百科

(2S,7R,E)-2-((4S,6R)-2,2-dimethyl-6-(pent-4-en-1-yl)-1,3-dioxan-4-yl)-5-methyl-7-((triethylsilyl)oxy)dec-4-en-3-one

(2S,7R,E)-2-((4S,6R)-2,2-dimethyl-6-(pent-4-en-1-yl)-1,3-dioxan-4-yl)-5-methyl-7-((triethylsilyl)oxy)dec-4-en-3-one

CAS号：1303438-77-8

英文名：(2S,7R,E)-2-((4S,6R)-2,2-dimethyl-6-(pent-4-en-1-yl)-1,3-dioxan-4-yl)-5-methyl-7-((triethylsilyl)oxy)dec-4-en-3-one

分子式：C28H52O4Si

分子量：480.796

合成路线

(3S,5S)-hepta-1,6-diene-3,5-diol

(3S,5S)-hepta-1,6-diene-3,5-diol

(2S,7R,E)-2-((4S,6R)-2,2-dimethyl-6-(pent-4-en-1-yl)-1,3-dioxan-4-yl)-5-methyl-7-((triethylsilyl)oxy)dec-4-en-3-one

(2S,7R,E)-2-((4S,6R)-2,2-dimethyl-6-(pent-4-en-1-yl)-1,3-dioxan-4-yl)-5-methyl-7-((triethylsilyl)oxy)dec-4-en-3-one

tert-butyl((R)-2-((4S,6R)-6-(5-(4-methoxybenzyloxy)pentyl)-2,2-dimethyl-1,3-dioxan-4-yl)propoxy)dimethylsilane

tert-butyl((R)-2-((4S,6R)-6-(5-(4-methoxybenzyloxy)pentyl)-2,2-dimethyl-1,3-dioxan-4-yl)propoxy)dimethylsilane

(2S,7R,E)-2-((4S,6R)-2,2-dimethyl-6-(pent-4-en-1-yl)-1,3-dioxan-4-yl)-5-methyl-7-((triethylsilyl)oxy)dec-4-en-3-one

(2S,7R,E)-2-((4S,6R)-2,2-dimethyl-6-(pent-4-en-1-yl)-1,3-dioxan-4-yl)-5-methyl-7-((triethylsilyl)oxy)dec-4-en-3-one

(4S,6S)-4,6-diethenyl-2-(2-propen-1-yloxy)-1,3,2-dioxaphosphorinane 2-oxide

(4S,6S)-4,6-diethenyl-2-(2-propen-1-yloxy)-1,3,2-dioxaphosphorinane 2-oxide

(2S,7R,E)-2-((4S,6R)-2,2-dimethyl-6-(pent-4-en-1-yl)-1,3-dioxan-4-yl)-5-methyl-7-((triethylsilyl)oxy)dec-4-en-3-one

(2S,7R,E)-2-((4S,6R)-2,2-dimethyl-6-(pent-4-en-1-yl)-1,3-dioxan-4-yl)-5-methyl-7-((triethylsilyl)oxy)dec-4-en-3-one

(1S,6S,8S)-8-vinyl-2,9,10-trioxa-1-phosphabicyclo[4.3.1]dec-4-ene 1-oxide

(1S,6S,8S)-8-vinyl-2,9,10-trioxa-1-phosphabicyclo[4.3.1]dec-4-ene 1-oxide

(2S,7R,E)-2-((4S,6R)-2,2-dimethyl-6-(pent-4-en-1-yl)-1,3-dioxan-4-yl)-5-methyl-7-((triethylsilyl)oxy)dec-4-en-3-one

(2S,7R,E)-2-((4S,6R)-2,2-dimethyl-6-(pent-4-en-1-yl)-1,3-dioxan-4-yl)-5-methyl-7-((triethylsilyl)oxy)dec-4-en-3-one

上游原料

(4S,6S)-4,6-diethenyl-2-(2-propen-1-yloxy)-1,3,2-dioxaphosphorinane 2-oxide (3S,5S)-hepta-1,6-diene-3,5-diol (1S,6S,8S)-8-vinyl-2,9,10-trioxa-1-phosphabicyclo[4.3.1]dec-4-ene 1-oxide tert-butyl((R)-2-((4S,6R)-6-(5-(4-methoxybenzyloxy)pentyl)-2,2-dimethyl-1,3-dioxan-4-yl)propoxy)dimethylsilane

下游产品

(5S,7R,9S,12R,13S,14S)-15-((4R,8R,9S,10S,12R,E)-4-acetoxy-10,12-dihydroxy-6,9-dimethylheptadeca-6,16-dien-8-yloxy)-13-(4-methoxybenzyloxy)-2,12,14-trimethyl-15-oxopentadec-1-ene-5,7,9-triyl triacetate