百科

(1R,2R,5R)-2-<(tert-Butyldimethylsilyloxy)methyl>-6-oxabicyclo<3.2.1>oct-3-en-7-one

(1R,2R,5R)-2-<(tert-Butyldimethylsilyloxy)methyl>-6-oxabicyclo<3.2.1>oct-3-en-7-one

CAS号：129482-69-5

英文名：(1R,2R,5R)-2-<(tert-Butyldimethylsilyloxy)methyl>-6-oxabicyclo<3.2.1>oct-3-en-7-one

分子式：C14H24O3Si

分子量：268.424

合成路线

(1S,6R)-Methyl 6-<(tert-Butyldimethylsilyloxy)methyl>-3-cyclohexene-1-carboxylate

(1S,6R)-Methyl 6-<(tert-Butyldimethylsilyloxy)methyl>-3-cyclohexene-1-carboxylate

(1R,2R,5R)-2-<(tert-Butyldimethylsilyloxy)methyl>-6-oxabicyclo<3.2.1>oct-3-en-7-one

(1R,2R,5R)-2-<(tert-Butyldimethylsilyloxy)methyl>-6-oxabicyclo<3.2.1>oct-3-en-7-one

(1S,2R,4R,5R)-4-Iodo-7-oxo-6-oxa-bicyclo[3.2.1]octane-2-carboxylic acid tert-butyl ester

(1S,2R,4R,5R)-4-Iodo-7-oxo-6-oxa-bicyclo[3.2.1]octane-2-carboxylic acid tert-butyl ester

(1R,2R,5R)-2-<(tert-Butyldimethylsilyloxy)methyl>-6-oxabicyclo<3.2.1>oct-3-en-7-one

(1R,2R,5R)-2-<(tert-Butyldimethylsilyloxy)methyl>-6-oxabicyclo<3.2.1>oct-3-en-7-one

上游原料

(1S,2R,4R,5R)-4-Iodo-7-oxo-6-oxa-bicyclo[3.2.1]octane-2-carboxylic acid tert-butyl ester (1S,6R)-Methyl 6-<(tert-Butyldimethylsilyloxy)methyl>-3-cyclohexene-1-carboxylate

下游产品

(6R,8S,8aR)-6,8-Bis-(tert-butyl-dimethyl-silanyloxy)-1,5,6,7,8,8a-hexahydro-isochromen-3-one (1S,2R,4S,5R,6R)-5-(tert-Butyl-dimethyl-silanyloxymethyl)-4-[1,3]dithian-2-ylidenemethyl-7-oxa-bicyclo[4.1.0]heptan-2-ol [(2S,3S,5R)-3,5-Bis-(tert-butyl-dimethyl-silanyloxy)-2-(2-nitro-phenylselanylmethyl)-cyclohex-(Z)-ylidene]-acetic acid methyl ester