百科

(4aR,4bS,8aS,10aR)-1,1,4a,7,8a-Pentamethyl-8-vinyl-1,2,3,4,4a,4b,5,6,8a,9,10,10a-dodecahydro-phenanthrene

(4aR,4bS,8aS,10aR)-1,1,4a,7,8a-Pentamethyl-8-vinyl-1,2,3,4,4a,4b,5,6,8a,9,10,10a-dodecahydro-phenanthrene

CAS号：121115-22-8

英文名：(4aR,4bS,8aS,10aR)-1,1,4a,7,8a-Pentamethyl-8-vinyl-1,2,3,4,4a,4b,5,6,8a,9,10,10a-dodecahydro-phenanthrene

分子式：C21H34

分子量：286.495

合成路线

isocopal-12-en-15-al

isocopal-12-en-15-al

(4aR,4bS,8aS,10aR)-1,1,4a,7,8a-Pentamethyl-8-vinyl-1,2,3,4,4a,4b,5,6,8a,9,10,10a-dodecahydro-phenanthrene

(4aR,4bS,8aS,10aR)-1,1,4a,7,8a-Pentamethyl-8-vinyl-1,2,3,4,4a,4b,5,6,8a,9,10,10a-dodecahydro-phenanthrene

(+/-)-14α-H-isogath-12-en-15-ol

(+/-)-14α-H-isogath-12-en-15-ol

(4aR,4bS,8aS,10aR)-1,1,4a,7,8a-Pentamethyl-8-vinyl-1,2,3,4,4a,4b,5,6,8a,9,10,10a-dodecahydro-phenanthrene

(4aR,4bS,8aS,10aR)-1,1,4a,7,8a-Pentamethyl-8-vinyl-1,2,3,4,4a,4b,5,6,8a,9,10,10a-dodecahydro-phenanthrene

上游原料

isocopal-12-en-15-al (+/-)-14α-H-isogath-12-en-15-ol

下游产品

(1S,2S,3S,4bR,6aS,10aS,10bR,12aS)-3-Hydroxy-4b,7,7,10a,12a-pentamethyl-octadecahydro-chrysene-1,2-dicarboxylic acid dimethyl ester (4bR,6aS,10aS,10bR,12aS)-4b,7,7,10a,12a-Pentamethyl-3-oxo-3,4b,5,6,6a,7,8,9,10,10a,10b,11,12,12a-tetradecahydro-chrysene-1,2-dicarboxylic acid dimethyl ester (1S,2S,3S,4bR,6aS,10aS,10bR,12aS)-3-Methanesulfonyloxy-4b,7,7,10a,12a-pentamethyl-octadecahydro-chrysene-1,2-dicarboxylic acid dimethyl ester (1R,4bR,6aS,10aS,10bR,12aR)-4b,7,7,10a,12a-Pentamethyl-1,4b,5,6,6a,7,8,9,10,10a,10b,11,12,12a-tetradecahydro-chrysene-1,2-dicarboxylic acid dimethyl ester (1S,2S,4bR,6aS,10aS,10bR,12aS)-4b,7,7,10a,12a-Pentamethyl-3-oxo-octadecahydro-chrysene-1,2-dicarboxylic acid dimethyl ester