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(1S,4S,4aS,8aS)-4-(tert-butyldimethylsilyloxy)-2-(tert-butyldimethylsilyloxymethyl)-1,4,4a,5,6,7,8,8a-octahydro-1-hydroxy-5,5,8a-trimethylnaphthalene-1-carboxaldehyde

CAS号：121617-70-7

英文名：(1S,4S,4aS,8aS)-4-(tert-butyldimethylsilyloxy)-2-(tert-butyldimethylsilyloxymethyl)-1,4,4a,5,6,7,8,8a-octahydro-1-hydroxy-5,5,8a-trimethylnaphthalene-1-carboxaldehyde

分子式：C27H52O4Si2

分子量：496.87

合成路线

158426-26-7

12-acetoxy-9α,11-carbonyldioxydrim-7-ene

121617-70-7

(1S,4S,4aS,8aS)-4-(tert-butyldimethylsilyloxy)-2-(tert-butyldimethylsilyloxymethyl)-1,4,4a,5,6,7,8,8a-octahydro-1-hydroxy-5,5,8a-trimethylnaphthalene-1-carboxaldehyde

192566-81-7

9α,11-carbonyldioxydrim-7-ene-6β,12-diol

121617-70-7

(1S,4S,4aS,8aS)-4-(tert-butyldimethylsilyloxy)-2-(tert-butyldimethylsilyloxymethyl)-1,4,4a,5,6,7,8,8a-octahydro-1-hydroxy-5,5,8a-trimethylnaphthalene-1-carboxaldehyde

192566-89-5

6β,12-bis(tert-butyldimethylsilyloxy)-9α,11-carbonyldioxydrim-7-ene

121617-70-7

(1S,4S,4aS,8aS)-4-(tert-butyldimethylsilyloxy)-2-(tert-butyldimethylsilyloxymethyl)-1,4,4a,5,6,7,8,8a-octahydro-1-hydroxy-5,5,8a-trimethylnaphthalene-1-carboxaldehyde

121701-36-8

(1S,4aS,8aS)-5,5,8a-trimethyl-2'-oxo-4a,5,6,7,8,8a-hexahydro-4H-spiro[naphthalene-1,4'-[1,3]dioxolane]-2-carbaldehyde

121617-70-7

(1S,4S,4aS,8aS)-4-(tert-butyldimethylsilyloxy)-2-(tert-butyldimethylsilyloxymethyl)-1,4,4a,5,6,7,8,8a-octahydro-1-hydroxy-5,5,8a-trimethylnaphthalene-1-carboxaldehyde

121617-67-2

(1S,4R,4aS,8aS)-4-(tert-Butyl-dimethyl-silanyloxy)-1,2-bis-hydroxymethyl-5,5,8a-trimethyl-1,4,4a,5,6,7,8,8a-octahydro-naphthalen-1-ol

121617-70-7

(1S,4S,4aS,8aS)-4-(tert-butyldimethylsilyloxy)-2-(tert-butyldimethylsilyloxymethyl)-1,4,4a,5,6,7,8,8a-octahydro-1-hydroxy-5,5,8a-trimethylnaphthalene-1-carboxaldehyde

121617-61-6

(4S,4a'S,8a'S)-2'-(1,3-dioxolan-2-yl)-4'a,5',6',7',8',8'a-hexahydro-5',5',8a'-trimethylspiro<1,3-dioxolane-4,1'(4'H)-naphthalene>-2-one

121617-70-7

(1S,4S,4aS,8aS)-4-(tert-butyldimethylsilyloxy)-2-(tert-butyldimethylsilyloxymethyl)-1,4,4a,5,6,7,8,8a-octahydro-1-hydroxy-5,5,8a-trimethylnaphthalene-1-carboxaldehyde

121617-66-1

(5S,5aS,9aS,9bS)-5-(tert-butyldimethylsilyloxy)-5,5a,6,7,8,9,9a,9b-octahydro-9b-hydroxy-6,6,9a-trimethylnaphtho<1,2-c>furan-3(1H)-one

121617-70-7

(1S,4S,4aS,8aS)-4-(tert-butyldimethylsilyloxy)-2-(tert-butyldimethylsilyloxymethyl)-1,4,4a,5,6,7,8,8a-octahydro-1-hydroxy-5,5,8a-trimethylnaphthalene-1-carboxaldehyde

