百科

(4R,8S)-8-{[(1,1-dimethylethyl)dimethylsilyl]oxy}non-1-en-4-ol

(4R,8S)-8-{[(1,1-dimethylethyl)dimethylsilyl]oxy}non-1-en-4-ol

CAS号：1215090-53-1

英文名：(4R,8S)-8-{[(1,1-dimethylethyl)dimethylsilyl]oxy}non-1-en-4-ol

分子式：C15H32O2Si

分子量：272.499

合成路线

(1,1-dimethylethyl)dimethyl{[(1S)-1-methylpent-4-enyl]oxy}silane

(1,1-dimethylethyl)dimethyl{[(1S)-1-methylpent-4-enyl]oxy}silane

(4R,8S)-8-{[(1,1-dimethylethyl)dimethylsilyl]oxy}non-1-en-4-ol

(4R,8S)-8-{[(1,1-dimethylethyl)dimethylsilyl]oxy}non-1-en-4-ol

(4S)-4-(tert-butyl(dimethyl)silyloxy)pentanal

(4S)-4-(tert-butyl(dimethyl)silyloxy)pentanal

(4R,8S)-8-{[(1,1-dimethylethyl)dimethylsilyl]oxy}non-1-en-4-ol

(4R,8S)-8-{[(1,1-dimethylethyl)dimethylsilyl]oxy}non-1-en-4-ol

(S,E)-ethyl 6-(tert-butyldimethylsilyloxy)hept-2-enoate

(S,E)-ethyl 6-(tert-butyldimethylsilyloxy)hept-2-enoate

(4R,8S)-8-{[(1,1-dimethylethyl)dimethylsilyl]oxy}non-1-en-4-ol

(4R,8S)-8-{[(1,1-dimethylethyl)dimethylsilyl]oxy}non-1-en-4-ol

(S)-ethyl 6-(tert-butyldimethylsilyloxy)heptanoate

(S)-ethyl 6-(tert-butyldimethylsilyloxy)heptanoate

(4R,8S)-8-{[(1,1-dimethylethyl)dimethylsilyl]oxy}non-1-en-4-ol

(4R,8S)-8-{[(1,1-dimethylethyl)dimethylsilyl]oxy}non-1-en-4-ol

(2R,6S)-6-(tert-butyldimethylsilyloxy)heptane-1,2-diol

(2R,6S)-6-(tert-butyldimethylsilyloxy)heptane-1,2-diol

(4R,8S)-8-{[(1,1-dimethylethyl)dimethylsilyl]oxy}non-1-en-4-ol

(4R,8S)-8-{[(1,1-dimethylethyl)dimethylsilyl]oxy}non-1-en-4-ol

(2R,6S)-6-((tert-butyldimethylsilyl)oxy)-2-hydroxyheptyl 4-methylbenzenesulfonate

(2R,6S)-6-((tert-butyldimethylsilyl)oxy)-2-hydroxyheptyl 4-methylbenzenesulfonate

(4R,8S)-8-{[(1,1-dimethylethyl)dimethylsilyl]oxy}non-1-en-4-ol

(4R,8S)-8-{[(1,1-dimethylethyl)dimethylsilyl]oxy}non-1-en-4-ol

上游原料

(S)-ethyl 6-(tert-butyldimethylsilyloxy)heptanoate (4S)-4-(tert-butyl(dimethyl)silyloxy)pentanal (2R,6S)-6-(tert-butyldimethylsilyloxy)heptane-1,2-diol (S,E)-ethyl 6-(tert-butyldimethylsilyloxy)hept-2-enoate (2R,6S)-6-((tert-butyldimethylsilyl)oxy)-2-hydroxyheptyl 4-methylbenzenesulfonate (1,1-dimethylethyl)dimethyl{[(1S)-1-methylpent-4-enyl]oxy}silane

下游产品

(+)-cephalosporolide D (3R,7S)-7-(tert-butyldimethylsilyloxy)-3-(4-methoxybenzyloxy)octanoic acid