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Methanesulfonic acid (1S,2R)-2-hydroxy-1-{(S)-3-hydroxy-3-[(2S,5R,2'R,5'R)-5'-((S)-1-hydroxy-1,5-dimethyl-hex-4-enyl)-2'-methyl-octahydro-[2,2']bifuranyl-5-yl]-butyl}-2,6-dimethyl-hept-5-enyl ester

CAS号：121401-04-5

英文名：Methanesulfonic acid (1S,2R)-2-hydroxy-1-{(S)-3-hydroxy-3-[(2S,5R,2'R,5'R)-5'-((S)-1-hydroxy-1,5-dimethyl-hex-4-enyl)-2'-methyl-octahydro-[2,2']bifuranyl-5-yl]-butyl}-2,6-dimethyl-hept-5-enyl ester

分子式：C31H56O8S

分子量：588.837

合成路线

121400-99-5

(2R,5R)-2-<(E)-(S)-1-<(tert-butyldimethylsilyl)oxy>-6-hydroxy-5-methylhex-4-enyl>tetrahydro-5-<(S)-1-(methoxymethoxy)-1,5-dimethylhex-4-enyl>-2-methylfuran

121401-04-5

Methanesulfonic acid (1S,2R)-2-hydroxy-1-{(S)-3-hydroxy-3-[(2S,5R,2'R,5'R)-5'-((S)-1-hydroxy-1,5-dimethyl-hex-4-enyl)-2'-methyl-octahydro-[2,2']bifuranyl-5-yl]-butyl}-2,6-dimethyl-hept-5-enyl ester

121400-97-3

(2R,5R)-2-<(S)-1-<(tert-butyldimethylsilyl)oxy>-4-hydroxybutyl>tetrahydro-5-<(S)-1-(methoxymethoxy)-1,5-dimethylhex-4-enyl>-2-methylfuran

121401-04-5

Methanesulfonic acid (1S,2R)-2-hydroxy-1-{(S)-3-hydroxy-3-[(2S,5R,2'R,5'R)-5'-((S)-1-hydroxy-1,5-dimethyl-hex-4-enyl)-2'-methyl-octahydro-[2,2']bifuranyl-5-yl]-butyl}-2,6-dimethyl-hept-5-enyl ester

76985-25-6

(-)-(2S,3R)-1,2-Epoxy-3,7-dimethyloct-6-en-3-ol

121401-04-5

Methanesulfonic acid (1S,2R)-2-hydroxy-1-{(S)-3-hydroxy-3-[(2S,5R,2'R,5'R)-5'-((S)-1-hydroxy-1,5-dimethyl-hex-4-enyl)-2'-methyl-octahydro-[2,2']bifuranyl-5-yl]-butyl}-2,6-dimethyl-hept-5-enyl ester

121400-98-4

(S)-4-(tert-Butyl-dimethyl-silanyloxy)-4-[(2R,5R)-5-((S)-1-methoxymethoxy-1,5-dimethyl-hex-4-enyl)-2-methyl-tetrahydro-furan-2-yl]-butyraldehyde

121401-04-5

Methanesulfonic acid (1S,2R)-2-hydroxy-1-{(S)-3-hydroxy-3-[(2S,5R,2'R,5'R)-5'-((S)-1-hydroxy-1,5-dimethyl-hex-4-enyl)-2'-methyl-octahydro-[2,2']bifuranyl-5-yl]-butyl}-2,6-dimethyl-hept-5-enyl ester

121400-96-2

{(S)-4-Benzyloxy-1-[(2R,5R)-5-((S)-1-methoxymethoxy-1,5-dimethyl-hex-4-enyl)-2-methyl-tetrahydro-furan-2-yl]-butoxy}-tert-butyl-dimethyl-silane

121401-04-5

Methanesulfonic acid (1S,2R)-2-hydroxy-1-{(S)-3-hydroxy-3-[(2S,5R,2'R,5'R)-5'-((S)-1-hydroxy-1,5-dimethyl-hex-4-enyl)-2'-methyl-octahydro-[2,2']bifuranyl-5-yl]-butyl}-2,6-dimethyl-hept-5-enyl ester

121400-92-8

(2R,5R)-2-<(E)-(S)-1-<(tert-butyldimethylsilyl)oxy>-5-(ethoxycarbonyl)hex-4-enyl>tetrahydro-5-<(S)-1-(methoxymethoxy)-1,5-dimethylhex-4-enyl>-2-methylfuran

121401-04-5

Methanesulfonic acid (1S,2R)-2-hydroxy-1-{(S)-3-hydroxy-3-[(2S,5R,2'R,5'R)-5'-((S)-1-hydroxy-1,5-dimethyl-hex-4-enyl)-2'-methyl-octahydro-[2,2']bifuranyl-5-yl]-butyl}-2,6-dimethyl-hept-5-enyl ester

121400-94-0

(2R,5R)-tetrahydro-2-<(E)-(1S,8S,9R)-1-hydroxy-8,9-bis(methoxymethoxy)-5,9,13-trimethyltetradeca-4,12-dienyl>-5-<(S)-1-(methoxymethoxy)-1,5-dimethylhex-4-enyl>-2-methylfuran

121401-04-5

Methanesulfonic acid (1S,2R)-2-hydroxy-1-{(S)-3-hydroxy-3-[(2S,5R,2'R,5'R)-5'-((S)-1-hydroxy-1,5-dimethyl-hex-4-enyl)-2'-methyl-octahydro-[2,2']bifuranyl-5-yl]-butyl}-2,6-dimethyl-hept-5-enyl ester

