百科

(1R,3S,4R,6S,7R)-5-Benzyl-7-benzyloxy-6-(tert-butyl-dimethyl-silanyloxymethyl)-3-methoxy-2-oxa-5-aza-bicyclo[2.2.1]heptane

(1R,3S,4R,6S,7R)-5-Benzyl-7-benzyloxy-6-(tert-butyl-dimethyl-silanyloxymethyl)-3-methoxy-2-oxa-5-aza-bicyclo[2.2.1]heptane

CAS号：121588-47-4

英文名：(1R,3S,4R,6S,7R)-5-Benzyl-7-benzyloxy-6-(tert-butyl-dimethyl-silanyloxymethyl)-3-methoxy-2-oxa-5-aza-bicyclo[2.2.1]heptane

分子式：C27H39NO4Si

分子量：469.688

合成路线

methyl 2-azido-3-O-benzyl-2-deoxy-α-D-mannofuranoside

methyl 2-azido-3-O-benzyl-2-deoxy-α-D-mannofuranoside

(1R,3S,4R,6S,7R)-5-Benzyl-7-benzyloxy-6-(tert-butyl-dimethyl-silanyloxymethyl)-3-methoxy-2-oxa-5-aza-bicyclo[2.2.1]heptane

(1R,3S,4R,6S,7R)-5-Benzyl-7-benzyloxy-6-(tert-butyl-dimethyl-silanyloxymethyl)-3-methoxy-2-oxa-5-aza-bicyclo[2.2.1]heptane

(R)-1-((2R,3R,4S,5S)-4-Azido-3-benzyloxy-5-methoxy-tetrahydro-furan-2-yl)-2-(tert-butyl-dimethyl-silanyloxy)-ethanol

(R)-1-((2R,3R,4S,5S)-4-Azido-3-benzyloxy-5-methoxy-tetrahydro-furan-2-yl)-2-(tert-butyl-dimethyl-silanyloxy)-ethanol

(1R,3S,4R,6S,7R)-5-Benzyl-7-benzyloxy-6-(tert-butyl-dimethyl-silanyloxymethyl)-3-methoxy-2-oxa-5-aza-bicyclo[2.2.1]heptane

(1R,3S,4R,6S,7R)-5-Benzyl-7-benzyloxy-6-(tert-butyl-dimethyl-silanyloxymethyl)-3-methoxy-2-oxa-5-aza-bicyclo[2.2.1]heptane

上游原料

(R)-1-((2R,3R,4S,5S)-4-Azido-3-benzyloxy-5-methoxy-tetrahydro-furan-2-yl)-2-(tert-butyl-dimethyl-silanyloxy)-ethanol methyl 2-azido-3-O-benzyl-2-deoxy-α-D-mannofuranoside

下游产品

methyl N-benzyl-3-O-benzyl-2,5-dideoxy-2,5-imino-β-L-gulofuranoside (1R,2R,3R,7R,7aS)-3-hydroxymethyl-2,3,5,6,7,7a-hexahydro-1H-pyrrolizin-1,2,7-triol