxy-2-bromo-7-(phenylmethoxy)-6H-<1,3>benzodioxolo<5,6-c><1>benzopyran-2-one

CAS号：120882-51-1

英文名：<(+/-)-(1α,2β,3α,4α,4aα,11bα)>-1,2,3,4,4a,11b-Hexahydro-3,4-dihydroxy-1-acetoxy-2-bromo-7-(phenylmethoxy)-6H-<1,3>benzodioxolo<5,6-c><1>benzopyran-2-one

分子式：C23H21BrO9

分子量：521.311

合成路线

120882-41-9

N,N-Diethyl-4-<(tert-butyldimethylsilyl)oxy>-6-(1,3-butadienyl)-1,3-benzodioxole-5-carboxamide

120882-51-1

<(+/-)-(1α,2β,3α,4α,4aα,11bα)>-1,2,3,4,4a,11b-Hexahydro-3,4-dihydroxy-1-acetoxy-2-bromo-7-(phenylmethoxy)-6H-<1,3>benzodioxolo<5,6-c><1>benzopyran-2-one

120882-49-7

<(+/-)-(1α,2β,4aα,11bα)>-1,2,4a,11b-Tetrahydro-1-acetoxy-2-bromo-7-(phenylmethoxy)-6H-<1,3>benzodioxolo<5,6-c><1>benzopyran-6-one

120882-51-1

<(+/-)-(1α,2β,3α,4α,4aα,11bα)>-1,2,3,4,4a,11b-Hexahydro-3,4-dihydroxy-1-acetoxy-2-bromo-7-(phenylmethoxy)-6H-<1,3>benzodioxolo<5,6-c><1>benzopyran-2-one

120882-43-1

N,N-Diethyl-4-<(tert-butyldimethylsilyl)oxy>-6-(2,5-cyclohexadien-1-yl)-1,3-benzodioxole-5-carboxamide

120882-51-1

<(+/-)-(1α,2β,3α,4α,4aα,11bα)>-1,2,3,4,4a,11b-Hexahydro-3,4-dihydroxy-1-acetoxy-2-bromo-7-(phenylmethoxy)-6H-<1,3>benzodioxolo<5,6-c><1>benzopyran-2-one

120882-47-5

<(+/-)-(1α,2α,4α,4aα,11bα)>-1,2,3,4,4a,11b-Hexahydro-1,2-dihydroxy-4-iodo-7-(phenylmethoxy)-6H-<1,3>benzodioxolo<5,6-c><1>benzopyran-6-one

120882-51-1

<(+/-)-(1α,2β,3α,4α,4aα,11bα)>-1,2,3,4,4a,11b-Hexahydro-3,4-dihydroxy-1-acetoxy-2-bromo-7-(phenylmethoxy)-6H-<1,3>benzodioxolo<5,6-c><1>benzopyran-2-one

120882-48-6

<(+/-)-(1α,2α,4aα,11bα)>-1,2,4a,11b-Tetrahydro-1,2-dihydroxy-7-(phenylmethoxy)-6H-<1,3>benzodioxolo<5,6-c><1>benzopyran-6-one

120882-51-1

<(+/-)-(1α,2β,3α,4α,4aα,11bα)>-1,2,3,4,4a,11b-Hexahydro-3,4-dihydroxy-1-acetoxy-2-bromo-7-(phenylmethoxy)-6H-<1,3>benzodioxolo<5,6-c><1>benzopyran-2-one

120882-46-4

<(+/-)-(4α,4aα,11bα)>-3,4,4a,11b-Tetrahydro-4-iodo-7-(phenylmethoxy)-6H-<1,3>benzodioxolo<5,6-c><1>benzopyran-6-one

120882-51-1

<(+/-)-(1α,2β,3α,4α,4aα,11bα)>-1,2,3,4,4a,11b-Hexahydro-3,4-dihydroxy-1-acetoxy-2-bromo-7-(phenylmethoxy)-6H-<1,3>benzodioxolo<5,6-c><1>benzopyran-2-one

120882-44-2

N,N-Diethyl-4-hydroxy-6-(2,5-cyclohexadien-1-yl)-1,3-benzodioxole-5-carboxamide

120882-51-1

<(+/-)-(1α,2β,3α,4α,4aα,11bα)>-1,2,3,4,4a,11b-Hexahydro-3,4-dihydroxy-1-acetoxy-2-bromo-7-(phenylmethoxy)-6H-<1,3>benzodioxolo<5,6-c><1>benzopyran-2-one

120882-42-0

N,N-Diethyl-4-<(tert-butyldimethylsilyl)oxy>-6-<5-(phenylsulfonyl)-6-nitro-2-cyclohexen-1-yl>-1,3-benzodioxole-5-carboxamide

120882-51-1

<(+/-)-(1α,2β,3α,4α,4aα,11bα)>-1,2,3,4,4a,11b-Hexahydro-3,4-dihydroxy-1-acetoxy-2-bromo-7-(phenylmethoxy)-6H-<1,3>benzodioxolo<5,6-c><1>benzopyran-2-one

120882-38-4

N,N-Diethyl-4-<(tert-butyldimethylsilyl)oxy>-1,3-benzodioxole-5-carboxamide

120882-51-1

<(+/-)-(1α,2β,3α,4α,4aα,11bα)>-1,2,3,4,4a,11b-Hexahydro-3,4-dihydroxy-1-acetoxy-2-bromo-7-(phenylmethoxy)-6H-<1,3>benzodioxolo<5,6-c><1>benzopyran-2-one

