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(-)-tert-butyldimethylsilyl (1R,3S,6R)-6-ethynyl-1,5,5-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl ether

(-)-tert-butyldimethylsilyl (1R,3S,6R)-6-ethynyl-1,5,5-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl ether

CAS号：130224-07-6

英文名：(-)-tert-butyldimethylsilyl (1R,3S,6R)-6-ethynyl-1,5,5-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl ether

分子式：C17H30O2Si

分子量：294.504

合成路线

(R)-5-(tert-butyldimethylsilyloxy)-2-[(trifluoromethanesulfonyl)oxy]-1,3,3-trimethylcyclohex-1-ene

(R)-5-(tert-butyldimethylsilyloxy)-2-[(trifluoromethanesulfonyl)oxy]-1,3,3-trimethylcyclohex-1-ene

(-)-tert-butyldimethylsilyl (1R,3S,6R)-6-ethynyl-1,5,5-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl ether

(-)-tert-butyldimethylsilyl (1R,3S,6R)-6-ethynyl-1,5,5-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl ether

142563-00-6

(-)-tert-butyldimethylsilyl (1R,3S,6R)-6-ethynyl-1,5,5-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl ether

(-)-tert-butyldimethylsilyl (1R,3S,6R)-6-ethynyl-1,5,5-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl ether

130320-94-4

(-)-tert-butyldimethylsilyl (1R,3S,6R)-6-ethynyl-1,5,5-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl ether

(-)-tert-butyldimethylsilyl (1R,3S,6R)-6-ethynyl-1,5,5-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl ether

(-)-(1S,4S,6R)-4-(tert-butyldimethylsilyloxy)-2,2,6-trimethyl-7-oxabicyclo[4.1.0]heptane-1-carbaldehyde

(-)-(1S,4S,6R)-4-(tert-butyldimethylsilyloxy)-2,2,6-trimethyl-7-oxabicyclo[4.1.0]heptane-1-carbaldehyde

(-)-tert-butyldimethylsilyl (1R,3S,6R)-6-ethynyl-1,5,5-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl ether

(-)-tert-butyldimethylsilyl (1R,3S,6R)-6-ethynyl-1,5,5-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl ether

(R)-4-(tert-Butyl-dimethyl-silanyloxy)-2,6,6-trimethyl-cyclohex-1-enecarboxylic acid methyl ester

(R)-4-(tert-Butyl-dimethyl-silanyloxy)-2,6,6-trimethyl-cyclohex-1-enecarboxylic acid methyl ester

(-)-tert-butyldimethylsilyl (1R,3S,6R)-6-ethynyl-1,5,5-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl ether

(-)-tert-butyldimethylsilyl (1R,3S,6R)-6-ethynyl-1,5,5-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl ether

130321-09-4

(-)-tert-butyldimethylsilyl (1R,3S,6R)-6-ethynyl-1,5,5-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl ether

(-)-tert-butyldimethylsilyl (1R,3S,6R)-6-ethynyl-1,5,5-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl ether

(1R,6S)-6-((E)-2-Chloro-vinyl)-1,5,5-trimethyl-7-oxa-bicyclo[4.1.0]heptan-3-one

(1R,6S)-6-((E)-2-Chloro-vinyl)-1,5,5-trimethyl-7-oxa-bicyclo[4.1.0]heptan-3-one

(-)-tert-butyldimethylsilyl (1R,3S,6R)-6-ethynyl-1,5,5-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl ether

(-)-tert-butyldimethylsilyl (1R,3S,6R)-6-ethynyl-1,5,5-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl ether

(4R,6R)-4-hydroxy-2,2,6-trimethylcyclohexan-1-one

(4R,6R)-4-hydroxy-2,2,6-trimethylcyclohexan-1-one

(-)-tert-butyldimethylsilyl (1R,3S,6R)-6-ethynyl-1,5,5-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl ether

(-)-tert-butyldimethylsilyl (1R,3S,6R)-6-ethynyl-1,5,5-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl ether

上游原料

(1R,6S)-6-((E)-2-Chloro-vinyl)-1,5,5-trimethyl-7-oxa-bicyclo[4.1.0]heptan-3-one (R)-5-(tert-butyldimethylsilyloxy)-2-[(trifluoromethanesulfonyl)oxy]-1,3,3-trimethylcyclohex-1-ene (-)-(1S,4S,6R)-4-(tert-butyldimethylsilyloxy)-2,2,6-trimethyl-7-oxabicyclo[4.1.0]heptane-1-carbaldehyde (R)-4-(tert-Butyl-dimethyl-silanyloxy)-2,6,6-trimethyl-cyclohex-1-enecarboxylic acid methyl ester (4R,6R)-4-hydroxy-2,2,6-trimethylcyclohexan-1-one

下游产品

(+)-(5E,1R,4S,6R)-5-[4-(tert-butyl(dimethyl)silyloxy)-2,2,6-trimethyl-7-oxabicyclo[4.1.0]-heptan-1-yl]pent-2-en-4-yn-1-ol