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(4S,5S,6S)-6-ethyl-5-methyl-4-(2-(1-phenyl-1H-tetrazol-5-ylthio)ethyl)-4-(trimethylsilyloxy)-tetrahydropyran-2-one

(4S,5S,6S)-6-ethyl-5-methyl-4-(2-(1-phenyl-1H-tetrazol-5-ylthio)ethyl)-4-(trimethylsilyloxy)-tetrahydropyran-2-one

CAS号：1299358-26-1

英文名：(4S,5S,6S)-6-ethyl-5-methyl-4-(2-(1-phenyl-1H-tetrazol-5-ylthio)ethyl)-4-(trimethylsilyloxy)-tetrahydropyran-2-one

分子式：C20H30N4O3SSi

分子量：434.628

合成路线

(4S,5S)-5-{[tert-butyl(dimethyl)silyl]oxy}-4-methylhept-1-en-3-one

(4S,5S)-5-{[tert-butyl(dimethyl)silyl]oxy}-4-methylhept-1-en-3-one

(4S,5S,6S)-6-ethyl-5-methyl-4-(2-(1-phenyl-1H-tetrazol-5-ylthio)ethyl)-4-(trimethylsilyloxy)-tetrahydropyran-2-one

(4S,5S,6S)-6-ethyl-5-methyl-4-(2-(1-phenyl-1H-tetrazol-5-ylthio)ethyl)-4-(trimethylsilyloxy)-tetrahydropyran-2-one

(4S,5S)-1-(benzyloxy)-5-{[tert-butyl(dimethyl)silyl]oxy}-4-methylheptan-3-one

(4S,5S)-1-(benzyloxy)-5-{[tert-butyl(dimethyl)silyl]oxy}-4-methylheptan-3-one

(4S,5S,6S)-6-ethyl-5-methyl-4-(2-(1-phenyl-1H-tetrazol-5-ylthio)ethyl)-4-(trimethylsilyloxy)-tetrahydropyran-2-one

(4S,5S,6S)-6-ethyl-5-methyl-4-(2-(1-phenyl-1H-tetrazol-5-ylthio)ethyl)-4-(trimethylsilyloxy)-tetrahydropyran-2-one

(4S,5S)-1-(benzyloxy)-5-hydroxy-4-methylheptan-3-one

(4S,5S)-1-(benzyloxy)-5-hydroxy-4-methylheptan-3-one

(4S,5S,6S)-6-ethyl-5-methyl-4-(2-(1-phenyl-1H-tetrazol-5-ylthio)ethyl)-4-(trimethylsilyloxy)-tetrahydropyran-2-one

(4S,5S,6S)-6-ethyl-5-methyl-4-(2-(1-phenyl-1H-tetrazol-5-ylthio)ethyl)-4-(trimethylsilyloxy)-tetrahydropyran-2-one

(4R,5S,6S)-4-(2-(benzyloxy)ethyl)-6-ethyl-4-hydroxy-5-methyl-tetrahydropyran-2-one

(4R,5S,6S)-4-(2-(benzyloxy)ethyl)-6-ethyl-4-hydroxy-5-methyl-tetrahydropyran-2-one

(4S,5S,6S)-6-ethyl-5-methyl-4-(2-(1-phenyl-1H-tetrazol-5-ylthio)ethyl)-4-(trimethylsilyloxy)-tetrahydropyran-2-one

(4S,5S,6S)-6-ethyl-5-methyl-4-(2-(1-phenyl-1H-tetrazol-5-ylthio)ethyl)-4-(trimethylsilyloxy)-tetrahydropyran-2-one

methyl (2S,3S)-3-(tert-butyldimethylsilyloxy)-2-methylpentanoate

methyl (2S,3S)-3-(tert-butyldimethylsilyloxy)-2-methylpentanoate

(4S,5S,6S)-6-ethyl-5-methyl-4-(2-(1-phenyl-1H-tetrazol-5-ylthio)ethyl)-4-(trimethylsilyloxy)-tetrahydropyran-2-one

(4S,5S,6S)-6-ethyl-5-methyl-4-(2-(1-phenyl-1H-tetrazol-5-ylthio)ethyl)-4-(trimethylsilyloxy)-tetrahydropyran-2-one

上游原料

methyl (2S,3S)-3-(tert-butyldimethylsilyloxy)-2-methylpentanoate (4S,5S)-1-(benzyloxy)-5-{[tert-butyl(dimethyl)silyl]oxy}-4-methylheptan-3-one (4R,5S,6S)-4-(2-(benzyloxy)ethyl)-6-ethyl-4-hydroxy-5-methyl-tetrahydropyran-2-one (4S,5S)-5-{[tert-butyl(dimethyl)silyl]oxy}-4-methylhept-1-en-3-one (4S,5S)-1-(benzyloxy)-5-hydroxy-4-methylheptan-3-one

下游产品

(4S,5S,6S)-6-ethyl-5-methyl-4-(2-(1-phenyl-1H-tetrazol-5-ylsulfonyl)ethyl)-4-(trimethylsilyloxy)-tetrahydropyran-2-one