120882-39-5

N,N-Diethyl-<(tert-butyldimethylsilyl)oxy>-6-formyl-1,3-benzodioxole-5-carboxamide

120882-51-1

<(+/-)-(1α,2β,3α,4α,4aα,11bα)>-1,2,3,4,4a,11b-Hexahydro-3,4-dihydroxy-1-acetoxy-2-bromo-7-(phenylmethoxy)-6H-<1,3>benzodioxolo<5,6-c><1>benzopyran-2-one

上游原料

N,N-Diethyl-4-<(tert-butyldimethylsilyl)oxy>-1,3-benzodioxole-5-carboxamide <(+/-)-(1α,2α,4aα,11bα)>-1,2,4a,11b-Tetrahydro-1,2-dihydroxy-7-(phenylmethoxy)-6H-<1,3>benzodioxolo<5,6-c><1>benzopyran-6-one <(+/-)-(1α,2α,4α,4aα,11bα)>-1,2,3,4,4a,11b-Hexahydro-1,2-dihydroxy-4-iodo-7-(phenylmethoxy)-6H-<1,3>benzodioxolo<5,6-c><1>benzopyran-6-one N,N-Diethyl-4-<(tert-butyldimethylsilyl)oxy>-6-(1,3-butadienyl)-1,3-benzodioxole-5-carboxamide <(+/-)-(4α,4aα,11bα)>-3,4,4a,11b-Tetrahydro-4-iodo-7-(phenylmethoxy)-6H-<1,3>benzodioxolo<5,6-c><1>benzopyran-6-one <(+/-)-(4α,4aα,11bα)>-3,4,4a,11b-Tetrahydro-4-iodo-7-hydroxy-6H-<1,3>benzodioxolo<5,6-c><1>benzopyran-6-one N,N-Diethyl-4-<(tert-butyldimethylsilyl)oxy>-6-(1-hydroxy-3-butenyl)-1,3-benzodioxole-5-carboxamide N,N-Diethyl-<(tert-butyldimethylsilyl)oxy>-6-formyl-1,3-benzodioxole-5-carboxamide <(+/-)-(1α,2β,4aα,11bα)>-1,2,4a,11b-Tetrahydro-1-acetoxy-2-bromo-7-(phenylmethoxy)-6H-<1,3>benzodioxolo<5,6-c><1>benzopyran-6-one 2-ethoxy4-hydroxy-1,3-benzodioxol N,N-Diethyl-4-hydroxy-6-(2,5-cyclohexadien-1-yl)-1,3-benzodioxole-5-carboxamide N,N-Diethyl-4-<(tert-butyldimethylsilyl)oxy>-6-(2,5-cyclohexadien-1-yl)-1,3-benzodioxole-5-carboxamide N,N-Diethyl-4-<(tert-butyldimethylsilyl)oxy>-6-<5-(phenylsulfonyl)-6-nitro-2-cyclohexen-1-yl>-1,3-benzodioxole-5-carboxamide

下游产品

<(+/-)-(1β,2α,3β,4β,4aβ,11bα)>-1,3,4,4a,5,11b-Hexahydro-1,3,4-trihydroxy-2,7-bis(phenylmethoxy)<1,3>dioxolo<4,5-j>phenanthridin-6-(2H)-one <(+/-)-(3α,4α,4aα,11bα)>-3,4,4a,11b-Tetrahydro-3-hydroxy-4,7-bis(phenylmethoxy)-6H-<1,3>benzodioxolo<5,6-c><1>benzopyran-6-one <(+/-)-(1α,2β,3α,4α,4aα,11bα)>-1,2,3,4,4a,11b-Hexahydro-3-hydroxy-1-acetoxy-2-bromo-4,7-bis(phenylmethoxy)-6H-<1,3>benzodioxolo<5,6-c><1>benzopyran-6-one <(+/-)-(1α,2β,3α,4α,4aα,11bα)>-1,2,3,4,4a,11b-Hexahydro-1-acetoxy-2-bromo-3-<(4-methoxyphenyl)methoxy>-4,7-bis(phenylmethoxy)-6H-<1,3>benzodioxolo<5,6-c><1>benzopyran-6-one <(+/-)-(3α,4α,4aα,11bα)>-3,4,4a,11b-Tetrahydro-3,4-dihydroxy-7-(phenylmethoxy)-6H-<1,3>benzodioxolo<5,6-c><1>benzopyran-6-one <(+/-)-(1α,4α,4aα,11bα)>-1,4,4a,11b-Tetrahydro-4,7-bis(phenylmethoxy)-1-<(2,2,2-trichloroacetyl)amino>-6H-<1,3>benzodioxolo<5,6-c><1>benzopyran-6-one <(+/-)-(1α,2β,3β,4α,4aα,11bα)>-1,2,3,4,4a,11b-Hexahydro-2,3-dihydroxy-4,7-bis(phenylmethoxy)-1-<(2,2,2-trichloroacetyl)amino>-6H-<1,3>benzodioxolo<5,6-c><1>benzopyran-6-one <(+/-)-(3α,4α,4aα,11bα)>-3,4,4a,11b-Tetrahydro-4,7-bis(phenylmethoxy)-3-<(2,2,2-trichloroethanimidoyl)oxy>-6H-<1,3>benzodioxolo<5,6-c><1>benzopyran-6-one