百科

(1S,5R,6R,7R)-(E)-3-(1,4-dimethoxycarbonyl-1-butylidene)-6-(3-oxo-E-1-octenyl)-7-tetrahydropyranyloxy-2-oxabicyclo<3.3.0>octane

(1S,5R,6R,7R)-(E)-3-(1,4-dimethoxycarbonyl-1-butylidene)-6-(3-oxo-E-1-octenyl)-7-tetrahydropyranyloxy-2-oxabicyclo<3.3.0>octane

CAS号：129944-63-4

英文名：(1S,5R,6R,7R)-(E)-3-(1,4-dimethoxycarbonyl-1-butylidene)-6-(3-oxo-E-1-octenyl)-7-tetrahydropyranyloxy-2-oxabicyclo<3.3.0>octane

分子式：C28H42O8

分子量：506.628

合成路线

(1S,5R,6S,7R)-6-(tert-butyldimethylsilyloxymethyl)-3-(1,4-dimethoxycarbonyl-1-butylidene)-7-tetrahydropyranyloxy-2-oxabicyclo<3.3.0>octane

(1S,5R,6S,7R)-6-(tert-butyldimethylsilyloxymethyl)-3-(1,4-dimethoxycarbonyl-1-butylidene)-7-tetrahydropyranyloxy-2-oxabicyclo<3.3.0>octane

(1S,5R,6R,7R)-(E)-3-(1,4-dimethoxycarbonyl-1-butylidene)-6-(3-oxo-E-1-octenyl)-7-tetrahydropyranyloxy-2-oxabicyclo<3.3.0>octane

(1S,5R,6R,7R)-(E)-3-(1,4-dimethoxycarbonyl-1-butylidene)-6-(3-oxo-E-1-octenyl)-7-tetrahydropyranyloxy-2-oxabicyclo<3.3.0>octane

上游原料

(1S,5R,6S,7R)-6-(tert-butyldimethylsilyloxymethyl)-3-(1,4-dimethoxycarbonyl-1-butylidene)-7-tetrahydropyranyloxy-2-oxabicyclo<3.3.0>octane

下游产品

2-[(3aR,4R,5R,6aS)-5-Hydroxy-4-((E)-(R)-3-hydroxy-oct-1-enyl)-hexahydro-cyclopenta[b]furan-(2E)-ylidene]-hexanedioic acid dimethyl ester (1S,5R,6R,7R)-(E)-3-(1,4-dimethoxycarbonyl-1-butylidene)-7-hydroxy-6(3(S)-hydroxy-E-1-octenyl)-2-oxabicyclo<3.3.0>octane