百科

(1S,2R,4aS,8aR)-trimethylsilyl 1,6-dimethyl-2-((E)-prop-1-en-1-yl)-5-((trimethylsilyl)oxy)-1,2,4a,7,8,8a-hexahydronaphthalene-1-carboxylate

(1S,2R,4aS,8aR)-trimethylsilyl 1,6-dimethyl-2-((E)-prop-1-en-1-yl)-5-((trimethylsilyl)oxy)-1,2,4a,7,8,8a-hexahydronaphthalene-1-carboxylate

CAS号：122924-29-2

英文名：(1S,2R,4aS,8aR)-trimethylsilyl 1,6-dimethyl-2-((E)-prop-1-en-1-yl)-5-((trimethylsilyl)oxy)-1,2,4a,7,8,8a-hexahydronaphthalene-1-carboxylate

分子式：C22H38O3Si2

分子量：406.706

合成路线

(1S,4aR,7R,8aR)-4,7-dimethyl-1-((1E,3E)-penta-1,3-dien-1-yl)tetrahydro-1H-isochromene-3,8(4H,8aH)-dione

(1S,4aR,7R,8aR)-4,7-dimethyl-1-((1E,3E)-penta-1,3-dien-1-yl)tetrahydro-1H-isochromene-3,8(4H,8aH)-dione

(1S,2R,4aS,8aR)-trimethylsilyl 1,6-dimethyl-2-((E)-prop-1-en-1-yl)-5-((trimethylsilyl)oxy)-1,2,4a,7,8,8a-hexahydronaphthalene-1-carboxylate

(1S,2R,4aS,8aR)-trimethylsilyl 1,6-dimethyl-2-((E)-prop-1-en-1-yl)-5-((trimethylsilyl)oxy)-1,2,4a,7,8,8a-hexahydronaphthalene-1-carboxylate

(((1S,4aR,8aR)-4,7-dimethyl-1-((1E,3E)-penta-1,3-dien-1-yl)-4a,5,6,8a-tetrahydro-1H-isochromene-3,8-diyl)bis(oxy))bis(trimethylsilane)

(((1S,4aR,8aR)-4,7-dimethyl-1-((1E,3E)-penta-1,3-dien-1-yl)-4a,5,6,8a-tetrahydro-1H-isochromene-3,8-diyl)bis(oxy))bis(trimethylsilane)

(1S,2R,4aS,8aR)-trimethylsilyl 1,6-dimethyl-2-((E)-prop-1-en-1-yl)-5-((trimethylsilyl)oxy)-1,2,4a,7,8,8a-hexahydronaphthalene-1-carboxylate

(1S,2R,4aS,8aR)-trimethylsilyl 1,6-dimethyl-2-((E)-prop-1-en-1-yl)-5-((trimethylsilyl)oxy)-1,2,4a,7,8,8a-hexahydronaphthalene-1-carboxylate

上游原料

(((1S,4aR,8aR)-4,7-dimethyl-1-((1E,3E)-penta-1,3-dien-1-yl)-4a,5,6,8a-tetrahydro-1H-isochromene-3,8-diyl)bis(oxy))bis(trimethylsilane) (1S,4aR,7R,8aR)-4,7-dimethyl-1-((1E,3E)-penta-1,3-dien-1-yl)tetrahydro-1H-isochromene-3,8(4H,8aH)-dione

下游产品

(2R,4aR,5S,6R,8aS)-5-(((tert-butyldimethylsilyl)oxy)methyl)-2,5-dimethyl-6-((E)-prop-1-en-1-yl)-1,2,3,4,4a,5,6,8a-octahydronaphthalen-1-yl methanesulfonate (1S,2R,4aS,6R,8aR)-1,6-dimethyl-5-oxo-2-((E)-prop-1-en-1-yl)-1,2,4a,5,6,7,8,8a-octahydronaphthalene-1-carboxylic acid (2R,4aR,5S,6R,8aS)-5-(((tert-butyldimethylsilyl)oxy)methyl)-2,5-dimethyl-6-((E)-prop-1-en-1-yl)-1,2,3,4,4a,5,6,8a-octahydronaphthalen-1-ol 尹奎色亭 (2R,4aR,5S,6R,8aS)-5-(hydroxymethyl)-2,5-dimethyl-6-((E)-prop-1-en-1-yl)-1,2,3,4,4a,5,6,8a-octahydronaphthalen-1-ol (1S,2R,4aS,6R,8aR)-methyl 1,6-dimethyl-5-oxo-2-((E)-prop-1-en-1-yl)-1,2,4a,5,6,7,8,8a-octahydronaphthalene-1-carboxylate