121617-63-8

methyl (4S,4a'S,8a'S)-4'a,5',6',7',8',8'a-hexahydro-5',5',8'a-trimethyl-2,2'-dioxospiro<1,3-dioxolane-4,1'(4'H)-naphthalene>-2'-carboxylate

121617-70-7

(1S,4S,4aS,8aS)-4-(tert-butyldimethylsilyloxy)-2-(tert-butyldimethylsilyloxymethyl)-1,4,4a,5,6,7,8,8a-octahydro-1-hydroxy-5,5,8a-trimethylnaphthalene-1-carboxaldehyde

121617-65-0

methyl (4S,4'S,4a'S,8a'S)-4'-(tert-butyldimethylsilyloxy)-4'a,5',6',7',8',8'a-hexahydro-5',5',8'a-trimethyl-2-oxospiro<1,3-dioxolane-4,1'(4'H)-naphthalene>-2'-carboxylate

121617-70-7

(1S,4S,4aS,8aS)-4-(tert-butyldimethylsilyloxy)-2-(tert-butyldimethylsilyloxymethyl)-1,4,4a,5,6,7,8,8a-octahydro-1-hydroxy-5,5,8a-trimethylnaphthalene-1-carboxaldehyde

121617-64-9

methyl (4S,4'S,4a'S,8a'S)-4'a,5',6',7',8',8'a-hexahydro-4'-hydroxy-5',5',8'a-trimethyl-2-oxospiro<1,3-dioxolane-4,1'(4'H)-naphthalene>-2'-carboxylate

121617-70-7

(1S,4S,4aS,8aS)-4-(tert-butyldimethylsilyloxy)-2-(tert-butyldimethylsilyloxymethyl)-1,4,4a,5,6,7,8,8a-octahydro-1-hydroxy-5,5,8a-trimethylnaphthalene-1-carboxaldehyde

上游原料

(1S,4aS,8aS)-5,5,8a-trimethyl-2'-oxo-4a,5,6,7,8,8a-hexahydro-4H-spiro[naphthalene-1,4'-[1,3]dioxolane]-2-carbaldehyde (1S,4R,4aS,8aS)-4-(tert-Butyl-dimethyl-silanyloxy)-1,2-bis-hydroxymethyl-5,5,8a-trimethyl-1,4,4a,5,6,7,8,8a-octahydro-naphthalen-1-ol 9α,11-carbonyldioxydrim-7-ene-6β,12-diol (4S,4a'S,8a'S)-2'-(1,3-dioxolan-2-yl)-4'a,5',6',7',8',8'a-hexahydro-5',5',8a'-trimethylspiro<1,3-dioxolane-4,1'(4'H)-naphthalene>-2-one (5S,5aS,9aS,9bS)-5-(tert-butyldimethylsilyloxy)-5,5a,6,7,8,9,9a,9b-octahydro-9b-hydroxy-6,6,9a-trimethylnaphtho<1,2-c>furan-3(1H)-one methyl (4S,4'S,4a'S,8a'S)-4'-(tert-butyldimethylsilyloxy)-4'a,5',6',7',8',8'a-hexahydro-5',5',8'a-trimethyl-2-oxospiro<1,3-dioxolane-4,1'(4'H)-naphthalene>-2'-carboxylate 12-acetoxy-9α,11-carbonyldioxydrim-7-ene 6β,12-bis(tert-butyldimethylsilyloxy)-9α,11-carbonyldioxydrim-7-ene methyl (4S,4'S,4a'S,8a'S)-4'a,5',6',7',8',8'a-hexahydro-4'-hydroxy-5',5',8'a-trimethyl-2-oxospiro<1,3-dioxolane-4,1'(4'H)-naphthalene>-2'-carboxylate methyl (4S,4a'S,8a'S)-4'a,5',6',7',8',8'a-hexahydro-5',5',8'a-trimethyl-2,2'-dioxospiro<1,3-dioxolane-4,1'(4'H)-naphthalene>-2'-carboxylate

下游产品

(1R,5R,5aS,9aS,9bS)-5-(tert-Butyl-dimethyl-silanyloxy)-6,6,9a-trimethyl-3,5,5a,6,7,8,9,9a-octahydro-naphtho[1,2-c]furan-1,9b-diol