121429-29-6

(2R,5R)-2-<(E)-(1S,8S,9R)-1-<(tert-butyldimethylsilyl)oxy>-8-hydroxy-9-(methoxymethoxy)-5,9,13-trimethyltetradeca-4,12-dienyl>tetrahydro-5-<(S)-1-(methoxymethoxy)-1,5-dimethylhex-4-enyl>-2-methylfuran

121401-04-5

Methanesulfonic acid (1S,2R)-2-hydroxy-1-{(S)-3-hydroxy-3-[(2S,5R,2'R,5'R)-5'-((S)-1-hydroxy-1,5-dimethyl-hex-4-enyl)-2'-methyl-octahydro-[2,2']bifuranyl-5-yl]-butyl}-2,6-dimethyl-hept-5-enyl ester

132298-83-0

121401-04-5

Methanesulfonic acid (1S,2R)-2-hydroxy-1-{(S)-3-hydroxy-3-[(2S,5R,2'R,5'R)-5'-((S)-1-hydroxy-1,5-dimethyl-hex-4-enyl)-2'-methyl-octahydro-[2,2']bifuranyl-5-yl]-butyl}-2,6-dimethyl-hept-5-enyl ester

121400-91-7

(2S,3R)-1,2-epoxy-3-(methoxymethoxy)-3,7-dimethyl-6-octene

121401-04-5

Methanesulfonic acid (1S,2R)-2-hydroxy-1-{(S)-3-hydroxy-3-[(2S,5R,2'R,5'R)-5'-((S)-1-hydroxy-1,5-dimethyl-hex-4-enyl)-2'-methyl-octahydro-[2,2']bifuranyl-5-yl]-butyl}-2,6-dimethyl-hept-5-enyl ester

上游原料

tert-Butyl-{(E)-(S)-6-chloro-1-[(2R,5R)-5-((S)-1-methoxymethoxy-1,5-dimethyl-hex-4-enyl)-2-methyl-tetrahydro-furan-2-yl]-5-methyl-hex-4-enyloxy}-dimethyl-silane (2R,5R)-tetrahydro-2-<(2S,5R)-tetrahydro-5-<(1S,4S,5R)-1-hydroxy-4,5-bis(methoxymethoxy)-1,5,9-trimethyldec-8-enyl>furan-2-yl>-5-<(S)-1-(methoxymethoxy)-1,5-dimethylhex-4-enyl>-2-methylfuran (2R,5R)-2-<(E)-(S)-1-<(tert-butyldimethylsilyl)oxy>-6-hydroxy-5-methylhex-4-enyl>tetrahydro-5-<(S)-1-(methoxymethoxy)-1,5-dimethylhex-4-enyl>-2-methylfuran (2R,5R)-2-<(S)-1-<(tert-butyldimethylsilyl)oxy>-4-hydroxybutyl>tetrahydro-5-<(S)-1-(methoxymethoxy)-1,5-dimethylhex-4-enyl>-2-methylfuran (2R,5R)-2-<(E)-(S)-1-<(tert-butyldimethylsilyl)oxy>-5-(ethoxycarbonyl)hex-4-enyl>tetrahydro-5-<(S)-1-(methoxymethoxy)-1,5-dimethylhex-4-enyl>-2-methylfuran (2R,5R)-2-<(E)-(1S,8S,9R)-1-<(tert-butyldimethylsilyl)oxy>-8-hydroxy-9-(methoxymethoxy)-5,9,13-trimethyltetradeca-4,12-dienyl>tetrahydro-5-<(S)-1-(methoxymethoxy)-1,5-dimethylhex-4-enyl>-2-methylfuran (2R,5R)-2-<(E)-(S)-1-<(tert-butyldimethylsilyl)oxy>-5-methyl-6-(phenylthio)hex-4-enyl>tetrahydro-5-<(S)-1-(methoxymethoxy)-1,5-dimethylhex-4-enyl>-2-methylfuran (S)-4-(tert-Butyl-dimethyl-silanyloxy)-4-[(2R,5R)-5-((S)-1-methoxymethoxy-1,5-dimethyl-hex-4-enyl)-2-methyl-tetrahydro-furan-2-yl]-butyraldehyde (S)-3-[(2S,3S)-3-((3S,4R)-3,4-Bis-methoxymethoxy-4,8-dimethyl-non-7-enyl)-3-methyl-oxiranyl]-1-[(2R,5R)-5-((S)-1-methoxymethoxy-1,5-dimethyl-hex-4-enyl)-2-methyl-tetrahydro-furan-2-yl]-propan-1-ol {(S)-4-Benzyloxy-1-[(2R,5R)-5-((S)-1-methoxymethoxy-1,5-dimethyl-hex-4-enyl)-2-methyl-tetrahydro-furan-2-yl]-butoxy}-tert-butyl-dimethyl-silane (2S,3R)-1,2-epoxy-3-(methoxymethoxy)-3,7-dimethyl-6-octene (2R,5R)-tetrahydro-2-<(E)-(1S,8S,9R)-1-hydroxy-8,9-bis(methoxymethoxy)-5,9,13-trimethyltetradeca-4,12-dienyl>-5-<(S)-1-(methoxymethoxy)-1,5-dimethylhex-4-enyl>-2-methylfuran (-)-(2S,3R)-1,2-Epoxy-3,7-dimethyloct-6-en-3-ol

下游产品

(S)-2-((2R,5R,2'S,5'R)-5'-{(S)-1-Hydroxy-1-methyl-3-[(2R,3S)-3-methyl-3-(4-methyl-pent-3-enyl)-oxiranyl]-propyl}-2-methyl-octahydro-[2,2']bifuranyl-5-yl)-6-methyl-hept-5-en-2-ol