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((1S,2R,7R)-1,6,6-Trimethyl-3,5,10-trioxa-bicyclo[5.2.1]dec-2-yl)-methanol

((1S,2R,7R)-1,6,6-Trimethyl-3,5,10-trioxa-bicyclo[5.2.1]dec-2-yl)-methanol

CAS号：121693-71-8

英文名：((1S,2R,7R)-1,6,6-Trimethyl-3,5,10-trioxa-bicyclo[5.2.1]dec-2-yl)-methanol

分子式：C11H20O4

分子量：216.274

合成路线

(1S,2R,7R)-2-Benzyloxymethyl-1,6,6-trimethyl-3,5,10-trioxa-bicyclo[5.2.1]decane

(1S,2R,7R)-2-Benzyloxymethyl-1,6,6-trimethyl-3,5,10-trioxa-bicyclo[5.2.1]decane

((1S,2R,7R)-1,6,6-Trimethyl-3,5,10-trioxa-bicyclo[5.2.1]dec-2-yl)-methanol

((1S,2R,7R)-1,6,6-Trimethyl-3,5,10-trioxa-bicyclo[5.2.1]dec-2-yl)-methanol

(2R,3S)-1-Benzyloxy-3,7-dimethyl-oct-6-ene-2,3-diol

(2R,3S)-1-Benzyloxy-3,7-dimethyl-oct-6-ene-2,3-diol

((1S,2R,7R)-1,6,6-Trimethyl-3,5,10-trioxa-bicyclo[5.2.1]dec-2-yl)-methanol

((1S,2R,7R)-1,6,6-Trimethyl-3,5,10-trioxa-bicyclo[5.2.1]dec-2-yl)-methanol

2-[(2R,5S)-5-((R)-2-Benzyloxy-1-hydroxy-ethyl)-5-methyl-tetrahydro-furan-2-yl]-propan-2-ol

2-[(2R,5S)-5-((R)-2-Benzyloxy-1-hydroxy-ethyl)-5-methyl-tetrahydro-furan-2-yl]-propan-2-ol

((1S,2R,7R)-1,6,6-Trimethyl-3,5,10-trioxa-bicyclo[5.2.1]dec-2-yl)-methanol

((1S,2R,7R)-1,6,6-Trimethyl-3,5,10-trioxa-bicyclo[5.2.1]dec-2-yl)-methanol

上游原料

2-[(2R,5S)-5-((R)-2-Benzyloxy-1-hydroxy-ethyl)-5-methyl-tetrahydro-furan-2-yl]-propan-2-ol (1S,2R,7R)-2-Benzyloxymethyl-1,6,6-trimethyl-3,5,10-trioxa-bicyclo[5.2.1]decane (2R,3S)-1-Benzyloxy-3,7-dimethyl-oct-6-ene-2,3-diol

下游产品

(1S,2S,7R)-1,6,6-Trimethyl-3,5,10-trioxa-bicyclo[5.2.1]decane-2-carbaldehyde (R)-1-[(2R,4aR,6R,8aS)-6-((2S,5R)-5-Bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-8a-methyl-octahydro-pyrano[3,2-b]pyran-2-yl]-3-((1S,2R,7R)-1,6,6-trimethyl-3,5,10-trioxa-bicyclo[5.2.1]dec-2-yl)-propan-1-ol (1S,2R,7R)-1,6,6-Trimethyl-2-vinyl-3,5,10-trioxa-bicyclo[5.2.1]decane (1S,2R,7R)-2-(2-Bromo-ethyl)-1,6,6-trimethyl-3,5,10-trioxa-bicyclo[5.2.1]decane (S)-2-[(2R,4aR,6R,8aS)-6-((2S,5R)-5-Bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-8a-methyl-octahydro-pyrano[3,2-b]pyran-2-yl]-4-((1S,2R,7R)-1,6,6-trimethyl-3,5,10-trioxa-bicyclo[5.2.1]dec-2-yl)-butan-2-ol 2-((1S,2R,7R)-1,6,6-Trimethyl-3,5,10-trioxa-bicyclo[5.2.1]dec-2-yl)-ethanol 1-[(2R,4aR,6R,8aS)-6-((2S,5R)-5-Bromo-2,6,6-trimethyl-tetrahydro-pyran-2-yl)-8a-methyl-octahydro-pyrano[3,2-b]pyran-2-yl]-3-((1S,2R,7R)-1,6,6-trimethyl-3,5,10-trioxa-bicyclo[5.2.1]dec-2-yl)-propan-1-one